Citation: ZHANG Ying, HU Yanming, LI Zhansheng, XU Jie, XIA Yuping, MASUDA Toshio. Preparation and Performance of Solvent Resistance Poly (diphenylacetylene) Nanofiltration Membranes[J]. Chinese Journal of Applied Chemistry, ;2017, 34(4): 443-448. doi: 10.11944/j.issn.1000-0518.2017.04.160297 shu

Preparation and Performance of Solvent Resistance Poly (diphenylacetylene) Nanofiltration Membranes

ZHANG Ying ^a ,
HU Yanming ^b ,
LI Zhansheng ^a,*,, ,
XU Jie ^a ,
XIA Yuping ^a ,
MASUDA Toshio ^c

a.
School of Chemical Engineering, Dalian university of technology, Dalian, Liaoning 116024, China
b.
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
c.
Department of Environmental and Biological Chemistry, Fukui University of Technology, Fukui 910-8505, Japan

Corresponding author: LI Zhansheng, lizs@dlut.edu.cn
Received Date: 18 July 2016
Revised Date: 29 August 2016
Accepted Date: 8 October 2016

Fund Project: the Fundamental Research Funds for the Central Universities DUT11LK14the Fundamental Research Funds for the Central Universities DUT14ZD223the National High Technology Research and Development Program of China 2015AA033802

Figures(6)

Poly (diphenylacetylene)(PDPA) is insoluble in organic solvents which makes it a new type promising membrane material for solvent resistant nanofiltration. PDPA membranes were obtained by desilylation of poly[1-phenyl-2-[p-(trimethylsilyl) phenyl]acetylene](PTMSDPA) dense membranes, which were prepared by solution-casting method. The permeation of pure ethanol and the retention of dye/ethanol solutions were investigated. The ethanol permeability of the PDPA membrane increases linearly with increased applying pressure. The transport mechanism for solvents in PDPA membrane can fall in the transition range between a pore flow and a solution diffusion mechanism. Moreover, the dye retention of the PDPA membrane is controlled by the molecular size of the dyes, the charge character and interaction between the dyes and the membrane.
- poly (diphenylacetylene),
- solvent resistant nanofiltration,
- dye retention
1. [1]
  Marchetti P F M, Solomon J. Molecular Separation with Organic Solvent Nanofiltration:A Ccritical Review[J]. Chem Rev, 2014,114(21):10735-10806. doi: 10.1021/cr500006j
2. [2]
  Cheng X, Zhang Y, Wang Z. Recent Advances in Polymeric Solvent-resistant Nanofiltration Membranes[J]. Adv Polym Technol, 2014,33(S1)21455.
3. [3]
  Vandezande P, Gevers L E M, Vankelecom I F J. Solvent Resistant Nanofiltration:Separating on a Molecular Level[J]. Chem Soc Rev, 2008,37(2):365-405. doi: 10.1039/B610848M
4. [4]
  WEI Wang, XIANGLI Fenjuan, JIN Wanqin. Solvent Resistant Nanofiltration Membranes[J]. Prog Chem, 2007,19(10):1592-1597.
5. [5]
  PAN Cheng, WANG Yu, LI Xuemei. The Preparation and Application of PES Hollow Fiber Nanofiltration Membrane by Coating Method[J]. Membr Sci Technol, 2012,32(1):18-22.
6. [6]
  XING Yanan, SU Baowei, ZHEN Hongyan. Research Progress of Solvent Resistant Nanofiltration Membranes[J]. Chem Ind Eng Prog, 2015,34(11):3832-3840.
7. [7]
  Fritsch D, Merten P, Heinrich K. High Performance Organic Solvent Nanofiltration Membranes:Development and Thorough Testing of Thin Film Composite Membranes Made of Polymers of Intrinsic Microporosity (PIMs)[J]. J Membr Sci, 2012,401/402:222-231. doi: 10.1016/j.memsci.2012.02.008
8. [8]
  Volkova A V, Stamatialis D F, Khotimsky V S. Poly[1-(trimethylsilyl)-1-propyne] as a Solvent Resistance Nanofiltration Membrane Material[J]. J Membr Sci, 2006,281(1/2):351-357.
9. [9]
  Volkov A V, Parashchuk V V, Stamatialis D F. High Permeable PTMSP/PAN Composite Membranes for Solvent Nanofiltration[J]. J Membr Sci, 2009,333(1/2):88-93.
10. [10]
  Volkov A, Yushkin A, Grekhov A. Liquid Permeation Through PTMSP:One Polymer for Two Different Membrane Applications[J]. J Membr Sci, 2013,440:98-107. doi: 10.1016/j.memsci.2013.03.067
11. [11]
  XU Jie, ZHANG Ying, LI Zhansheng. Nanofiltration Performance Research of PTMSDPA Membrane[J]. Membr Sci Technol, 2016,36(1):50-54.
12. [12]
  Raharjo R D, Lee H J, Freeman B D. Pure Gas and Vapor Permeation Properties of Poly[1-phenyl-2-[p-(trimethylsilyl) phenyl]acetylene](PTMSDPA) and Its Desilylated Analog, Poly[diphenylacetylene](PDPA)[J]. Polymer, 2005,46(17):6316-6324. doi: 10.1016/j.polymer.2005.05.093
13. [13]
  Hu Y, Sakaguchi T, Shiotsuki M. Synthesis and Properties of Poly (diphenylacetylenes) Containing Siloxy and Halogen/Methyl Groups and Their Desilylated Membranes[J]. Polymer, 2007,48(1):43-49. doi: 10.1016/j.polymer.2006.11.007
14. [14]
  HUA Youqing, JIN Riguang. Polymer Physics[M]. Beijing:Chemical Industry Press, 2013(in Chinese).
15. [15]
  CHENG Nenglin. Solvents Handbook. 4^th Ed[M]. Beijing:Chemical Industry Press, 2008(in Chinese).
16. [16]
  Machado D R, Hasson D, Semiat R. Effect of Solvent Properties on Permeate Flow Through Nanofiltration Membranes. Part I:Investigation of Parameters Affecting Solvent Flux[J]. J Membr Sci, 1999,163(1):93-102. doi: 10.1016/S0376-7388(99)00158-1
17. [17]
  Uragami T, Yono T, Sugihara M. Studies on Syntheses and Permeabilities of Special Polymer Membranes. XX.Permeabilities of Alcohols and Hydrocarbons Through Acrylonitrile-butadiene-styrene Terpolymer Membranes[J]. Angew Makromol Chem, 1979,82(1):89-102. doi: 10.1002/apmc.1979.050820108
18. [18]
  Wijmans J G, Baker R W. The Solution-Diffusion Model:A Review[J]. J Membr Sci, 1995,107:1-21. doi: 10.1016/0376-7388(95)00102-I
19. [19]
  Tsar'Kov S E, Malakhov A O, Litvinova E G. Nanofiltration of Dye Solutions Through Membranes Based on Poly (trimethylsilylpropyne)[J]. Pet Chem, 2013,53(7):537-545. doi: 10.1134/S0965544113070189
20. [20]
  Tsarkov S, Khotimskiy V, Budd P M. Solvent Nanofiltration Through High Permeability Glassy Polymers:Effect of Polymer and Solute Nature[J]. J Membr Sci, 2012,423/424:65-72. doi: 10.1016/j.memsci.2012.07.026
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