Citation: XU Neng-Bin, FENG Jia-Yong, ZHU Li-Bo, QIAN Fei-Zhong, XU Li-Hong, CHEN Zhong-Quan, WANG Sheng-Le. Comparison of Two Ionic Liquid Dispersive Liquid-Liquid Microextraction Approaches for Determination of Acrylamide, Caprolactam, Benzidine and Aniline in Water[J]. Chinese Journal of Analytical Chemistry, ;2016, 44(1): 117-123. doi: 10.11895/j.issn.0253-3820.150411 shu

Comparison of Two Ionic Liquid Dispersive Liquid-Liquid Microextraction Approaches for Determination of Acrylamide, Caprolactam, Benzidine and Aniline in Water

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¹ Ningbo Environmental Monitoring Center, Ningbo 315012, China;
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² Shaoxing Environmental Monitoring Center, Shaoxing 312000, China

Corresponding author: FENG Jia-Yong,
Received Date: 19 May 2015
Available Online: 16 September 2015
Fund Project: 本文系国家高技术研究发展计划(No.2011AA060603) (No.2011AA060603)环保部科研公益性行业专项(No.201209016) (No.201209016)宁波市自然科学基金(No.2011A610087)资助 (No.2011A610087)

A comparative study of the performance of ultrasound-assisted (UA), and temperature-controlled (TC) ionic liquid (IL) dispersive liquid-liquid microextraction (IL-DLLME) was presented. Various parameters that affected extraction efficiency were evaluated. UA-IL-DLLME was found to provide the better extraction efficiency. After adjustment of pH, the water sample was mixed with[C₈MIM] [PF₆] and acetonitrile, then was extracted under ultrasound-assisted/temperature-controlled conditions. The mixture was then centrifuged, separated, and analyzed by UPLC-MS/MS. Under the optimal conditions, the calibration curves were linear well with correlation coefficient ranged from 0.9969-0.9991, and the limits of detection of acrylamide, caprolactam, aniline and benzidine were in the range of 5.0-50 ng/L. At the spiked levels of three concentrations, the average recoveries were between 81.5% and 106.9%. The relative standard deviations of run-to-run and day-to-day were 7.6%-15.7% and 14.7%-22.9%, respectively. The developed method is simple and sensitive, and was suitable for rapid analysis of large quantities of samples.
- Acrylamide,
- Caprolactam,
- Benzidine,
- Aniline,
- Ultra performance liquid chromatography tandem mass spectrometry,
- Dispersive liquid-liquid microextraction,
- Ionic liquid,
- Ultrasound-assisted
1. [1]
  1 ZHU Li-Bo, XU Neng-Bin, FENG Jia-Yong, QIAN Fei-Zhong, CHEN Zhong-Quan. Chinese J. Anal. Chem., 2013,41(4):594-597 朱丽波, 徐能斌, 冯加永, 钱飞中, 陈钟佺.分析化学,2013,41(4):594-597
2. [2]
  2 CAO Jiang-Ping, XIE Qi-Long, ZHOU Ji-Hai, YI Zong-Hui. Journal of Instrumental Analysis, 2015, 34(5):616-624 曹江平, 解启龙, 周继梅, 易宗慧.分析测试学报,2015,34(5):616-624
3. [3]
  3 ZANG Xiao-Huan, WU Qiu-Hua, ZHANG Mei-Yue, XI Guo-Hong, WANG Zhi. Chinese J Anal Chem., 2009,37(2):161-168 臧晓欢, 吴秋华, 张美月, 郗国宏, 王志.分析化学,2009,37(2):161-168
4. [4]
  4 Rezaee M, Assadi Y, Milani Hosseini M R, Aghaee E, Ahmadi F, Berijani S. J. Chromatogr. A, 2006,1116:1-9
5. [5]
  5 Anderson J L, Armstrong D W, Wei G T. Anal. Chem., 2006,78:2893-2902
6. [6]
  6 He L J, Zhang W Z, Zhao L, Liu X, Jiang S X. J. Chromatogr. A, 2003,1007:39-45
7. [7]
  7 Aguilera-Herrador E, Lucena R, Crdenas S, Valcárcel M. Trends Anal. Chem., 2010,29:602-616
8. [8]
  8 Tan Z Q, Liu J F, Pang L. Trends Anal. Chem., 2012,39:218-227
9. [9]
  9 Zhou Q, Bai H, Xie G, Xiao J. J. Chromatogr. A, 2008,1177(1):43-49
10. [10]
  10 ZHANG Yao-Hai, ZHANG Xue-Lian, ZHAO Qi-Yang, CHEN Wei-Jun, WANG Cheng-Qiu, CHEN Ai-Hua, JIAO Bi-Ning. Chinese J Anal Chem, 2014,42(10):1434-1440 张耀海, 张雪莲, 赵其阳, 陈卫军, 王成秋, 陈爱华, 焦必宁.分析化学,2014,42(10):1434-1440
11. [11]
  11 Zhou Q, Zhang X, Xiao J. J. Chromatogr. A, 2009,1216(1):4361-4365
12. [12]
  12 Zhang J, Gao H, Peng B, Li S, Zhou Z. J. Chromatogr. A, 2011,1218(38):6621-6629
13. [13]
  13 Vázquez M, Vázquez P, Galera M, Gar-cía M. J. Chromatogr. A, 2014,1356:1-9
14. [14]
  14 XIONG Jie, QIAN Shu, XIE Yong-Hong, XIE Zhen-Bang, LI Hai-Xia. Chinese J. Anal. Chem., 2014,42(1):93-98 熊杰, 钱蜀, 谢永洪, 谢振伟, 李海霞.分析化学,2014,42(1):93-98
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沈阳化工大学材料科学与工程学院沈阳 110142