Citation: NING Lu-Sheng, XU Ming, GUO Cheng-An, ZHAO Peng, WEN Lu-Hong, ZHANG Xin-Rong. Study of Single Electrode Dielectric Barrier Discharge Ion Source[J]. Chinese Journal of Analytical Chemistry, ;2016, 44(2): 252-257. doi: 10.11895/j.issn.0253-3820.150784 shu

Study of Single Electrode Dielectric Barrier Discharge Ion Source

1.
¹ The Research Institute of Advanced Technologies, Ningbo University, Ningbo 315211, China;
2.
² Department of Chemistry, Tsinghua University, Beijing 100084, China

Corresponding author: ZHAO Peng,
Received Date: 9 October 2015
Available Online: 13 November 2015
Fund Project: 本文系宁波大学学校人才工程项目(No.ZX2014000824) (No.ZX2014000824)宁波市自然科学基金(No.2014A610158) (No.2014A610158)

Dielectric barrier discharge ion source is an ambient ion source. Coupled with its advantages of solvent-free method, extensive application scope and easy miniaturization, it has attracted widespread attention. The conventional dielectric barrier discharge ion source uses surface double electrode or needle-ring electrode designs. The grounded electrode of the former can weaken ionization head energy formed in strong electric field of helium ionization, and shorten the distance of plasma beam. The electric field of the latter mainly concentrates on the peak of the needle electrode, which can weaken the energy of ionization head and make the length of the plasma beam shorter than the surface double electrode. In this work, the influencing factors of discharge were analyzed, and the electric field was adjusted by changing the shape of the electrode and increasing insulation medium components, thus forcing the strong electric field to focus on one side of the electrode, which could avoid the reflux discharge phenomenon and achieve stable and efficient plasma beam. The maximum length of plasma beam could reach more than 8 cm. On the basis, a single electrode dielectric barrier discharge ion source (DBDI), mainly composed of inert carrier gas, high voltage electrode, insulation tube, gas control and temperature control parts, was developed. Using the new type of ion source, the liquid sample of caffeine and the solid tablets of acetaminophen were analyzed by DBDI-MS. The correlation coefficient of the caffeine quantitative curve was 99.66%, and the signal to noise ratio of 100 μg/L was 23. The main component of the acetaminophen was C₈H₉NO₂ that could be rapidly detected in the mass spectrum, and the response intensity was 1.26×10⁶. The results showed that the new type of ion source could realize the quantitative and rapid in situ analysis of the sample.
- Single electrode,
- Dielectric barrier discharge,
- Ion source
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