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Citation: ZHANG Dechun, WANG Wen'ge, LIU Hongwei, ZHANG Chanjuan, PENG Huibing. Synthesis of Aromatic Oligosulfonate-Bridged Macrocycles and Selective Recognition of Sn²⁺ and Bi³⁺[J]. Chinese Journal of Applied Chemistry, ;2015, 32(6): 629-635. doi: 10.11944/j.issn.1000-0518.2015.06.140335 shu

Synthesis of Aromatic Oligosulfonate-Bridged Macrocycles and Selective Recognition of Sn²⁺ and Bi³⁺

1.
Department of Materials & Chemical Engineering, Hu'nan Institute of Technology, Hengyang, Hu'nan 421002, China

Corresponding author: WANG Wen'ge,
Received Date: 28 September 2014
Available Online: 28 January 2015
Fund Project: 衡阳市科学技术发展计划项目(2014KS39) (2014KS39)广西师范大学药用资源与药物分子工程教育部重点实验室开放基金(CMEMR2011-03)资助 (CMEMR2011-03)

Three aromatic oligosulfonate-bridged macrocyclic compounds were synthesized using 4,6-dialkoxybenzene-1,3-disulfonyl dichlorides and aromatic diphenol as the starting materials,triethylamine as the acid binding agent,and dichloromethane as the solvent. The products were characterized by IR,¹H NMR,¹³C NMR, MALDI-TOF techniques. The recognition capabilities of aromatic oligosulfonate-bridged macrocyclic compound 5 for 20 metal ions were studied by UV spectroscopy. Compound 5 has certain recognition abilities for Sn²⁺. If Bi³⁺solution is added into compound 5 and Sn²⁺ system,the absorption peak at 325 nm increases greatly in UV spectroscopy because of the synergy effect of Sn²⁺ and Bi³⁺,suggesting that compound 5 has better recognition ability for Bi³⁺than that for Sn²⁺.
- macrocyclic compound,
- sulfonate,
- synthesis,
- UV-Vis spectra,
- metal ion recognition
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Synthesis of Aromatic Oligosulfonate-Bridged Macrocycles and Selective Recognition of Sn2+ and Bi3+

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Synthesis of Aromatic Oligosulfonate-Bridged Macrocycles and Selective Recognition of Sn²⁺ and Bi³⁺