Citation: YANG Yu, WANG Zhipeng, WANG Honghua, ZHOU Guangyuan, ZHU Xiaofei. Preparation and Characterization of Poly(aryl ether sulfone) Copolymers Containing Imidazolyl Group[J]. Chinese Journal of Applied Chemistry, ;2017, 34(6): 623-630. doi: 10.11944/j.issn.1000-0518.2017.06.160381 shu

Preparation and Characterization of Poly(aryl ether sulfone) Copolymers Containing Imidazolyl Group

YANG Yu ^a ,
WANG Zhipeng ^b,c ,
WANG Honghua ^b,c ,
ZHOU Guangyuan ^b,*,, ,
ZHU Xiaofei ^a,*,,

a.
Institute of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, China
b.
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
c.
Changzhou Institute of Energy Storage Meterials & Devices, Changzhou, Jiangsu 213002, China

Corresponding author: ZHOU Guangyuan, gyzhou@ciac.ac.cn ZHU Xiaofei, zhuxiaofei@ccut.edu.cn
Received Date: 21 September 2016
Revised Date: 3 November 2016
Accepted Date: 6 December 2016

Fund Project: National High Technology Research and Development Projects 2015AA033901

Figures(6)

A series of different content of benzimidazolone and 5, 6-dimethyl-2-benzimidazolone poly(aryl ether sulfone) copolymers with side groups were synthesized by copolymerization on the basis of poly(aryl ether sulfone) with cardo group(PES-C). The structures and properties of the copolymers were characterized by nuclear magnetic resonance spectroscopy(NMR), Fourier transform infrared spectrometer(FTIR), thermal gravimetric analyzer(TGA) and so on. The resulsts show that poly(aryl ether sulfone) copolymers are amorphous. The copolymers exhibit good heat resistance, and present a single glass transition temperature(T_g>271℃), when the mole fraction of benzimidazolone and 5, 6-dimethyl-2-benzimidazolone increases, the copolymer glass transition temperature rises, ranging from 270℃ to 318℃ and 314℃, respectively. At the same time, the copolymers have good thermal stability. These copolymers have good solubility in N, N-dimethyl formamide(DMF), N, N-dimethylacetamide(DMAc), dimethyl sulfoxide(DMSO), N-methyl pyrrolidone(NMP) which are the commonly polar aprotic solvents, and trichloromethane(CHCl₃). Based on good solution processability and film-forming properties, the toughness thin film can be prepared by solution preparation.
- poly(aryl ether sulfone),
- benzimidazolone,
- phenolphthalein,
- copolymer,
- amorphous form
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Characterization of Poly(aryl ether sulfone) Copolymers Containing Imidazolyl Group

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com