Citation: LIU Bao-Feng, GAO Feng-Zhang, FANG Qiang, WANG Li. Determination of Red Freesia Flower Volatiles with Indirect Headspace Solid Phase Microextraction Coupled to Gas Chromatography and Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry, ;2016, 44(3): 444-450. doi: 10.11895/j.issn.0253-3820.150831 shu

Determination of Red Freesia Flower Volatiles with Indirect Headspace Solid Phase Microextraction Coupled to Gas Chromatography and Mass Spectrometry

1.
Institute of Genetics and Cytology, Northeast Normal University, Changchun 130024, China

Corresponding author: WANG Li,
Received Date: 20 October 2015
Available Online: 17 December 2015
Fund Project: 本文系国家自然科学基金(Nos.31170276,31300271)资助项目 (Nos.31170276,31300271)

A method was established for the analysis of red Freesia flower volatiles by indirect headspace solid phase microextraction (HS-SPME). The gas collecting tube was used to enrich flower volatiles, and adsorbing material was resolved in the extraction solution. Then, the adsorbing material was analyzed by HS-SPME. The experimental conditions for the quantification of major flower volatiles (linalool, terpineol, ionone and dihydrogen-ionone) were optimized. Florisil was used as adsorbent, with water-methanol solution (9:1, V/V) and 0.6 mol/L hydrochloric acid as the extraction solution. The thermal desorption temperature was 70℃ and the extraction time was 25 min. The results showed that the concentration range of linear relationship for linalool and terpineol (R²≥0.981) was 1-100 μg/mL, with detection limits of 0.05 and 0.10 μg, respectively, and 0.5-50 μg/mL for dihydro ionone and ionone (R²≥0.988) with a detection limit of 0.02 μg.
- Red Freesia,
- Flower volatiles,
- Indirect headspace solid phase microextraction,
- Gas chromatography-mass spectrometry
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沈阳化工大学材料科学与工程学院沈阳 110142