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Citation: LIU Hongjun, ZHOU Tong, SHEN Yuhua, XIE Anjian. Catalytic Performance of Ce(Ⅲ)-barbitone Complex for Bis(p-nitrophenyl) Phosphate Hydrolysis[J]. Chinese Journal of Applied Chemistry, ;2015, 32(12): 1410-1415. doi: 10.11944/j.issn.1000-0518.2015.12.150250 shu

Catalytic Performance of Ce(Ⅲ)-barbitone Complex for Bis(p-nitrophenyl) Phosphate Hydrolysis

1.
School of Chemistry and Chemical Engineering, Anhui University, Hefei 230601, China

Corresponding author: XIE Anjian,
Received Date: 17 July 2015
Available Online: 21 August 2015
Fund Project: 国家自然科学基金(21171001,51372004)资助项目 (21171001,51372004)

Hydrolysis of bis(p-nitrophenyl) phosphate(BNPP) catalyzed by Ce(Ⅲ)-barbitone complex was explored. The results indicate that the Ce(Ⅲ)-barbitone complex exhibits excellent catalytic activity for BNPP hydrolysis. The complex can increase the rate of the BNPP hydrolysis by a factor of 1.52×10⁸ times compared to that of the spontaneous hydrolysis. The effect of temperature and pH on the catalytic activity of Ce(Ⅲ)-barbitone complex for BNPP hydrolysis was also investigated. It is found that the optimal catalytic condition is at 25℃ and pH 8.50.
- Ce(Ⅲ),
- barbitone sodium,
- Ce(Ⅲ)-barbitone complex,
- bis(p-nitrophenyl) phosphate hydrolysis,
- catalytic activity
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