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Citation: WU Qiong, XING Na, MA Xitong, XU Liting, XING Yongheng. Lactic Acid Promoted Cyclohexane Oxidation with Ammonium Paramolybdate[J]. Chinese Journal of Applied Chemistry, ;2015, 32(1): 85-92. doi: 10.11944/j.issn.1000-0518.2015.01.140071 shu

Lactic Acid Promoted Cyclohexane Oxidation with Ammonium Paramolybdate

1.
College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China

Corresponding author: XING Na,
Received Date: 10 March 2014
Available Online: 15 May 2014
Fund Project: 国家自然科学基金(21306073,21371086) (21306073,21371086)大连市优秀青年科学技术基金(2012J21DW007)资助项目 (2012J21DW007)

Cyclohexane oxidation is one of the most important industrial reactions. In order to find more efficient and cheap catalysts for this reaction,we studied the catalytic activity of ammonium paramolybdate (APM). By GC analysis,we focus on the effects of the species and the amount of the acids on the reactivity. Compared with nitric acid,lactic acid is more effective for the oxidation of cyclohexanol to cyclohexanone,and thus improve the TON(turn over number) value of the target products from 124 to 161. Furthermore,we propose a possible reaction mechanism of this new way for green oxidation of cyclohexane.
- ammonium paramolybdate,
- lactic acid,
- nitric acid,
- cyclohexane oxidation,
- mechanism
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