Citation: Chengyu JIANG, Xufeng LIU. Synthesis, structural characterization, electrocatalytic proton reduction, and fungicidal activity of thiazole-containing di-iron complexes[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(2): 355-364. doi: 10.11862/CJIC.20250253 shu

Synthesis, structural characterization, electrocatalytic proton reduction, and fungicidal activity of thiazole-containing di-iron complexes

Chengyu JIANG ,
Xufeng LIU ^,

School of Materials and Chemical Engineering, Ningbo University of Technology, Ningbo, Zhejiang 315211, China

Corresponding author: Xufeng LIU, nkxfliu@126.com
Received Date: 3 August 2025
Revised Date: 22 November 2025

Figures(6)

This paper reports the preparation of three di-iron complexes containing a thiazole moiety. Esterification of complex [Fe₂(CO)₆(μ-SCH₂CH(CH₂OH)S)] (1) with 4-methylthiazole-5-carboxylic acid gave the corresponding ester [Fe₂(CO)₆(μ-tedt)] (2), where tedt=SCH₂CH(CH₂OOC(5-C₃HNSCH₃))S. Further reactions of complex 2 with tri(p-tolyl)phosphine (tp) or tris(4-fluorophenyl)phosphine (fp) gave the phosphine-substituted derivatives [Fe₂(CO)₅(tp)(μ-tedt)] (3) and [Fe₂(CO)₅(fp)(μ-tedt)] (4). The structures of the newly prepared complexes were elucidated by elemental analysis, NMR, IR, and X-ray photoelectron spectroscopy. Moreover, single-crystal X-ray diffraction analysis confirmed their molecular structures, showing that they contain a di-iron core ligated by a bridged dithiolate bearing a thiazole moiety and terminal carbonyls. The electrochemical and electrocatalytic proton reduction were probed by cyclic voltammetry, revealing that three complexes can catalyze the reduction of protons to H₂ under the electrochemical conditions. For comparison, complex 4 possessed the best efficiency with a turnover frequency of 23.5 s^-1 at 10 mmol·L^-1 HOAc concentration. In addition, the fungicidal activity of these complexes was also investigated in this study.
- thiazole,
- di-iron complex,
- crystal structure,
- electrocatalytic proton reduction,
- fungicidal activity
1. [1]
  FREY M. Hydrogenases: Hydrogen-activating enzymes[J]. ChemBioChem, 2002, 3(2/3): 153-160
2. [2]
  DU P W, SCHNEIDER J, JAROSZ P, EISENBERG R. Photocatalytic generation of hydrogen from water using a platinum (Ⅱ) terpyridyl acetylide chromophore[J]. J. Am. Chem. Soc., 2006, 128(24): 7726-7727 doi: 10.1021/ja0610683
3. [3]
  NA Y, WANG M, PAN J X, ZHANG P, ÅKERMARK B, SUN L C. Visible light-driven electron transfer and hydrogen generation catalyzed by bioinspired [2Fe2S] complexes[J]. Inorg. Chem., 2008, 47(7): 2805-2810 doi: 10.1021/ic702010w
4. [4]
  LI X Q, WANG M, ZHANG S P, PAN J X, NA Y, LIU J H, ÅKERMARK B, SUN L C. Noncovalent assembly of a metalloporphyrin and an iron hydrogenase active-site model: Photo-induced electron transfer and hydrogen generation[J]. J. Phys. Chem. B, 2008, 112(27): 8198-8202 doi: 10.1021/jp710498v
5. [5]
  ZHONG W, WU L, JIANG W D, LI Y L, MOOKAN N, LIU X M. Proton-coupled electron transfer in the reduction of diiron hexacarbonyl complexes and its enhancement on the electrocatalytic reduction of protons by a pendant basic group[J]. Dalton Trans., 2019, 48(36): 13711-13718 doi: 10.1039/C9DT02058F
6. [6]
  ZHAO P H, JIN B, WANG S J, WANG D, GUO Y, HU T P. Variation of dithiolate bridges in carbon nanotube-attached diiron chelate compounds for electrocatalytic hydrogen evolution reaction[J]. Appl. Surf. Sci., 2023, 639: 158276 doi: 10.1016/j.apsusc.2023.158276
7. [7]
  TARD C, PICKETT C J. Structural and functional analogues of the active sites of the [Fe]-, [NiFe]-, and [FeFe]-hydrogenases[J]. Chem. Rev., 2009, 109(6): 2245-2274 doi: 10.1021/cr800542q
8. [8]
  LUBITZ W, OGATA H, RÜDIGER O, REIJERSE E. Hydrogenases[J]. Chem. Rev., 2014, 114(8): 4081-4148 doi: 10.1021/cr4005814
9. [9]
  PETERS J W, LANZILOTTA W N, LEMON B J, SEEFELDT L C. X-ray crystal structure of the Fe-only hydrogenase (CpI) from Clostridium pasteurianum to 1.8 angstrom resolution[J]. Science, 1998, 282(5395): 1853-1858 doi: 10.1126/science.282.5395.1853
10. [10]
  NICOLET Y, PIRAS C, LEGRAND P, HATCHIKIAN C E, FONTECILLA-CAMPS J C. Desulfovibrio desulfuricans iron hydrogenase: The structure shows unusual coordination to an active site Fe binuclear center[J]. Structure, 1999, 7(1): 13-23 doi: 10.1016/S0969-2126(99)80005-7
11. [11]
  SCHMIDT M, CONTAKES S M, RAUCHFUSS T B. First generation analogues of the binuclear site in the Fe-only hydrogenases: Fe₂(μ-SR)₂(CO)₄(CN)₂^2‒[J]. J. Am. Chem. Soc., 1999, 121(4): 9736-9737
12. [12]
  MEJIA-RODRIGUEZ R, CHONG D, REIBENSPIES J H, SORIAGA M P, DARENSBOURG M Y. The hydrophilic phosphatriazaadamantane ligand in the development of H₂ production electrocatalysts: Iron hydrogenase model complexes[J]. J. Am. Chem. Soc., 2004, 126(38): 12004-12014 doi: 10.1021/ja039394v
13. [13]
  AHMED M E, NAYEK A, KRIžAN A, COUTARD N, MOROZAN A, DEY S G, LOMOTH R, HAMMARSTRöM L, ARTERO V, DEY A. A bidirectional bioinspired [FeFe]-hydrogenase model[J]. J. Am. Chem. Soc., 2022, 144(8): 3614-3625 doi: 10.1021/jacs.1c12605
14. [14]
  ORTON G R F, RINGENBERG M R, HOGARTH G. Biomimics of [FeFe]-hydrogenases incorporating redox-active ligands: Ferrocene-bridged dithiolate complexes [Fe₂(CO)₆(μ-EC₅H₄FeC₅H₄E)] (E=S, Se)[J]. J. Organomet. Chem., 2022, 978: 122472 doi: 10.1016/j.jorganchem.2022.122472
15. [15]
  MERINERO A D, COLLADO A, CASARRUBIOS L, GÓMEZ-GALLEGO M, DE ARELLANO C R, CABALLERO A, ZAPATA F, SIERRA M A. Triazole-containing [FeFe] hydrogenase mimics: Synthesis and electrocatalytic behavior[J]. Inorg. Chem., 2019, 58(23): 16267-16278 doi: 10.1021/acs.inorgchem.9b02813
16. [16]
  ORTAN G R F, GHOSH S, ALKER L, SARKER J C, PUGH D, RICHMOND M G, HARTL F, HOGARTH G. Biomimics of [FeFe]-hydrogenases incorporating redox-active ligands: Synthesis, redox properties and spectroelectrochemistry of diiron-dithiolate complexes with ferrocenyl-diphosphines as Fe₄S₄ surrogates[J]. Dalton Trans., 2022, 51(25): 9748-9769 doi: 10.1039/D2DT00419D
17. [17]
  SOLIMAN N N, SALAM M A E, FADDA A A, ABDEL-MOTAAL M. Synthesis, characterization, and biochemical impacts of some new bioactive sulfonamide thiazole derivatives as potential insecticidal agents against the cotton leafworm, Spodoptera littoralis[J]. J. Agric. Food Chem., 2020, 68(21): 5790-5805 doi: 10.1021/acs.jafc.9b06394
18. [18]
  LIU H, XU T, XUE Z H, HUANG M J, WANG T T, ZHANG M M, YANG R G, GUO Y. Current development of thiazole-containing compounds as potential antibacterials against methicillin-resistant Staphylococcus aureus[J]. ACS Infect. Dis., 2024, 10(2): 350-370 doi: 10.1021/acsinfecdis.3c00647
19. [19]
  GUO X F, ZHAO B, FAN Z J, YANG D Y, ZHANG N L, WU Q F, YU B, ZHOU S, KALININA T A, BELSKAYA N P. Discovery of novel thiazole carboxamides as antifungal succinate dehydrogenase inhibitors[J]. J. Agric. Food Chem., 2019, 67(6);1647-1655 doi: 10.1021/acs.jafc.8b06935
20. [20]
  LIU N, WAN Y H, BAI Z D, HAN J C, BAI H D, LI H, WANG Y Y, BAI L Y, LUO D F, LI Z R. Design, synthesis, and herbicidal activities of N-(5-(3,5-methoxyphenyl)-(thiazole-2-yl))phenoxyacetamide derivatives[J]. J. Agric. Food Chem., 2024, 72(42): 23097-23107 doi: 10.1021/acs.jafc.4c01824
21. [21]
  RAZAVET M, LE CLOIREC A, DAVIES S C, HUGHES D L, PICKETT C J. X-ray crystallographic analysis of D, L-[Fe₂{SCH₂CH(CH₂OH)S}(CO)₆] reveals a hydrogen-bonded cyclic hexamer with ordered optical centres[J]. Dalton Trans., 2001: 3551-3552
22. [22]
  TONG J Y, MIN L J, SUN N B, WU H K, YU S J, BIAN Q, LIU X H. Facile synthesis of novel quinolin-8-amine derivatives: Crystallographic study, in silico and antifungal investigation[J]. Chem. Biol. Technol. Agric., 2025, 12: 134 doi: 10.1186/s40538-025-00853-4
23. [23]
  ZHAO P H, LI J R, MA Z Y, HAN H F, QU Y P, LU B P. Diiron azadithiolate clusters supported on carbon nanotubes for efficient electrocatalytic proton reduction[J]. Inorg. Chem. Front., 2021, 8(8): 2107-2118 doi: 10.1039/D0QI01415J
24. [24]
  GAO Y, WANG S J, GUO Z, WANG Y Z, QU Y P, ZHAO P H. Covalent versus noncovalent attachments of [FeFe]-hydrogenase models onto carbon nanotubes for aqueous hydrogen evolution reaction[J]. J. Inorg. Biochem., 2024, 259: 112665 doi: 10.1016/j.jinorgbio.2024.112665
25. [25]
  LIU X F, XU B, XU H, LI Y L. Diiron butane-1, 2-dithiolate complexes with phosphine ligands: Preparation, crystal structures, and electrochemical catalytic performance[J]. Chinese J. Inorg. Chem., 2022, 38(12): 2521-2529
26. [26]
  YAN L, HU K, LIU X F, LI Y L, LIU X H, JIANG Z Q. Diiron ethane-1, 2-dithiolate complexes with 1, 2, 3-thiadiazole moiety: Synthesis, X-ray crystal structures, electrochemistry and fungicidal activity[J]. Appl. Organomet. Chem., 2021, 35(2): e6084 doi: 10.1002/aoc.6084
27. [27]
  CHEN F Y, HE J, YU X Y, WANG Z, MU C, LIU X F, LI Y L, JIANG Z Q, WU H K. Electrocatalytic properties of diiron ethanedithiolate complexes containing benzoate ester[J]. Appl. Organomet. Chem., 2018, 32(12): e4549 doi: 10.1002/aoc.4549
28. [28]
  LIN H M, LI J R, MU C, LI A, LIU X F, ZHAO P H, LI Y L, JIANG Z Q, WU H K. Synthesis, characterization, and electrochemistry of monophosphine-containing diiron propane-1, 2-dithiolate complexes related to the active site of [FeFe]-hydrogenases[J]. Appl. Organomet. Chem., 2019, 33(11): e5196 doi: 10.1002/aoc.5196
29. [29]
  LIU X F, XU B, XU H, LI Y L. Synthesis, characterization, and electrocatalytic hydrogen evolution of diiron dithiolato pentacarbonyl complexes bearing phosphine ligand[J]. Chinese J. Inorg. Chem., 2023, 39(8): 1619-1627
30. [30]
  LIU X F, LI Y L, LIU X H. Synthesis, characterization, electrocatalytic properties, and antifungal activity of isoxazole-containing di-iron complexes[J]. Chinese J. Inorg. Chem., 2023, 39(12): 2367-2376
31. [31]
  GHOSH S, HOGARTH G, HOLLINGSWORTH N, HOLT K B, RICHARD I, RICHMOND M G, SANCHEZ B E, UNWIN D. Models of the iron-only hydrogenase: A comparison of chelate and bridge isomers of Fe₂(CO)₄{Ph₂PN(R)PPh₂}(μ-pdt) as proton-reduction catalysts[J]. Dalton Trans., 2013, 42(19): 6775-6792 doi: 10.1039/c3dt50147g
32. [32]
  ZHAO P H, MA Z Y, HU M Y, HE J, WANG Y Z, JING X B, CHEN H Y, LI Y L. PNP-chelated and -bridged diiron dithiolate complexes Fe₂(μ-pdt)(CO)₄{(Ph₂P)₂NR} together with related monophosphine complexes for the [2Fe]_H subsite of [FeFe]-hydrogenases: Preparation, structure, and electrocatalysis[J]. Organometallics, 2018, 37(8): 1280-1290 doi: 10.1021/acs.organomet.8b00030
33. [33]
  DEY S, RANA A, DEY S G, DEY A. Electrochemical hydrogen production in acidic water by an azadithiolate bridged synthetic hydrogenese mimic: Role of aqueous solvation in lowering overpotential[J]. ACS Catal., 2013, 3(3): 429-436 doi: 10.1021/cs300835a
34. [34]
  AHMED M E, DEY S, MONDAL B, DEY A. H₂ evolution catalyzed by a FeFe-hydrogenase synthetic model covalently attached to graphite surfaces[J]. Chem. Commun., 2017, 53(58): 8188-8191 doi: 10.1039/C7CC04281G
35. [35]
  JIN B, TAN X, ZHANG X X, WANG Z Y, QU Y P, HE Y B, HU T P, ZHAO P H. Substituent effects in carbon-nanotube-supported diiron monophosphine complexes for hydrogen evolution reaction[J]. Electrochim. Acta, 2022, 434: 141325 doi: 10.1016/j.electacta.2022.141325
36. [36]
  CHONG D, GEORGAKAKI I P, MEJIA-RODRIGUEZ R, SANABRIA-CHINCHILLA J, SORIAGA M P, DARENSBOURG M Y. Electrocatalysis of hydrogen production by active site analogues of the iron hydrogenase enzyme: Structure/function relationships[J]. Dalton Trans., 2003: 4158-4163
37. [37]
  GLOAGUEN F, LAWRENCE J D, RAUCHFUSS T B. Biomimetic hydrogen evolution catalyzed by an iron carbonyl thiolate[J]. J. Am. Chem. Soc., 2001, 123(38): 9476-9477 doi: 10.1021/ja016516f
38. [38]
  BAI S F, DU X M, TIAN W J, XU H, ZHANG R F, MA C L, WANG Y L, LÜ S, LI Q L, LI Y L. Di-, tri- and tetraphosphine-substituted Fe/Se carbonyls: Synthesis, characterization and electrochemical properties[J]. Dalton Trans., 2022, 51(29): 11125-11134 doi: 10.1039/D2DT01376B
39. [39]
  ZHU L J, LIU X F. Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands[J]. Chinese J. Inorg. Chem., 2025, 41(2): 321-328
40. [40]
  YAN L, YANG J, Lü S, LIU X F, LI Y L, LIU X H, JIANG Z Q. Phosphine-containing diiron propane-1, 2-dithiolate derivatives: Synthesis, spectroscopy, X-ray crystal structures, and electrochemistry[J]. Catal. Lett., 2021, 151(7): 1857-1867 doi: 10.1007/s10562-020-03450-2
41. [41]
  HOGARTH G. An unexpected leading role for [Fe₂(CO)₆(μ-pdt)] in our understanding of [FeFe]-H₂ases and the search for clean hydrogen production[J]. Coord. Chem. Rev., 2023, 490: 215174 doi: 10.1016/j.ccr.2023.215174
42. [42]
  LÜ S, HUANG H L, ZHANG R F, MA C L, LI Q L, HE J, YANG J, LI T, LI Y L. Phosphine-substituted Fe-Te clusters related to the active site of [FeFe]-H₂ases[J]. Inorg. Chem. Front., 2020, 7(12): 2352-2361 doi: 10.1039/D0QI00276C
43. [43]
  ZHU L J, LIU X F. Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine[J]. Chinese J. Inorg. Chem., 2025, 41(5): 939-947
44. [44]
  HELM M L, STEWART M P, BULLOCK R M, DUBOIS M R, DUBOIS D L. A synthetic nickel electrocatalyst with a turnover frequency above 100, 000 s^-1 for H₂ production[J]. Science, 2011, 333(6044): 863-866 doi: 10.1126/science.1205864
45. [45]
  LIU X H, QIAO L, ZHAI Z W, CAI P P, CANTRELL C L, TAN C X, WENG J Q, HAN L, WU H K. Novel 4-pyrazole carboxamide derivatives containing flexible chain motif: Design, synthesis and antifungal activity[J]. Pest Manag. Sci., 2019, 75(11): 2892-2900 doi: 10.1002/ps.5463
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