Citation: YANG Chengxiong, WANG Shiwei, YAN Xiuping. Adsorption Thermodynamics and Kinetics of Phenols on Metal-Organic Framework Aluminum Terephthalate in Water[J]. Chinese Journal of Applied Chemistry, ;2016, 33(9): 1040-1046. doi: 10.11944/j.issn.1000-0518.2016.09.160211 shu

Adsorption Thermodynamics and Kinetics of Phenols on Metal-Organic Framework Aluminum Terephthalate in Water

1.
Research Center for Analytical Sciences, College of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: YAN Xiuping,
Received Date: 20 May 2016
Available Online: 27 June 2016
Fund Project:

Adsorption of phenols such as o-nitrophenol, phenol, and catechol on metal-organic framework aluminum terephthalate[MIL-53(Al), MIL:Materials of Institut Lavoisier] was investigated in detail in terms of adsorption isotherms, thermodynamics, and kinetics. The adsorption of the phenols on MIL-53(Al) follows a pseudo-second order kinetic model. Intraparticle diffusion model analysis reveals that the adsorption of the phenols on MIL-53(Al) proceeds by two phases, surface sorption and intraparticle/pore diffusion. The adsorption of phenols fits well with the Freundlich model. In addition, the results indicate that the adsorption of the phenols on MIL-53(Al) is a thermodynamically spontaneous process with positive enthalpy change and positive entropy change. The adsorption capacities for o-nitrophenol, phenol, and catechol at 40℃ are 78.6, 30.5, and 16.5 mg/g, respectively.
- metal-organic framework,
- adsorption,
- phenols,
- aluminum terephthalate
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