Citation: Wanting CHEN, Chufei MIAO, Yan LIU, Bobi ZHENG, Xiaoyu ZHENG, Han XU, Jumei TIAN. Syntheses, characterization, and luminescence properties of Yb(Ⅲ)-based one-dimensional chain coordination polymer[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(8): 1672-1680. doi: 10.11862/CJIC.20250013 shu

Syntheses, characterization, and luminescence properties of Yb(Ⅲ)-based one-dimensional chain coordination polymer

Wanting CHEN ^{1, #} ,
Chufei MIAO ^{1, #} ,
Yan LIU ¹ ,
Bobi ZHENG ¹ ,
Xiaoyu ZHENG ¹ ,
Han XU ² ,
Jumei TIAN ^1,,

1.
Engineering Research Center of Stomatological Biomaterials, Fujian Province University, School of Stomatology of Xiamen Medical College, Xiamen, Fujian 361023, China
2.
Yunnan Key Laboratory of Pharmacology for Natural Products, School of Pharmaceutical Science, Kunming Medical University, Kunming 650500, China

Corresponding author: Jumei TIAN, 201400010312@xmmc.edu.cn

Received Date: 11 January 2025
Revised Date: 24 May 2025

Figures(3)

One Yb(Ⅲ)-based coordination polymer, {[Yb(H₂dhtp)_1.5(H₂O)₄]·3H₂O}_n (1) (H₄dhtp=2, 5-dihydroxyterephthalic acid), was fabricated and structurally characterized by single-crystal X-ray diffraction, IR, powder X-ray diffraction, X-ray diffraction, and elemental analysis. Complex 1 displays a 1D chain structure, and belongs to P1 group. The solid-state luminescent spectrum of 1 showed an emission band with the maximum at 508 nm (λ_ex=408 nm). It exhibited the emission characteristic of the H₄dhtp ligand. The fluorescence of 1 in water displayed the strongest intensity. In detecting various metal ions, adding Zr⁴⁺ led to a blue shift in fluorescence, accompanied by an increase in intensity, whereas the presence of Fe³⁺ resulted in a decrease in luminescence. The changes observed in the IR spectrum indicate an interaction between Fe³⁺/Zr⁴⁺ and complex 1, resulting in the variation of luminescence properties.
- coordination polymers,
- structure,
- luminescence
1. [1]
  WANG W M, WU Z L, CUI J Z. Molecular assemblies from linear-shaped Ln₄ clusters to Ln₈ clusters using different β-diketonates: Disparate magnetocaloric effects and single-molecule magnet behaviours[J]. Dalton Trans., 2021,50(37):12931-12943.
2. [2]
  WANG W M, QIAO N, XIN X Y, WU Z L, CUI J Z. Octanuclear Ln(Ⅲ)-based clusters assembled by a polydentate Schiff base ligand and a β-diketone co-ligand: Efficient conversion of CO₂ to cyclic carbonates and large magnetocaloric effect[J]. Cryst. Growth Des., 2023,23(1):87-95.
3. [3]
  HAN L J, WU X X, MA Z G, LI Y, WEI Q H. Novel luminescent homo/heterometallic platinum(Ⅱ) alkynyl complexes based on Y-shaped pyridyl diphosphines[J]. Dalton Trans., 2020,49(24):8347-8353.
4. [4]
  ZHAO D, XUE Y L, ZHANG R J, FAN Y P, LIU B Z, LI Y A, ZHANG S R. Design, synthesis, crystal structure and luminescent properties introduced by Eu³⁺ of a new type of rare-earth borophosphate CsNa₂REE₂(BO₃)(PO₄)₂ (REE=Y, Gd)[J]. Dalton Trans., 2020,49(29):10104-10113.
5. [5]
  SHI X H, XIN X Y, CHEN F J, LI W Y, WEI S J, LIU J C, HAN H, WU W H Y, WANG J N, WANG J Y, WANG J, SHI Y. Crystal structure, fluorescence properties, and biological activity of three butterfly-shaped Ln₄ compounds[J]. Polyhedron, 2023,234116321.
6. [6]
  XU Y Y, CHEN P, GAO T, LI H F, YAN P F. White-light emission based on a single component Sm(Ⅲ) complex and enhanced optical properties by doping methods[J]. CrystEngComm, 2019,21(6):964-970.
7. [7]
  MA Y A, YANG X P, SHI D L, NIU M Y, SCHIPPER D. One high-nuclearity Cd(Ⅱ)-Yb(Ⅲ) nanoring with near-IR luminescent sensing to antibiotics[J]. Inorg. Chem., 2020,59(23):16809-16813.
8. [8]
  OTHONG J, BOONMAK J, CHEANSIRISOMBOON A, PUANGMALI T, PHANCHAI W, YOUNGME S. pH modulated luminescent switching and discriminative detection of amino acid based on metal-organic framework[J]. Anal. Chim. Acta, 2021,1187339157.
9. [9]
  ALTHOMALI R H, HAMOUD ALSHAHRANI S, QASIM ALMAJIDI Y, KAMAL HASAN W, GULNOZA D, ROMERO-PARRA R M, ABID M K, RADIE ALAWADI A H, ALSALAMYH A, JUYAL A. Current trends in nanomaterials-based electrochemiluminescence aptasensors for the determination of antibiotic residues in foodstuffs: A comprehensive review[J]. Crit. Rev. Anal. Chem., 2023:1-17.
10. [10]
  SHI D L, YANG X P, XIAO Z Y, LIU X M, CHEN H F, MA Y N, SCHIPPER D, JONES R A. A 42-metal Yb(Ⅲ) nanowheel with NIR luminescent response to anions[J]. Nanoscale, 2020,12(3):1384-1388.
11. [11]
  ZUO C Y, LI Q Q, DAI M Z, FAN C Y, XU Y, LIU G Z, WANG S Y. A cadmium-based metal-organic framework for fluorescence detection of acetone and Fe³⁺[J]. Chinese J. Inorg. Chem., 2023,39(12):2301-2310.
12. [12]
  QUAREZ É, JOUHARA A, GROLLEAU S, DOLHEM F, DUPR N, POIZOT P. From partial to complete neutralization of 2, 5-dihydroxyterephthalic acid in the Li-Na system: Crystal chemistry and electrochemical behavior of Na₂Li₂C₈H₂O₆ vs. Li[J]. CrystEngComm, 2020,22(9):1653-1663.
13. [13]
  BELLIS J D, BELLUCCI L, BOTTARO G, LABELLA L, MARCHETTI F, SAMARITANI S, BELLI DELL'AMICO D, ARMELAO L. Single-crystal-to-single-crystal post-synthetic modifications of three-dimensional LOFs (Ln=Gd, Eu): A way to modulate their luminescence and thermometric properties[J]. Dalton Trans., 2020,49(18):6030-6042.
14. [14]
  VOGEL D J, SAVA GALLIS D F, NENOFF T M, RIMSZA J M. Structure and electronic properties of rare earth DOBDC metal-organic-frameworks[J]. Phys. Chem. Chem. Phys., 2019,21(41):23085-23093.
15. [15]
  HENKELIS S E, RADEMACHER D, VOGEL D J, VALDEZ N R, RODRIGUEZ M A, ROHWER L E S, NENOFF T M. Luminescent properties of DOBDC containing MOFs: The role of free hydroxyls[J]. ACS Appl. Mater. Interfaces, 2020,12(20):22845-22852.
16. [16]
  HU F, YANG X P, LENG X L, WANG C R, YANG K Q, ZHANG L J, SCHIPPER D. Construction of a near-IR-luminescent rectangular Yb(Ⅲ) complex from a dodecadentate Schiff base ligand for the excitation-wavelength-dependent detection of aloe emodin (a natural medicinal ingredient)[J]. Inorg. Chem., 2023,62(6):2508-2512.
17. [17]
  TOLEDO-JALDIN H P, PINZON-VANEGAS C, BLANCO-FLORES A, ZAMORA-MORENO J, ROSALES-V ZQUEZ L D, VILCHIS-NESTOR A R, REYES-DOM NGUEZ I A, ROMERO-SOLANO M Á, DORAZCO-GONZ LEZ A. Pesticides luminescent sensing by a Tb³⁺-doped Zn metal-organic framework with selectivity towards parathion[J]. Environ. Pollut., 2024,343123195.
18. [18]
  ZHENG B B, MIAO C F, XU H, LAI J Q, LI M, TIAN J M. Gd(Ⅲ)/ Dy(Ⅲ)-based coordination polymers for luminescent and magnetic properties[J]. Results Chem., 2024,7101276.
19. [19]
  PINSKY M, AVNIR D. Continuous symmetry measures. 5. The classical polyhedra[J]. Inorg. Chem., 1998,37(21):5575-5582.
20. [20]
  ROY S, DU J Y, MANOHAR E M, AZIZ T, PAL T K, SUN L, AHMED N, DAS S. Syntheses, structures, and magnetic properties of novel[3×1+2×1] pentanuclear zinc(Ⅱ)-lanthanide(Ⅲ) cocrystal complexes: Slow magnetic relaxation behavior of the Dy(Ⅲ) analogue[J]. Cryst. Growth Des., 2023,23(4):2218-2230.
21. [21]
  BRESE N E, KEEFFE M O. Bond-valence parameters for solids[J]. Acta Crystallogr. Sect. B, 1991,47:192-197.
22. [22]
  GAMONCHUANG J, SANTALADCHAIYAKIT Y, BURAKHAM R. Magnetic solid-phase extraction of carbamate pesticides using magnetic metal-organic frameworks derived from benzoate ligands, followed by digital image colorimetric screening and high-performance liquid chromatography analysis[J]. ACS Omega, 2022,7(14):12202-12211.
23. [23]
  OTHONG J, BOONMAK J, KIELAR F, YOUNGME S. Dual function based on switchable colorimetric luminescence for water and temperature sensing in two-dimensional metal-organic framework nanosheets[J]. ACS Appl. Mater. Interfaces, 2020,12(37):41776-41784.
24. [24]
  WU H N, GAO L L, ZHANG J, ZHAI L J, GAO T, NIU X Y, HU T P. Syntheses, characterization, and slow magnetic relaxation or luminescence properties of three new 2D coordination polymers[J]. J. Mol. Struct., 2020,1219128613.
25. [25]
  WANG H, LI X, CHENG H, LI Y J, SONG X Q, WANG L. Two luminescent film sensors constructed from new lanthanide coordination polymers for ratiometric detection of Zn²⁺ and NH₃ in water and their white emission properties[J]. Polym. Chem., 2022,13(6):778-793.
26. [26]
  LIN Z G, SONG F Q, WANG H, SONG X Q, YU X X, LIU W S. The construction of a novel luminescent lanthanide framework for the selective sensing of Cu²⁺ and 4-nitrophenol in water[J]. Dalton Trans., 2021,50(5):1874-1886.
27. [27]
  WANG H. Preparation and sensing performance study of multi-branch luminescent compounds and their lanthanide coordination polymers[D]. Lanzhou: Lanzhou Jiaotong University, 2022: 1-87
28. [28]
  HASEGAWA M, OHMAGARI H, TANAKA H, MACHIDA K. Luminescence of lanthanide complexes: From fundamental to prospective approaches related to water- and molecular-stimuli[J]. J. Photochem. Photobiol. C‒Photochem. Rev., 2022,50100484.
29. [29]
  BINNEMANS K. Lanthanide-based luminescent hybrid materials[J]. Chem. Rev., 2009,109(9):4283-4374.
30. [30]
  CHEN Q. Research on the synthesis and detection Application of multidentate functional ligand complexes[D]. Wuxi: Jiangnan University, 2023: 1-90
31. [31]
  LEI K W, LIU W S, TAN M Y. Solvent effect on the luminescent properties of new europium and terbium nitrate complexes with 3, 3, 7, 7-tetra[N-methyl-N-phenyl(acetamide)-2-oxymethyl]-5-oxanonane[J]. Spectroc. Acta Pt. A‒Molec. Biomolec. Spectr., 2007,66(3):590-593.
32. [32]
  BÜNZLI J C G. Lanthanide luminescence: From a mystery to rationalization, understanding, and applications[M]//Bünzli J C G, Pecharsky V K. Handbook on the Physics and Chemistry of Rare Earths: Vol. 50. Amsterdam, Oxford: Elsevier, 2016: 141-176
33. [33]
  RODRIGUEZ-CACERES M I, AGBARIA R A, LUNA U J, WHITE S, WARNER I M. Fluorescence of zirconium-naphthalene complexes: Effect of ortho-naphthalene substitution[J]. Spectroc. Acta Pt. A‒Molec. Biomolec. Spectr., 2008,71(3):907-914.
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