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Citation: ZHENG Jianhua, LIU Jun, XIAO Yao, DAI Linglin, LI Haiyang, TAN Yuxing, FENG Yonglan, JIANG Wujiu, YU Jiangxi, KUANG Daizhia. Synthesis, Crystal Structure, Thermal Stability and DNA Interaction of the Dibutytin Complex Based on Salicylacylhydrazone[J]. Chinese Journal of Applied Chemistry, ;2015, 32(5): 562-569. doi: 10.11944/j.issn.1000-0518.2015.05.140324 shu

Synthesis, Crystal Structure, Thermal Stability and DNA Interaction of the Dibutytin Complex Based on Salicylacylhydrazone

1.
a Key Laboratory of Functional Organometallic Materials of College of Hu'nan Province, Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hu'nan 421008, China;
2.
b College of Chemistry and Chemical Engineering, Hu'nan Normal University, Changsha 410081, China

Corresponding author: KUANG Daizhia,
Received Date: 18 September 2014
Available Online: 12 January 2015
Fund Project: 国家级大学生创新创业训练计划(201310546127) (201310546127)湖南省大学生研究性学习项目(cx1301) (cx1301)湖南省科技计划项目(2013TZ2025,2014NK3086,2014FJ3060) (2013TZ2025,2014NK3086,2014FJ3060)湖南省教育厅基金项目(14C0171)资助 (14C0171)

2-(Salicyloylhydrazone) propionic acid dibutytin complex was synthesized via the reaction of 2-(salicyloylhydrazone) propionic acid with dibutyltin oxide.The complex was characterized by IR,¹H NMR,¹³C NMR spectroscopy,and elemental analysis.The crystal structure was determined to be a tetragonal system by single crystal X-ray diffraction.The crystal structure of the complex belongs to a centrosymmetric structure mode with a four-member central Sn₂O₂ unit,in which the central Sn atom is seven-coordinated in a distorted pentagonal pyramid configuration.The complex is stable below 103℃ according to thermal analysis.The interaction between the complex and Herring sperm DNA was studied by UV spectroscopy,ethidium bromide(EB) fluorescent probe and viscosity,and the results suggest the intercalation interaction between the complex and Herring sperm DNA.
- organotin complex,
- synthesis,
- crystal structure,
- thermal stability,
- DNA
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