光子晶体纤维素膜检测二氧化硫气体

引用本文: 王一飞, 周丽君, 杨吉, 孟子晖, 薛敏, 邱丽莉, 刘学涌, 何璇, 钟发春. 光子晶体纤维素膜检测二氧化硫气体[J]. 分析化学, 2018, 46(9): 1472-1478. doi: 10.11895/j.issn.0253-3820.181044 shu

Citation: WANG Yi-Fei, ZHOU Li-Jun, YANG Ji, MENG Zi-Hui, XUE Min, QIU Li-Li, LIU Xue-Yong, HE Xuan, ZHONG Fa-Chun. Detection of Sulfur Dioxide Using Cellulose Photonic Crystal Membrane[J]. Chinese Journal of Analytical Chemistry, 2018, 46(9): 1472-1478. doi: 10.11895/j.issn.0253-3820.181044 shu

光子晶体纤维素膜检测二氧化硫气体

王一飞 ^1, ,
周丽君 ^1, ,
杨吉 ^1, ,
孟子晖 ^1, ,
薛敏 ^1, ,
邱丽莉 ^1, ,
刘学涌 ^2, ,
何璇 ^2, ,
钟发春 ^2,

1.
北京理工大学化学与化工学院, 北京 100081;
2.
中国工程物理研究院化工材料研究所, 绵阳 621900
基金项目:
本文系国家自然科学基金项目（Nos.U1530141，21375009）和北京理工大学基础研究基金项目（No.20141642005）资助

摘要: 二氧化硫作为重要的大气污染源一直备受关注，但是目前的检测方法操作复杂，不利于现场实时监测。本研究采用垂直沉降法制备了高度有序的紧密堆积型三维聚甲基丙稀酸甲酯（PMMA）胶体阵列，并且利用甲基纤维素（MC）和羧甲基纤维素（CMC）作为三维阵列的载体制备了蛋白石型和反蛋白石型纤维素膜。这些纤维素光子晶体膜结构色明亮，反射峰明显且峰型良好。二甲基亚砜（DMSO）对二氧化硫有较强溶解性能，负载了DMSO的反蛋白石膜吸附二氧化硫气体后结构色由红色变为无色，实现了裸眼检测，且检测限低于国家二级防护浓度（7898 mg/m³），为大气中二氧化硫现场检测提供了一种重复性好、便捷高效的方法。

关键词:

English

Detection of Sulfur Dioxide Using Cellulose Photonic Crystal Membrane

1.
School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China;
2.
Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang 621900, China
Received Date: 21 January 2018
Revised Date: 25 June 2018
Fund Project:
This work was supported by the National Natural Science Foundation of China (Nos. U1530141, 21375009).

Abstract: Sulfur oxide is one of the most concerned air pollutants. Current detection technique for sulfur oxide is complicated, and in situ techniques are in highly demand. Herein, 3D polymethyl methacylate colloidal arrays which were embedded inside methylcellulose (MC) and carboxymethylcellulose (CMC) membrane were prepared, and then opal and inverse opal cellulose photonic crystal with bright structural color were obtained. After treated with dimethyl sulfoxide (DMSO), the structural color of the inverse opal cellulose photonic crystal turned from red to colorless, and the naked-eye detection for SO₂ was achieved with a detection limit of lower than 7898 mg/m³. This technique might be useful for the in situ detection of SO₂ pollutant in the air.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

光子晶体纤维素膜检测二氧化硫气体

English

Detection of Sulfur Dioxide Using Cellulose Photonic Crystal Membrane

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

光子晶体纤维素膜检测二氧化硫气体

English

Detection of Sulfur Dioxide Using Cellulose Photonic Crystal Membrane

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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