Citation: WANG Jiaoliang, LONG Liping, XIE Dan. A Coumarin 343 Basded Fluorescent Probe for Fast Sensing of Sulfite Ion[J]. Chinese Journal of Applied Chemistry, ;2016, 33(7): 841-847. doi: 10.11944/j.issn.1000-0518.2016.07.150348 shu

A Coumarin 343 Basded Fluorescent Probe for Fast Sensing of Sulfite Ion

1.
College of Chemistry and Environment Engineering, Hu'nan City University, Yiyang, Hu'nan 413000, China

Corresponding author: WANG Jiaoliang,
Received Date: 28 September 2015
Available Online: 12 January 2016
Fund Project:

The probe, Coumarin 343-SO₂, was readily synthesized from Coumarin 343 and 2-benzothiazole acetonitrile. The structure of this probe was fully characterized by ¹H NMR, ¹³C NMR, MS, and HRMS. The mechanism of this fluorescent probes for SO₃^2- is based on blocking conjugated structure of the benzothiazole and coumarin upon SO₃^2- nucleophilic addition. The probe exhibits excellent water solubility, fast response, high sensitivity, and high selectivity over other biological related species, with the low detection limit at 0.08 μmol/L. In addition, the probe has good cell membrane permeability, and is suitable for fluorescence imaging of SO₃^2- in living cells.
- coumarin 343,
- fluorescence probe,
- sulfite ion,
- cell imaging
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沈阳化工大学材料科学与工程学院沈阳 110142