Citation: Ruiying WANG, Hui WANG, Fenglan CHAI, Zhinan ZUO, Benlai WU. Three-dimensional homochiral Eu(Ⅲ) coordination polymer and its amino acid configuration recognition[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(5): 877-884. doi: 10.11862/CJIC.20250052 shu

Three-dimensional homochiral Eu(Ⅲ) coordination polymer and its amino acid configuration recognition

Ruiying WANG ¹ ,
Hui WANG ¹ ,
Fenglan CHAI ^1,, ,
Zhinan ZUO ² ,
Benlai WU ^2,,

1.
School of Chemical Engineering, Henan Technical Institute of Applied Technology, Zhengzhou 450042, China
2.
College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: Fenglan CHAI, 965996899@qq.com Benlai WU, wbl@zzu.edu.cn
Received Date: 19 February 2025
Revised Date: 20 March 2025

Figures(8)

Solvothermal reaction of a designed enantiomerically pure chiral ligand S-4'-[(2-carboxy-5-oxopyrrolidin1-yl)methyl]-(1, 1'-biphenyl)-3, 5-dicarboxylic acid (H₃L) with Eu(Ⅲ) salt produced a new homochiral coordination polymer {[Eu(L)]·0.5CH₃CN}_n (1). Single crystal X-ray diffraction analysis has displayed that 1 belongs to the tetragonal I4 ₁ chiral space group. In 1, anionic ligands L^3- acted as μ₇-bridges and connected Eu(Ⅲ) ions to form a 3D helical structure with 7-connected topology. Ligand H₃L not only transfers chirality to the resulting metal-organic framework but also induces helical chirality generation. Complex 1 exhibited excellent ligandsensitized emission and thermal stability. Using complex 1 as a fluorescent probe, its configuration recognition performance on common amino acids was investigated. Our results showed that the different enantiomers of aspartic acid, alanine, lysine, leucine, tyrosine, and valine had various impacts on the fluorescence intensity of 1, indicating that 1 can detect their configurations of the six amino acids mentioned above.
- homochiral metal-organic framework,
- Eu(Ⅲ) complex,
- crystal structure,
- fluorescence property,
- enantiomer recognition
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