Citation: MA Zhen-Hua, WANG Hui-Cai, YAO Xiao-Xia, LIU Ming-Qiang, MA Yu-Qiang. Simultaneous Determination of Catechol and Hydroquinone Based on Fluorinated Graphite Modified Glassy Carbon Electrode[J]. Chinese Journal of Analytical Chemistry, ;2015, 43(12): 1906-1912. doi: 10.11895/j.issn.0253-3820.150372 shu

Simultaneous Determination of Catechol and Hydroquinone Based on Fluorinated Graphite Modified Glassy Carbon Electrode

1.
¹ School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, China;

Corresponding author: WANG Hui-Cai,
Received Date: 6 May 2015
Available Online: 14 October 2015
Fund Project: 本文系天津市与科技部中小企业创新基金(Nos.13ZXCXSY14200,13C26211200305) (Nos.13ZXCXSY14200,13C26211200305)天津市科技特派员目(No.14JCTPJC00500)以及国家自然科学基金(No.30900325)资助项目 (No.14JCTPJC00500)以及国家自然科学基金(No.30900325)

The fluorinated graphite was prepared by fluoridation of pre-oxidized graphite to fabricate modified glassy carbon electrode(FFPGO/GCE). The electrochemical behaviors of catechol(CC) and hydroquinone(HQ) at the modified electrode were investigated by cyclic voltammetry(CV). Effects of experimental parameters such as pH, scan rate, and amount of drop coating on the simultaneous determination of CC and HQ were investigated. Under the optimized conditions, in 0.2 mol/L phosphate buffer solutions(pH 6.0), CC and HQ could be simultaneously determined on the FFPGO/GCE by differential pulse voltammetry(DPV). The oxidation peak current showed a good linear relationship with concentration of CC and HQ in the range of 1.0-150μmol/L. The detection limits were 0.31μmol/L(S/N=3) for CC and 0.43μmol/L(S/N=3) for HQ. Furthermore, the modified electrode exhibited good reproducibility, stability and selectivity. The modified electrode was used for determination of CC and HQ in imitative water samples with satisfactory results.
- Fluorinated graphite,
- Catechol,
- Hydroquinone,
- Differential pulse voltammetry,
- Simultaneous determination
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沈阳化工大学材料科学与工程学院沈阳 110142