Citation: YU Guang-Qin, YUAN Ze-Li, YANG Jie, WU Qing, HU Qing-Hong, ZHANG Ming-Qin, JIANG Bo, WEI Gang. Synthesis and Application of a Spirobenzopyran-based Probe for Detection of Cu²⁺ and Hydrazine[J]. Chinese Journal of Analytical Chemistry, ;2016, 44(10): 1495-1503. doi: 10.11895/j.issn.0253-3820.160394 shu

Synthesis and Application of a Spirobenzopyran-based Probe for Detection of Cu²⁺ and Hydrazine

YU Guang-Qin ^1, ,
YUAN Ze-Li ¹ ,
YANG Jie ¹ ,
WU Qing ¹ ,
HU Qing-Hong ¹ ,
ZHANG Ming-Qin ¹ ,
JIANG Bo ¹ ,
WEI Gang ²

1.
School of Pharmacy, Zunyi Medical University Zunyi 563003, China;
2.
CSIRO Manufacturing Flagship, PO Box 218, Lindfield, NSW 2070, Australia

Received Date: 24 May 2016
Revised Date: 16 August 2016

Fund Project: This work was supported by the National Natural Science Foundation of China (No. 81360471)

Figures(11)

A spirobenzopyran-based probe (L) for the detection of Cu²⁺ and hydrazine was synthesized by using 4-methyl-2,6-diformylphenol and 1,3,3-trimethyl-2-methyleneindoline, and its structure was characterized by ¹H NMR, ¹³C NMR, FT-IR and H RMS(ESI-MS). The recognition properties of the probe L with nineteen kinds of metral ions, eighteen kinds of anion ions and nine kinds of amine compounds had been investigated in Tris-HCl(pH=7.40)-ethanol solution (1:1, V/V) by UV-Vis, fluorescence spectrophotometry, ¹H NMR titration and MS. The results showed that the probe L exhibited higher selectivity and sensitivity towards Cu²⁺ and hydrazine over other interfering objects in Tris-HCl(pH=7.40)-ethanol solution(1:1, V/V), and the color changes of L caused by Cu²⁺ and hydrazine could be observed by naked eyes. Thus, L could be loaded as test paper for detecting Cu²⁺ at μmol/L level in water solution by naked eyes. Notably, probe L could be used to detect hydrazine in liquid and gas state with different concentrations by detecting the color changes from readily prepared TLC plates. On the basis of this, the probe L was used in the determination of Cu²⁺ in the water and drug samples with recoveries of 83.5%-111.0% and RSD of 4.0%. The results showed that this probe L had potential applications in the monitoring of environmental pollution and the analysis of Cu²⁺ and hydrazine in drug.
- Spirobenzopyran,
- Probe,
- Copper(Ⅱ),
- Hydrazine,
- Synthesis
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Synthesis and Application of a Spirobenzopyran-based Probe for Detection of Cu2+ and Hydrazine

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Synthesis and Application of a Spirobenzopyran-based Probe for Detection of Cu²⁺ and Hydrazine