Citation: TAN Jiang, TAN Xi, KANG Wenbin, ZHANG Chuhong. Two Dimensional Molybdenum Disulfide/Graphite Composites Prepared by Direct All-Solid-State Ball-Milling for Lithium-Ion Batteries[J]. Chinese Journal of Applied Chemistry, ;2017, 34(7): 810-817. doi: 10.11944/j.issn.1000-0518.2017.07.170100 shu

Two Dimensional Molybdenum Disulfide/Graphite Composites Prepared by Direct All-Solid-State Ball-Milling for Lithium-Ion Batteries

State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute, Sichuan University, Chengdu 610065, China

Corresponding author: ZHANG Chuhong, chuhong.zhang@scu.edu.cn
Received Date: 1 April 2017
Revised Date: 24 April 2017
Accepted Date: 28 April 2017

Fund Project: the Project of State Key Laboratory of Polymer Materials Engineering of Sichuan University SKLPME2014-2-07the National Natural Science Foundation of China 51673123the National Basic Research Program of China 2013CB934700

Figures(5)

Two dimensional flaky composites of MoS₂/graphite are first prepared via direct all-solid-state ball-milling using commercial molybdenum disulfide(MoS₂) and graphite as raw materials. As evidenced from X-ray difraction, scanning electron microscopy and energy dispersive spectrometry, MoS₂ and graphite are exfoliated into thin sheets, which entangle uniformly alleviating the agglomeration of MoS₂. Thus as-prepared MoS₂/graphite composites exhibit significantly improved cycling stability and rate capability. When tested at the current density of 100 mA/g, MoS₂/graphite(mass ratio 7:3) composite shows an initial specific discharge capacity of 801 mA·h/g and retains a reversible specific capacity of 694 mA·h/g after 100 cycles, which is much superior to that of bulk MoS₂(about 110 mA·h/g remained after 100 cycles). The outstanding electrochemical performance of ball-milled MoS₂/graphite composites could be attributed to following reasons:exfoliated graphite sheets not only improve the electrical conductivity of MoS₂/graphite composite, but also prevent the agglomeration of MoS₂ during the charge/discharge process, which enhances structural stability of the composite electrode. In addition, the technique reported herein also demonstrates a facile and low-cost method for the production of high performance lithium ion battery electrode materials on a large scale.
- all-solid-state ball-milling,
- molybdenum disulfide,
- lithium ion battery,
- anode material
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