Citation: DONG Tingting, BI Congcong, GAO Baojiao. Catalytic Oxidation Property and Mechanism of 2,2,6,6-Tetramethylpiperidine-1-oxyl Immobilized on Crosslinked Polystyrene Microspheres[J]. Chinese Journal of Applied Chemistry, ;2016, 33(9): 1017-1025. doi: 10.11944/j.issn.1000-0518.2016.09.150452 shu

Catalytic Oxidation Property and Mechanism of 2,2,6,6-Tetramethylpiperidine-1-oxyl Immobilized on Crosslinked Polystyrene Microspheres

1.
Department of Chemical Engineering, North University of China, Taiyuan 030051, China

Corresponding author: GAO Baojiao,
Received Date: 17 December 2015
Available Online: 28 March 2016
Fund Project:

2,2,6,6-Tetramethylpiperidine-1-oxyl(TEMPO) was immobilized on crosslinked polystyrene(CPS) microspheres to give a heterogeneous microspheres TEMPO/CPS catalyst. A combined catalysts of TEMPO/CPS microspheres and metal salts were used in the oxidation of cinnamyl alcohol with molecular oxygen as the oxidant. The catalytic properties and catalytic mechanisms of these combinational catalysts were investigated. Some combined catalysts can effectively catalyze the oxidation reaction of cinnamyl alcohol to cinnamyl aldehyde as sole product. For nitrate co-catalysts, if the corresponding metal ion has weaker oxidizing ability than NO₃^- ion, for example, Fe(NO₃)₃ and Cu(NO₃)₂, the cations and anions will work together in the catalytic process. If the oxidizability of metal ion is stronger than NO₃^- ion, for example, Co(NO₃)₂ and Mn(NO₃)₂, the metal ion will alone play a role in the oxidation. Among several transition metal salts, Fe(NO₃)₃ is the best co-catalyst, and leads to the oxidation of cinnamyl alcohol to cinnamyl aldehyde in 92% conversion under mild conditions (at 55℃ and with O₂ at ordinary pressure).
- tetramethylpiperidine-1-oxyl,
- heterogeneous catalyst,
- cinnamyl alcohol,
- molecular oxygen,
- catalytic oxidation
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