Citation: ZHANG Xiaonan, SUN Yudong, LI Naixuan. Synthesis and Photocatalytic Activity of Graphitic Carbon Nitride/Cyanuric Chloride Composite Photocatalyst[J]. Chinese Journal of Applied Chemistry, ;2016, 33(7): 820-826. doi: 10.11944/j.issn.1000-0518.2016.07.150356 shu

Synthesis and Photocatalytic Activity of Graphitic Carbon Nitride/Cyanuric Chloride Composite Photocatalyst

  • Corresponding author: LI Naixuan, 
  • Received Date: 9 October 2015
    Available Online: 6 January 2016

    Fund Project:

  • A graphitic carbon nitride/cyanuric chloride(g-C3N4/C3Cl3N3) composite photocatalyst was developed. The obtained catalyst effectively expands π-conjugated system of g-C3N4. Moreover, the band gap is significantly shifted, and the reduction ability of the photo generated charge is improved because of the introduction of a chlorine atom. The catalyst can effectively degrade organic pollutants under visible light. The result shows that the degradation ratio of reactive red-dye is 94.7% and is still kept at 94% after using 5 times. The mechanism on the degradation of organic pollutants under visible light was studied.
  • 加载中
    1. [1]

      [1] Wang X C,Maeda K,Thomas A,et al. Ametal-Free Polymeric Photocatalyst for Hydrogen Production from Water under Visible Light[J]. Nat Mater,2009,8(1):76-80.

    2. [2]

      [2] Wang Y F,Gao B Y,Yue Q Y,et al. Flocculation Performance of Epichlorohydrin-Dimethylamine Polyamine in Treating Dyeing Wastewater[J]. Environ Manage,2009,1(2):423-431.

    3. [3]

      [3] Zhang F J,Xie F Z,Zhu S F,et al. A Novel Photofunctional g-C3N4/Ag3PO4 Bulk Heterojunction for Decolorization of RhB[J]. Chem Eng,2013,28(15):435-441.

    4. [4]

      [4] Mitoraj D,Kisch H. On the Mechanism of Urea Induced Titania Modification[J]. Chem Eur,2010,16(1):261-269.

    5. [5]

      [5] He P Z,Song L M,Zhang S J,et al. Synthesis of g-C3N4/Ag3PO4 Heterojunction with Enhanced Photocatalytic Performance[J]. Mater Res Bull,2014,51(6):432-437.

    6. [6]

      [6] Xu H,Yan J,Xu Y G,et al. Novel Visible-Light-Driven AgX/Graphite-Like C3N4(X=Br,I) Hybrid Materials with Synergistic Photocatalytic Activity[J]. Appl Catal B:Environ,2013,129:182-193.

    7. [7]

      [7] Meng Y L,Shen J,Chen D,et al. Photodegradation Peoformance of Methylene Blue Aqueous Solution on Ag/g-C3N4 Catalyst[J]. Rare Met,2011,30(1):276-279.

    8. [8]

      [8] Wang X C,Blechert S,Antonietti M. Polymeric Graphitic Carbon Nitride for Heterogeneous Photocatalysis[J]. ACS Catal,2012,2(8):1596-1606.

    9. [9]

      [9] Maeda K,Wang X C,Nishihara D,et al. Photocatalytic Activities of Graphitic Carbon Nitride Powder for Water Reduction and Oxidation under Visible Light[J]. Phys Chem,2009,113(12):4940-4947.

    10. [10]

      [10] Wang X C,Thomas A,Fu X Z,et al. Metal-Containing Carbon Nitride Compounds:A New Functional Organic-Metal Hybrid Material[J]. Adv Mater,2009,21(16):1609-1612.

    11. [11]

      [11] Fu X Z,Wang X C,Antonietti M,et al. Fe-g-C3N4-Catalyzed Oxidation of Benzene to Phenol Using Hydrogen Peroxide and Visible Light[J]. J Am Chem Soc,2009,131(33):11658-11659.

    12. [12]

      [12] Ding Z X,Wang X C,Antonietti M,et al. Synthesis of Transition Metal-Modified Carbon Nitride Polymers for Selective Hydrocarbon Oxidation[J]. ChemSusChem,2011,4(2):274-281.

    13. [13]

      [13] Yan S C,Li Z S. Photodegradation of Rhodamine B and Methyl Orange over Boron-Doped g-C3N4 under Visible Light Irradiation[J]. Langmuir,2010,26(6):3894-3901.

    14. [14]

      [14] Liu G,Niu P,Smith S,et al. Unique Electronic Structure Induced High Photoreactivity of Sulfur-Doped Graphitic C3N4[J]. J Am Chem Soc,2010,132(33):11642-11648.

    15. [15]

      [15] Zhang Y J,Mori T,Antonietti M,et al. Phosphorus-Doped Carbon Nitride Solid: Enhanced Electrical Conductivity and Photocurrent Generation[J]. J Am Chem Soc,2010,132(18):6294-6295.

    16. [16]

      [16] Dong G H,Zhao Kun,Zhang L Z,et al. Carbon Self-Doping Induced High Electronic Conductivity and Photoreactivity of g-C3N4[J]. Chem Commun,2012,48(49):6178-6180.

    17. [17]

      [17] Li J H,Shen B,Chen Y L,et al. A Facile Approach to Synthesize Novel Oxygen-Doped g-C3N4 with Superior Visible-Light Photoreactivity[J]. Chem Commun,2012,48(98):12017-12019.

    18. [18]

      [18] Wang Y,Antonietti M,Wang X C,et al. Excellent Visible Light Photocatalysis of Fluorinated Polymeric Carbon Nitride Solids[J]. Chem Mater,2010,22(18):5119-5121.

    19. [19]

      [19] Niu P,Zhang L L,Liu G,et al. Graphene-Like Carbon Nitride Nanosheets for Improved Photocatalytic Activities[J]. Funct Mater,2012,21(22):4763 4770.

    20. [20]

      [20] Bettina V,Sehnert J,Seyfarth L,et al. Unmasking Melon by a Complementary Approach Employing Electron Diffraction, Solid-State NMR Spectroscopy, and Theoretical Calculations-Structural Characterization of a Carbon Nitride Polymer[J]. Chem Eur,2007,13(17):4969-4980.

    21. [21]

      [21] Jing D L,Chen L L,Xie J M,et al. Ag2S/g-C3N4 Composite Photocatalysts for Efficient Pt-Free Hydrogen Production[J]. Dalton Trans,2014,43(12):4878-4885.

    22. [22]

      [22] DONG Fan,LI Yuhan,HO Wingkei,et al. Synthesis of Mesoporous Polymeric Carbon Nitride Exhibiting Enhanced and Durable Visible Light Photocatalytic Performance[J]. Chinese Sci Bull,2014,59(7):688-698(in Chinese).董帆,李昱翰,何咏基博,等. 增强和持久可见光催化性能的介孔聚合物碳氮化物的合成[J]. 中国科学通报,2014,59(7):688-698 .

    23. [23]

      [23] Wang S M,Li D L,Sun C,et al. Synthesis and Characterization of g-C3N4/Ag3VO4 Composites with Significantly Enhanced Visible-Light Photocatalytic Activity for Triphenylmethane Dye Degradation[J]. Appl Catal B:Environ,2014,144(2):885-892.

    24. [24]

      [24] Chu S,Wang Y,Guo Y,et al. Band Structure Engineering of Carbon Nitride:In Search of a Polymer Photocatalyst with High Photooxidation Property[J]. ACS Catal,2013,3(5):912-919.

    25. [25]

      [25] Li X F,Zheng J,Shen L H,et al. Preparation and Characterization of Graphitic Carbon Nitride through Pyrolysis of Melamine[J]. Appl Phys,2009,94(2):387-392.

    26. [26]

      [26] LU Changyuan,HAN Zhenhui,PAN Jingxi,et al. Riboflavin(vitamin B2) Photochemical Activity:The Potential Biological Effects of Light Particles[J]. J Radiat Res Radiat Process,2000,2(1):12-18(in Chinese).陆长元,韩镇辉,潘景喜,等. 核黄素(维生素B2)的光化学活性粒子:潜在的光生物学效应[J]. 辐射研究与辐射工艺学报,2000,2(1):12-18.

    27. [27]

      [27] Cao J,Zhao Y J,Lin H L,et al. Ag/AgBr/g-C3N4:A Highly Efficient and Stable Composite Photocatalyst for Degradation of Organic Contaminants under Visible Light[J]. Mater Res Bull,2013,48(10):3873-3880.

  • 加载中
    1. [1]

      Jingzhao ChengShiyu GaoBei ChengKai YangWang WangShaowen Cao . Construction of 4-Amino-1H-imidazole-5-carbonitrile Modified Carbon Nitride-Based Donor-Acceptor Photocatalyst for Efficient Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-0. doi: 10.3866/PKU.WHXB202406026

    2. [2]

      Tongyan Yu Pan Xu . Visible-Light Photocatalyzed Radical Rearrangement Reaction. University Chemistry, 2025, 40(7): 169-176. doi: 10.12461/PKU.DXHX202409070

    3. [3]

      Yadan LuoHao ZhengXin LiFengmin LiHua TangXilin She . Modulating reactive oxygen species in O, S co-doped C3N4 to enhance photocatalytic degradation of microplastics. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-0. doi: 10.1016/j.actphy.2025.100052

    4. [4]

      Yurong Tang Yunren Shi Yi Xu Bo Qin Yanqin Xu Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087

    5. [5]

      Dan Liu . 可见光-有机小分子协同催化的不对称自由基反应研究进展. University Chemistry, 2025, 40(6): 118-128. doi: 10.12461/PKU.DXHX202408101

    6. [6]

      Wei ZhongDan ZhengYuanxin OuAiyun MengYaorong Su . Simultaneously Improving Inter-Plane Crystallization and Incorporating K Atoms in g-C3N4 Photocatalyst for Highly-Efficient H2O2 Photosynthesis. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-0. doi: 10.3866/PKU.WHXB202406005

    7. [7]

      Rui LIUXinjun ZHOUTao WANG . Photocatalytic degradation performance of tetracycline by MOF-74-Mn/g-C3N4 Z-type heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1796-1804. doi: 10.11862/CJIC.20250033

    8. [8]

      Fan FanHao XiuYuting WangYongpeng CuiYajun Wang . Construction of NH2-MIL-125/Na-doped g-C3N4 composite S-scheme heterojunction and its performance in photocatalytic hydrogen peroxide production. Acta Physico-Chimica Sinica, 2026, 42(2): 100143-0. doi: 10.1016/j.actphy.2025.100143

    9. [9]

      Yun ChenDaijie DengLi XuXingwang ZhuHenan LiChengming Sun . Covalent bond modulation of charge transfer for sensitive heavy metal ion analysis in a self-powered electrochemical sensing platform. Acta Physico-Chimica Sinica, 2026, 42(1): 100144-0. doi: 10.1016/j.actphy.2025.100144

    10. [10]

      Weikang WangYadong WuJianjun ZhangKai MengJinhe LiLele WangQinqin Liu . Green H2O2 synthesis via melamine-foam supported S-scheme Cd0.5Zn0.5In2S4/S-doped carbon nitride heterojunction: synergistic interfacial charge transfer and local photothermal effect. Acta Physico-Chimica Sinica, 2025, 41(8): 100093-0. doi: 10.1016/j.actphy.2025.100093

    11. [11]

      Bing LIUHuang ZHANGHongliang HANChangwen HUYinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO2 mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398

    12. [12]

      Yuanqing WangYusong PanHongwu ZhuYanlei XiangRong HanRun HuangChao DuChengling Pan . Enhanced Catalytic Activity of Bi2WO6 for Organic Pollutants Degradation under the Synergism between Advanced Oxidative Processes and Visible Light Irradiation. Acta Physico-Chimica Sinica, 2024, 40(4): 2304050-0. doi: 10.3866/PKU.WHXB202304050

    13. [13]

      Xiaofei ZhangShanhao XuZhiyuan WangLong HeTiangcheng HuangYongming XuYucui BianYike LiHaijun ChenZhongjun Li . Surface doping of graphene into BiOCl for efficient photocatalytic amine coupling under visible light. Acta Physico-Chimica Sinica, 2026, 42(5): 100202-0. doi: 10.1016/j.actphy.2025.100202

    14. [14]

      Zehui JIABin WENShuting ZHANGZhengliang ZHAOHongfei HANChuntao WANGCaimei FAN . Mechanism of carbon quantum dots-modified BiOCl/diatomite composites for ciprofloxacin degradation under visible light irradiation. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 317-330. doi: 10.11862/CJIC.20250199

    15. [15]

      Bo YANGGongxuan LÜJiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346

    16. [16]

      Xinzhe HUANGLihui XUYue YANGLiming WANGZhangyong LIUZhongjian WANG . Preparation and visible light responsive photocatalytic properties of BiSbO4/BiOBr. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 284-292. doi: 10.11862/CJIC.20240212

    17. [17]

      Ke LiChuang LiuJingping LiGuohong WangKai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi4Ti3O12 Coupling with g-C3N4 for Photocatalytic H2O2 Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009

    18. [18]

      Jiayao WangGuixu PanNing WangShihan WangYaolin ZhuYunfeng Li . Preparation of donor-π-acceptor type graphitic carbon nitride photocatalytic systems via molecular level regulation for high-efficient H2O2 production. Acta Physico-Chimica Sinica, 2025, 41(12): 100168-0. doi: 10.1016/j.actphy.2025.100168

    19. [19]

      Qin LiHuihui ZhangHuajun GuYuanyuan CuiRuihua GaoWei-Lin DaiIn situ Growth of Cd0.5Zn0.5S Nanorods on Ti3C2 MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-0. doi: 10.3866/PKU.WHXB202402016

    20. [20]

      Yan KongWei WeiLekai XuChen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO2 Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2307049-0. doi: 10.3866/PKU.WHXB202307049

Metrics
  • PDF Downloads(0)
  • Abstract views(1009)
  • HTML views(89)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return