Citation:
ZHANG Xiaonan, SUN Yudong, LI Naixuan. Synthesis and Photocatalytic Activity of Graphitic Carbon Nitride/Cyanuric Chloride Composite Photocatalyst[J]. Chinese Journal of Applied Chemistry,
;2016, 33(7): 820-826.
doi:
10.11944/j.issn.1000-0518.2016.07.150356
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A graphitic carbon nitride/cyanuric chloride(g-C3N4/C3Cl3N3) composite photocatalyst was developed. The obtained catalyst effectively expands π-conjugated system of g-C3N4. Moreover, the band gap is significantly shifted, and the reduction ability of the photo generated charge is improved because of the introduction of a chlorine atom. The catalyst can effectively degrade organic pollutants under visible light. The result shows that the degradation ratio of reactive red-dye is 94.7% and is still kept at 94% after using 5 times. The mechanism on the degradation of organic pollutants under visible light was studied.
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[1]
[1] Wang X C,Maeda K,Thomas A,et al. Ametal-Free Polymeric Photocatalyst for Hydrogen Production from Water under Visible Light[J]. Nat Mater,2009,8(1):76-80.
-
[2]
[2] Wang Y F,Gao B Y,Yue Q Y,et al. Flocculation Performance of Epichlorohydrin-Dimethylamine Polyamine in Treating Dyeing Wastewater[J]. Environ Manage,2009,1(2):423-431.
-
[3]
[3] Zhang F J,Xie F Z,Zhu S F,et al. A Novel Photofunctional g-C3N4/Ag3PO4 Bulk Heterojunction for Decolorization of RhB[J]. Chem Eng,2013,28(15):435-441.
-
[4]
[4] Mitoraj D,Kisch H. On the Mechanism of Urea Induced Titania Modification[J]. Chem Eur,2010,16(1):261-269.
-
[5]
[5] He P Z,Song L M,Zhang S J,et al. Synthesis of g-C3N4/Ag3PO4 Heterojunction with Enhanced Photocatalytic Performance[J]. Mater Res Bull,2014,51(6):432-437.
-
[6]
[6] Xu H,Yan J,Xu Y G,et al. Novel Visible-Light-Driven AgX/Graphite-Like C3N4(X=Br,I) Hybrid Materials with Synergistic Photocatalytic Activity[J]. Appl Catal B:Environ,2013,129:182-193.
-
[7]
[7] Meng Y L,Shen J,Chen D,et al. Photodegradation Peoformance of Methylene Blue Aqueous Solution on Ag/g-C3N4 Catalyst[J]. Rare Met,2011,30(1):276-279.
-
[8]
[8] Wang X C,Blechert S,Antonietti M. Polymeric Graphitic Carbon Nitride for Heterogeneous Photocatalysis[J]. ACS Catal,2012,2(8):1596-1606.
-
[9]
[9] Maeda K,Wang X C,Nishihara D,et al. Photocatalytic Activities of Graphitic Carbon Nitride Powder for Water Reduction and Oxidation under Visible Light[J]. Phys Chem,2009,113(12):4940-4947.
-
[10]
[10] Wang X C,Thomas A,Fu X Z,et al. Metal-Containing Carbon Nitride Compounds:A New Functional Organic-Metal Hybrid Material[J]. Adv Mater,2009,21(16):1609-1612.
-
[11]
[11] Fu X Z,Wang X C,Antonietti M,et al. Fe-g-C3N4-Catalyzed Oxidation of Benzene to Phenol Using Hydrogen Peroxide and Visible Light[J]. J Am Chem Soc,2009,131(33):11658-11659.
-
[12]
[12] Ding Z X,Wang X C,Antonietti M,et al. Synthesis of Transition Metal-Modified Carbon Nitride Polymers for Selective Hydrocarbon Oxidation[J]. ChemSusChem,2011,4(2):274-281.
-
[13]
[13] Yan S C,Li Z S. Photodegradation of Rhodamine B and Methyl Orange over Boron-Doped g-C3N4 under Visible Light Irradiation[J]. Langmuir,2010,26(6):3894-3901.
-
[14]
[14] Liu G,Niu P,Smith S,et al. Unique Electronic Structure Induced High Photoreactivity of Sulfur-Doped Graphitic C3N4[J]. J Am Chem Soc,2010,132(33):11642-11648.
-
[15]
[15] Zhang Y J,Mori T,Antonietti M,et al. Phosphorus-Doped Carbon Nitride Solid: Enhanced Electrical Conductivity and Photocurrent Generation[J]. J Am Chem Soc,2010,132(18):6294-6295.
-
[16]
[16] Dong G H,Zhao Kun,Zhang L Z,et al. Carbon Self-Doping Induced High Electronic Conductivity and Photoreactivity of g-C3N4[J]. Chem Commun,2012,48(49):6178-6180.
-
[17]
[17] Li J H,Shen B,Chen Y L,et al. A Facile Approach to Synthesize Novel Oxygen-Doped g-C3N4 with Superior Visible-Light Photoreactivity[J]. Chem Commun,2012,48(98):12017-12019.
-
[18]
[18] Wang Y,Antonietti M,Wang X C,et al. Excellent Visible Light Photocatalysis of Fluorinated Polymeric Carbon Nitride Solids[J]. Chem Mater,2010,22(18):5119-5121.
-
[19]
[19] Niu P,Zhang L L,Liu G,et al. Graphene-Like Carbon Nitride Nanosheets for Improved Photocatalytic Activities[J]. Funct Mater,2012,21(22):4763 4770.
-
[20]
[20] Bettina V,Sehnert J,Seyfarth L,et al. Unmasking Melon by a Complementary Approach Employing Electron Diffraction, Solid-State NMR Spectroscopy, and Theoretical Calculations-Structural Characterization of a Carbon Nitride Polymer[J]. Chem Eur,2007,13(17):4969-4980.
-
[21]
[21] Jing D L,Chen L L,Xie J M,et al. Ag2S/g-C3N4 Composite Photocatalysts for Efficient Pt-Free Hydrogen Production[J]. Dalton Trans,2014,43(12):4878-4885.
-
[22]
[22] DONG Fan,LI Yuhan,HO Wingkei,et al. Synthesis of Mesoporous Polymeric Carbon Nitride Exhibiting Enhanced and Durable Visible Light Photocatalytic Performance[J]. Chinese Sci Bull,2014,59(7):688-698(in Chinese).董帆,李昱翰,何咏基博,等. 增强和持久可见光催化性能的介孔聚合物碳氮化物的合成[J]. 中国科学通报,2014,59(7):688-698 .
-
[23]
[23] Wang S M,Li D L,Sun C,et al. Synthesis and Characterization of g-C3N4/Ag3VO4 Composites with Significantly Enhanced Visible-Light Photocatalytic Activity for Triphenylmethane Dye Degradation[J]. Appl Catal B:Environ,2014,144(2):885-892.
-
[24]
[24] Chu S,Wang Y,Guo Y,et al. Band Structure Engineering of Carbon Nitride:In Search of a Polymer Photocatalyst with High Photooxidation Property[J]. ACS Catal,2013,3(5):912-919.
-
[25]
[25] Li X F,Zheng J,Shen L H,et al. Preparation and Characterization of Graphitic Carbon Nitride through Pyrolysis of Melamine[J]. Appl Phys,2009,94(2):387-392.
-
[26]
[26] LU Changyuan,HAN Zhenhui,PAN Jingxi,et al. Riboflavin(vitamin B2) Photochemical Activity:The Potential Biological Effects of Light Particles[J]. J Radiat Res Radiat Process,2000,2(1):12-18(in Chinese).陆长元,韩镇辉,潘景喜,等. 核黄素(维生素B2)的光化学活性粒子:潜在的光生物学效应[J]. 辐射研究与辐射工艺学报,2000,2(1):12-18.
-
[27]
[27] Cao J,Zhao Y J,Lin H L,et al. Ag/AgBr/g-C3N4:A Highly Efficient and Stable Composite Photocatalyst for Degradation of Organic Contaminants under Visible Light[J]. Mater Res Bull,2013,48(10):3873-3880.
-
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