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Citation: CONG Yunling, YANG Chun. Catalytic Selective Synthesis of Mono(2-Methacryloyloxyethyl) Phosphate[J]. Chinese Journal of Applied Chemistry, ;2015, 32(6): 658-665. doi: 10.11944/j.issn.1000-0518.2015.06.140338 shu

Catalytic Selective Synthesis of Mono(2-Methacryloyloxyethyl) Phosphate

CONG Yunling ,
YANG Chun ^,

1.
Jiangsu Collaborative Innovation Center of Biomedical Functional Materials;Jiangsu Key Laboratory of Biofunctional Materials, College of Chemistry and Material Science, Nanjing Normal University, Nanjing 210097, China

Corresponding author: YANG Chun,
Received Date: 4 October 2014
Available Online: 25 December 2014
Fund Project:

Two series of catalysts, HPW/AC and TEAPW/AC, were prepared by impregnating tungstophosphoric acid and[TEAH]₃PW₁₂O₄₀ solution on active carbon. The structure and acidic property of these catalysts were characterized by IR,XRD,N₂adsorption-desorption and NH₃-TPD techniques. Then these catalysts were used to catalyze the synthesis of 2-methacryloyloxyethyl phosphate, a functional phosphate,by using P₂O₅ as phosphorylation agent. These catalysts possess not only high activity but also high selectivity for the mono(2-methacryloyloxyethyl) phosphate since the formations of di(2-methacryloyloxyethyl)phosphate and tri(2-methacryloyloxyethyl) phosphate are restricted by the micropores of catalysts. Under the optimum conditions and on the optimal catalyst, the total ester yield and the selectivity of mono(2-methacryloyloxyethyl) phosphate are 94% and 95%,respectively. The catalyst can be isolated and recycled with high stability. This catalytic process not only avoids using chlorine-containing reagent in the synthesis,but also greatly increases monophoshpate content in the product.
- phosphate,
- polyoxometalates,
- catalysts,
- catalytic synthesis
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