注册 English

形貌可控卟啉材料的合成及光电性质

杨建东 ,  马蓉 ,  燕翔 ,  王都留 ,  卢小泉

downloadPDF
引用本文: 杨建东, 马蓉, 燕翔, 王都留, 卢小泉. 形貌可控卟啉材料的合成及光电性质[J]. 应用化学, 2016, 33(3): 307-312. doi: 10.11944/j.issn.1000-0518.2016.03.150217 shu
Citation:  YANG Jiandong, MA Rong, YAN Xiang, WANG douliu, LU Xiaoquan. Synthesis of Morphology-controllable Porphyrin Materials and Their Photoelectric Properties[J]. Chinese Journal of Applied Chemistry, 2016, 33(3): 307-312. doi: 10.11944/j.issn.1000-0518.2016.03.150217 shu

形貌可控卟啉材料的合成及光电性质

  • a.

    a. 陇南师范专科学校农林技术学院 甘肃 成县 742500;

  • b.

    b. 甘肃省生物电化学与环境分析重点实验室 兰州 730070

    • 通讯作者: 卢小泉,教授;Tel/Fax:0931-7975276;E-mail:lnszyjd@163.com;研究方向:卟啉电化学及卟啉纳米材料的合成、应用
  • 基金项目:

    国家自然科学基金（21175108) 

    甘肃省自然科学基金（1308RJZK171) 

    甘肃省高等学校科研项目（2013B132) 

    校重点科研项目（2012LSZK01003) 

    博士科研启动项目资助 

摘要: 通过自组装方法制备了一种卟啉材料，并通过调节溶液pH值实现了对其形貌的可控。当pH值较低时形成卟啉棒状结构；当pH值较高时形成卟啉叶片状结构。利用紫外、红外和X衍射仪等多种表征方法对其结构和性质进行了表征。结果表明，在无机酸的作用下，卟啉分子通过π-π、静电作用形成一维结构的J-聚集体；当pH值增加时，氢键的作用占主要作用形成二维片状结构。将此卟啉棒状材料构筑微纳米器件，测试其光电性能，表明对可见光有很好的响应。这种具有光电响应的卟啉材料有望成为微纳电子器件的光电元件。

English

  • 

    1. [1] Liu H B,Xu J L,Li Y J,et al. Aggregate Nanostructures of Organic Molecular Materials[J]. Acc Chem Res,2010,43(12):1496-1508.[1] Liu H B,Xu J L,Li Y J,et al. Aggregate Nanostructures of Organic Molecular Materials[J]. Acc Chem Res,2010,43(12):1496-1508.

    2. [2] Li R J,Hu W P,Liu Y Q,et al. Micro- and Nanocrystals of Organic Semiconductors[J]. Acc Chem Res,2010,43(4):529-540.[2] Li R J,Hu W P,Liu Y Q,et al. Micro- and Nanocrystals of Organic Semiconductors[J]. Acc Chem Res,2010,43(4):529-540.

    3. [3] Wang Z Q,Zheng C J,Liu H,et al. Efficient and Stable Non-doped Deep-blue Organic Light Emitting Diode Based on an Anthracene Derivative[J]. Sci China:Chem,2011,54(4):666-670.[3] Wang Z Q,Zheng C J,Liu H,et al. Efficient and Stable Non-doped Deep-blue Organic Light Emitting Diode Based on an Anthracene Derivative[J]. Sci China:Chem,2011,54(4):666-670.

    4. [4] Imahori H,Umeyama T,Ito S. Large π-Aromatic Molecules as Potential Sensitizers for Highly Efficient Dye-Sensitized Solar Cells[J]. Acc Chem Res,2009,42(11):1809-1818.[4] Imahori H,Umeyama T,Ito S. Large π-Aromatic Molecules as Potential Sensitizers for Highly Efficient Dye-Sensitized Solar Cells[J]. Acc Chem Res,2009,42(11):1809-1818.

    5. [5] Imahori H. Giant Multiporphyrin Arrays as Artificial Light-Harvesting Antennas[J]. J Phys Chem B,2004,108(20):6130-6143.[5] Imahori H. Giant Multiporphyrin Arrays as Artificial Light-Harvesting Antennas[J]. J Phys Chem B,2004,108(20):6130-6143.

    6. [6] Gong X C,Milic T,Drain C M,et al. Preparation and Characterization of Porphyrin Nanoparticles[J]. J Am Chem Soc,2002,124(48):14290-14291.[6] Gong X C,Milic T,Drain C M,et al. Preparation and Characterization of Porphyrin Nanoparticles[J]. J Am Chem Soc,2002,124(48):14290-14291.

    7. [7] Wang L L,Liu H G,Hao J C. Stable Porphyrin Vesicles Formed in Non-aqueous Media and Dried to Produce Hollow Shells[J]. Chem Commun,2009:1353-1355.[7] Wang L L,Liu H G,Hao J C. Stable Porphyrin Vesicles Formed in Non-aqueous Media and Dried to Produce Hollow Shells[J]. Chem Commun,2009:1353-1355.

    8. [8] Sandanayaka S D,Araki Y,Wada T,et al. Size-Controlled Self-Assembled Porphyrin Nanoassemblies Organized by Ethylene Glycol Derivatives for Photophysical Studies[J]. J Phys Chem C,2008,112(49):19209-19216.[8] Sandanayaka S D,Araki Y,Wada T,et al. Size-Controlled Self-Assembled Porphyrin Nanoassemblies Organized by Ethylene Glycol Derivatives for Photophysical Studies[J]. J Phys Chem C,2008,112(49):19209-19216.

    9. [9] Schwab D,Smith D E,Rich C S,et al. Porphyrin Nanorods[J]. J Phys Chem B,2003,107(41):11339-11345.[9] Schwab D,Smith D E,Rich C S,et al. Porphyrin Nanorods[J]. J Phys Chem B,2003,107(41):11339-11345.

    10. [10] Schwab D,Smith D E,Bond-Watts B,et al. Photoconductivity of Self-Assembled Porphyrin Nanorods[J]. Nano Lett,2004,4(7):1261-1265.[10] Schwab D,Smith D E,Bond-Watts B,et al. Photoconductivity of Self-Assembled Porphyrin Nanorods[J]. Nano Lett,2004,4(7):1261-1265.

    11. [11] Wang Z C,Medforth C J,Shelnutt J A. Self-Metallization of Photocatalytic Porphyrin Annotates[J]. J Am Chem Soc,2004,126(51):16720-16721.[11] Wang Z C,Medforth C J,Shelnutt J A. Self-Metallization of Photocatalytic Porphyrin Annotates[J]. J Am Chem Soc,2004,126(51):16720-16721.

    12. [12] Hu J S,Guo Y G,Wan L J,et al. Three-Dimensional Self-Organization of Supramolecular Self-Assembled Porphyrin Hollow Hexagonal Nanoprisms[J]. J Am Chem Soc,2005,127(48):17090-17095.[12] Hu J S,Guo Y G,Wan L J,et al. Three-Dimensional Self-Organization of Supramolecular Self-Assembled Porphyrin Hollow Hexagonal Nanoprisms[J]. J Am Chem Soc,2005,127(48):17090-17095.

    13. [13] Qiu Y F,Chen P L,Liu M H. Evolution of Various Porphyrin Nanostructures via an Oil/Aqueous Medium: Controlled Self-Assembly, Further Organization, and Supramolecular Chirality[J]. J Am Chem Soc,2010,132(28):9644-9652.[13] Qiu Y F,Chen P L,Liu M H. Evolution of Various Porphyrin Nanostructures via an Oil/Aqueous Medium: Controlled Self-Assembly, Further Organization, and Supramolecular Chirality[J]. J Am Chem Soc,2010,132(28):9644-9652.

    14. [14] Cai J H,Wang,J X,Jiang L,et al. Morphology-controlled Self-assembled Nanostructures of a Porphyrin Derivative and their Photoelectrochemical Properties[J]. RSC Adv,2014,8:4063-4068.[14] Cai J H,Wang,J X,Jiang L,et al. Morphology-controlled Self-assembled Nanostructures of a Porphyrin Derivative and their Photoelectrochemical Properties[J]. RSC Adv,2014,8:4063-4068.

    15. [15] Yoon S M,Hwang I C,Choi H Cet,et al. Synthesis of Single-crystal Tetra(4-pyridyl)porphyrin Rectangular Nanotubes in the Vapor Phase[J]. Angew Chem Int Ed,2009,48(14):2506-2509.[15] Yoon S M,Hwang I C,Choi H Cet,et al. Synthesis of Single-crystal Tetra(4-pyridyl)porphyrin Rectangular Nanotubes in the Vapor Phase[J]. Angew Chem Int Ed,2009,48(14):2506-2509.

    16. [16] Zheng W Q,Shan N,Yu L X,et al. UV-Vis, Fluorescence and EPR Properties of Porphyrins and Metalloporphyrins[J]. Dye Pigm,2008,77(1):153-157.[16] Zheng W Q,Shan N,Yu L X,et al. UV-Vis, Fluorescence and EPR Properties of Porphyrins and Metalloporphyrins[J]. Dye Pigm,2008,77(1):153-157.

    17. [17] Choi M Y,Pollard J A,Webb M A,et al. Counterion Dependent Dye Aggregates:Nanorods and Nanorings of Tetra(p-carboxyphenyl)porphyrin[J]. J Am Chem Soc,2003,125(3):810-820.[17] Choi M Y,Pollard J A,Webb M A,et al. Counterion Dependent Dye Aggregates:Nanorods and Nanorings of Tetra(p-carboxyphenyl)porphyrin[J]. J Am Chem Soc,2003,125(3):810-820.

    18. [18] Stone A,Fleischer E B. The Molecular and Crystal Structure of Porphyrin Diacids[J]. J Am Chem Soc,1968,90(11):2735-2748.[18] Stone A,Fleischer E B. The Molecular and Crystal Structure of Porphyrin Diacids[J]. J Am Chem Soc,1968,90(11):2735-2748.

    19. [10] Zhang Y Q,Chen P L,Hu W P,et al. Controllable Fabrication of Supramolecular Nanocoils and Nanoribbons and Their Morphology-Dependent Photoswitching[J]. J Am Chem Soc,2009,131(8):2756-2757.[10] Zhang Y Q,Chen P L,Hu W P,et al. Controllable Fabrication of Supramolecular Nanocoils and Nanoribbons and Their Morphology-Dependent Photoswitching[J]. J Am Chem Soc,2009,131(8):2756-2757.

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  1
  • 文章访问数:  611
  • HTML全文浏览量:  99
文章相关
  • 收稿日期:  2015-06-29
  • 网络出版日期:  2015-10-30
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net