Citation: HE Hong-Mei, WU Min, ZHANG Chun-Rong, YU Jian-Zhong, ZHAO Hua, ZHU Ya-Hong, HE Kai-Yu, ZHANG Chang-Peng, CAI Lei-Ming, XU Ling-Ying, TANG Qing-Hong. Residue Analysis of SIOC0426 in Environmental Samples and Its Degradation in Soil[J]. Chinese Journal of Analytical Chemistry, ;2017, 45(10): 1564-1570. doi: 10.11895/j.issn.0253-3820.170338 shu

Residue Analysis of SIOC0426 in Environmental Samples and Its Degradation in Soil

1.
State Key Lab Breeding Base for Zhejiang Sustainable Plant Pest Control, MOA Key Lab for Pesticide Residue Detection;Institute of Quality and Standard for Agro-products, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, China;2 Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Received Date: 27 May 2017
Revised Date: 4 August 2017

Fund Project: This work was supported by the National Natural Science Foundation of China (No. 31401772) and the National Key Research and Development Program of China (No.2016YFD0200204-4).

An analytical method based on ultra performance liquid chromatography-tandem mass spectrometry was developed for the determination of SIOC0426 residues in environment samples (soil, sediment and water). The fate of SIOC0426 in three kinds of soils was also evaluated. The target compound was extracted with acetonitrile, cleaned up by C₁₈ cartridge, and analyzed by gradient ultra performance liquid chromatography-tandem mass spectrometry with electrospray ionization under positive mode (ESI+) using a UPLC BEH C₁₈ column. The method was validated using fortified soil, sediment and water. Mean recoveries of SIOC0426 at three spiked levels (0.005, 0.05 and 2.0 mg/kg) ranged from 87% to 106% with relative standard deviations of 2.8%-8.0%. Limits of quantification (LOQs) of SIOC0426 in soil (sediment) and water were 0.2 μg/kg and 0.2 μg/L, respectively. Linear calibration functions with correlation coefficients R²>0.9999 were obtained in the concentration range of 0.5-20 μg/L. This method was applied to the analysis of SIOC0426 residues in soil degradation samples. The results showed that the half-life of SIOC0426 ranged from 1.72 days to 28.2 days in three kinds of soils under aerobiotic conditions. While, the half-life of SIOC0426 ranged from 2.93 days to 31.4 days in three kinds of soils under anaerobic conditions. The degradation speed of SIOC0426 under aerobiotic conditions was faster than that under anaerobic conditions in the same soil. And the degradation speed of SIOC0426 in soils may be connected with the pH value of soils, cation exchange capacity and soil texture.
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1.
沈阳化工大学材料科学与工程学院沈阳 110142