化学计量学辅助三维室温磷光法快速测定大气污染源样品中苊含量

引用本文: 邓伟, 卿湘东, 陈铭, 吴康佳, 雷坚志, 陈畅亚, 许素文, 李双双, 文瑾, 申湘忠. 化学计量学辅助三维室温磷光法快速测定大气污染源样品中苊含量[J]. 分析化学, 2018, 46(9): 1438-1445. doi: 10.11895/j.issn.0253-3820.181151 shu

Citation: DENG Wei, QING Xiang-Dong, CHEN Ming, WU Kang-Jia, LEI Jian-Zhi, CHEN Chang-Ya, XU Su-Wen, LI Shuang-Shuang, WEN Jin, SHEN Xiang-Zhong. Chemometrics-assisted Three-dimensional Room Temperature Phosphorescence for Rapid Quantitative Determination of Acenaphthene Contents in Air-pollution Samples[J]. Chinese Journal of Analytical Chemistry, 2018, 46(9): 1438-1445. doi: 10.11895/j.issn.0253-3820.181151 shu

化学计量学辅助三维室温磷光法快速测定大气污染源样品中苊含量

邓伟 ^1, ,
卿湘东 ^1, ,
陈铭 ^1, ,
吴康佳 ^1, ,
雷坚志 ^2, ,
陈畅亚 ^1, ,
许素文 ^1, ,
李双双 ^1, ,
文瑾 ^1, ,
申湘忠 ^1,

1.
湖南人文科技学院, 材料与环境工程学院, 精细陶瓷与粉体材料湖南省重点实验室, 娄底 417000;
2.
娄底市环境保护局环境监测站, 娄底 417000
基金项目:
本文系国家自然科学基金项目（No.21707032）、湖南省教育厅科学研究重点项目（No.16A109）和湖南人文科技学院校级国家培育基金项目（No.2016PY04）资助

摘要: 建立了基于交替三线性分解的化学计量学辅助三维室温磷光法（ATLD-TRTP）快速准确检测大气污染源样品中多环芳烃苊（ACE）的方法。对采集的大气污染源，如餐厨油污、油烟气和烟囱灰等样品，经过简单的样品预处理后，采用荧光光谱仪的磷光模式进行测量，并对获得的激发发射矩阵三维磷光数阵采用ATLD算法进行分解。在n=5时，获得ACE的平均回收率分别为90.5%±7.9%、99.4%±6.1%和101.4%±10.9%，预测均方根误差（RMSEP）分别为0.25、0.12和0.20 μg/mL，检出限（LOD）分别为39.2、18.9和31.0 ng/mL。结果表明，ATLD-TRTP方法能够在背景干扰共存下，快速检测大气污染源样品中ACE的含量，且方法准确、绿色环保，为研究大气颗粒物中PAHs的来源提供了一种很有潜力的分析手段。

关键词:

English

Chemometrics-assisted Three-dimensional Room Temperature Phosphorescence for Rapid Quantitative Determination of Acenaphthene Contents in Air-pollution Samples

1.
Hunan Provincial Key Laboratory of Fine Ceramics and Powder Materials, School of Materials and Environmental Engineering, Hunan University of Humanities, Science and Technology, Loudi 417000, China;
2.
Loudi Environment Protection Agency, Environmental Monitoring Station, Loudi 417000, China
Received Date: 10 March 2018
Revised Date: 05 July 2018
Fund Project:
This work was supported by the National Natural Science Foundation of China (No.21707032), the Research Foundation of Education Bureau of Hunan Province, China (No. 16A109) and the School-level Supports for National Foundation Cultivation of Hunan University of Humanities, Science and Technology, China (No.2016PY04).

Abstract: A new method based on alternating trilinear decomposition assisted three-dimensional room temperature phosphorescence (ATLD-TRTP) was developed for fast quantitative determination of acenaphthene (ACE) contents in samples of air-pollution source. The contents of ACE in air-pollution source samples, such as greasy dirt, oil smoke and flue dust in Loudi city were detected after simple sample pretreatment. Using ATLD algorithm (n=5), the average recoveries of ACE were 90.5%±7.9%, 99.4%±6.1% and 101.4%±10.9%, respectively, the root-mean-square errors of prediction (RMSEP) were 0.25, 0.12 and 0.20 μg/mL, respectively, and the limits of detection (LOD) were 39.2, 18.9 and 31.0 ng/mL, respectively. The results showed that the ATLD-TRTP method was suitable for the determination of ACE in air-pollution source samples even in the presence of uncalibrated interferents.

Key words:

1. [1]
  Peltonen K, Kuljukka T. J. Chromatogr. A,1995,710(1):93-108
2. [2]
  ZHAO Guo-Dong. Environ. Stu. Monit.,2016,29(4):40-44 赵国栋.环境研究与监测,2016,29(4):40-44
3. [3]
  HAO Liang, WU Da-Peng, GUAN Ya-Feng. Chinese Journal of Chromatography,2014,32(9):906-912 郝亮, 吴大朋, 关亚风.色谱,2014,32(9):906-912
4. [4]
  YAO Run-Sheng, XUE Yong-Qiang, WANG Zhi-Zhong, CUI Zi-Xiang. Coal Convers.,2010,33(1):86-88 姚润生, 薛永强, 王志忠, 崔子祥.煤炭转化,2010,33(1):86-88
5. [5]
  LUAN Li-Xin, ZHU Jing, ZHANG Ping, TANG Jun. Chem. Eng.,2008,151(4):25-26 栾利新, 朱静, 张萍, 唐军.化学工程师,2008,151(4):25-26
6. [6]
  LI Yao-Qun, SHI Ning, QING Fang, HUANG Xian-Zhi. Chem. J. Chinese Universities,1997,18(4):538-540 李耀群, 时宁, 钱方, 黄贤智.高等学校化学学报,1997,18(4):538-540
7. [7]
  Simko P. J. Chromatogr. B,2002,770(1-2):3-18
8. [8]
  RAO Zhu, LI Song, HE Miao, SU Jing. Chinese J. Anal. Chem.,2007,35(7):954-958 饶竹, 李松, 何淼, 苏劲.分析化学,2007,35(7):954-958
9. [9]
  Acimovic D D, Nikolic Z M, Tosic M S, Milovanovic D S, Nikolic V M, Brdaric T P, Marceta-Kaninski M P. J. Hazard. Mater.,2017,325:271-278
10. [10]
  Ni Y N, Mei M H,Kokot S. Anal. Chim. Acta,2012,712(27):37-44
11. [11]
  Santos L O, dos Anjos J P, Ferreira S L C, de Andrade J B. Microchem. J.,2017,133:431-440
12. [12]
  Gao Z Y, Jiang W S, Sun D, Xie Y, Chen Z L, Yu L J, Xie S Y, Huang R B, Zheng L S. Talanta,2010,81(1-2):48-54
13. [13]
  ZHU Ruo-Hua, XU Wen-Ting, WANG Wei. Chinese J. Anal. Lab.,2007,26(4):114-122 朱若华, 徐文婷, 王伟.分析实验室,2007,26(4):114-122
14. [14]
  Carretero A S, Blanco C C, Gutiérrez A F. Anal. Chim. Acta,1997,353:337-344
15. [15]
  LONG Wen-Qing.J. Anal. Sci.,2003,19(3):258-260 龙文清.分析科学学报,2003,19(3):258-260
16. [16]
  JIA Li-Hua, GUO Xiang-Feng, QIAN Xu-Hong. Chinese J. Anal. Chem.,2004,32(6):837 贾丽华, 郭祥峰, 钱旭红.分析化学,2004,32(6):837
17. [17]
  AN Zhao-Qi, LI Dong-Xia, YU Jian-Min, YAN Gui-Qin. J. Anal. Sci.,2017,33(4):467-472 安昭琦, 栗东霞, 于建敏, 闫桂琴.分析科学学报,2017,33(4):467-472
18. [18]
  Yang J, Zhen X, Wang B, Gao X M, Ren Z C, Wang J Q, Xie Y J, Li J R, Peng Q, Pu K Y, Li Z. Nat. Commun.,2018,9(1):840-849
19. [19]
  QING Xiang-Dong, WU Hai-Long, LI Yuan-Na, YU Ru-Qin. Sci. Sin. Chem.,2010,40(11):1655-1663 卿湘东, 吴海龙, 李元娜, 俞汝勤.中国科学:化学,2010,40(11):1655-1663
20. [20]
  Ni Y N, Zhu R R, Kokot S. Analyst,2011,136(22):4794-4801
21. [21]
  QING Xiang-Dong, WU Hai-Long, GU Hui-Wen, YIN Xiao-Li, WEN Jin, SHEN Xiang-Zhong, YU Ru-Qin. Acta Chim. Sinica,2016,74(3):277-284 卿湘东, 吴海龙, 谷惠文, 尹小丽, 文瑾, 申湘忠, 俞汝勤.化学学报,2016,74(3):277-284
22. [22]
  WANG Yu, WU Hai-Long, YU Yong-Jie, WANG Jian-Yao, ZHAO Juan, CHEN Yao, ZHANG Xi-Hua, YU Ru-Qin. Sci. Sin. Chem.,2012,42(8):1226-1233 王予, 吴海龙, 于永杰, 王建瑶, 赵娟, 陈瑶, 张喜华, 俞汝勤.中国科学:化学,2012,42(8):1226-1233
23. [23]
  Wu H L,Shibukawa M, Oguma K. J. Chemom.,1998,12(1):1-26
24. [24]
  NIE Chong-Chong, WU Hai-Long, QING Xiang-Dong, LI Yuan-Na, LI Yong, XU Hui, ZHU Shao-Hua, YU Ru-Qin. J. Environ. Chem.,2011,30(11):1837-1843 聂重重, 吴海龙, 卿湘东, 李元娜, 李勇, 许慧, 朱绍华, 俞汝勤.环境化学,2011,30(11):1837-1843
25. [25]
  LI Long-Di, MOU Lan, CHEN Xiao-Kang. Chem. J. Chinese Universities,2000,21(7):1040-1043 李隆弟, 牟兰, 陈小康.高等学校化学学报,2000,21(7):1040-1043
26. [26]
  Bro R, Kiers H A L.J. Chemom.,2003,17(5):274-286
27. [27]
  Olivieri A C, Faber N M.Chemom. Intell. Lab. Syst.,2004,70(1):75-82
28. [28]
  Olivieri A C.Chem. Rev.,2014,114(10):5358-5378
29. [29]
  Olivieri A C.Anal. Chem.,2005,77(15):4936-4946
30. [30]
  HJ 646-2013. Ambient Air and Stationary Source Emissions-Determination of Gas and Particle-Phase Polycyclic Aromatic Hydrocarbons with Gas Chromatography/Mass Spectrometry. Ministry of Environmental Protection of the People's Republic of China 环境空气和废气-气相和颗粒物中多环芳烃的测定:气相色谱-质谱法.中华人民共和国国家环境保护标准. HJ646-2013
31. [31]
  ZHANG Guo-An, WANG Fu, LI Gui-Zhen, XIE Yan, DU Xiang-Dong. J. East China University Sci. Tech.,2001,27(2):186-190 张国安, 王复, 李桂贞, 谢焰, 杜向东.华东理工大学学报,2001,27(2):186-190
32. [32]
  HJ 647-2013. Ambient Air and Stationary Source Emissions-Determination of Gas and Particle-Phase Polycyclic Aromatic Hydrocarbons-High Performance Liquid Chromatography. Ministry of Environmental Protection of the People's Republic of China 环境空气和废气-气相和颗粒物中多环芳烃的测定:高效液相色谱法.中华人民共和国国家环境保护标准, HJ647-2013

扫一扫看文章

计量

PDF下载量: 8
文章访问数: 430
HTML全文浏览量: 27

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

化学计量学辅助三维室温磷光法快速测定大气污染源样品中苊含量

English

Chemometrics-assisted Three-dimensional Room Temperature Phosphorescence for Rapid Quantitative Determination of Acenaphthene Contents in Air-pollution Samples

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

化学计量学辅助三维室温磷光法快速测定大气污染源样品中苊含量

English

Chemometrics-assisted Three-dimensional Room Temperature Phosphorescence for Rapid Quantitative Determination of Acenaphthene Contents in Air-pollution Samples

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs