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Citation: ZHU Rong, ZHANG Hong-Hai, YANG Gui-Peng. Determination of Volatile Sulfur Compounds in Seawater and Atmosphere[J]. Chinese Journal of Analytical Chemistry, ;2017, 45(10): 1504-1510. doi: 10.11895/j.issn.0253-3820.170291 shu

Determination of Volatile Sulfur Compounds in Seawater and Atmosphere

1.
College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China;2 Laboratory for Marine Ecology and Environmental Science, Qingdao National Laboratory for Marine Science and Technology, Qingdao 266071, China

Received Date: 8 May 2017
Revised Date: 8 August 2017

Fund Project: This work was supported by the National Key Research and Development Program of China (No. 2016YFA0601301) and the National Natural Science Foundation of China (Nos. 41576073, 41320104008).

Volatile sulfur compounds (VSCs) in the marine environment has significant implications for global climate change. In the present study, a gas chromatographic analytical method was set up to determine the concentrations of VSCs in seawater and atmosphere, and the optimized experimental conditions were established. For the analysis of VSCs in atmosphere, multistage traps and gas chromatography-mass spectrometry (GC-MS) were used, with the precisions of 7.7%-15.1% and the detection limits of 0.23-4.7 ng. Moreover, for the analyses of VSCs in seawater, pre-concentration and gas chromatography coupled with flame photometric detector (GC-FPD) were utilized, with the precisions of 3.5%-5.3% and the detection limits of 2.5-3.5 ng. This method was applied to analyze the VSCs in Qingdao coastal seawater and atmosphere, and the average concentrations of carbonyl sulfide, dimethyl sulfide and carbon disulfide in the seawater were (268±58), (1264±278), (19±2) pmol/L, and (543±39), (29±9), (56±20) (×10^-12, V/V) in the atmosphere, respectively.
- Volatile sulfur compounds,
- Carbonyl sulfide,
- Dimethyl sulfide,
- Carbon disulfide
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