Citation: Ruolin CHENG, Yue WANG, Xiyao NIU, Huagen LIANG, Ling LIU, Shijian LU. Efficient photothermal catalytic CO₂ cycloaddition over W₁₈O₄₉/rGO composites[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(7): 1276-1284. doi: 10.11862/CJIC.20240424 shu

Efficient photothermal catalytic CO₂ cycloaddition over W₁₈O₄₉/rGO composites

Ruolin CHENG ^{1, 2,,} ,
Yue WANG ² ,
Xiyao NIU ³ ,
Huagen LIANG ^{1, 2} ,
Ling LIU ^{1, 2} ,
Shijian LU ^{1, 2,,}

1.
Jiangsu Key Laboratory of Coal-based Greenhouse Gas Control and Utilization, Carbon Neutrality Institute, China University of Mining and Technology, Xuzhou, Jiangsu 221008, China
2.
School of Chemical Engineering, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China
3.
School of Information and Control Engineering, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China

Corresponding author: Ruolin CHENG, ruolin.cheng@cumt.edu.cn Shijian LU, lushijian@cumt.edu.cn
Received Date: 2 December 2024
Revised Date: 12 April 2025

Figures(8)

Converting CO₂ into cyclic carbonates, a process with 100% atom efficiency, offers a promising route for carbon utilization, yet it is hindered by harsh reaction conditions (high temperature/pressure). To provide a cost- effective, high-efficiency catalyst design strategy for sustainable CO₂ conversion, oxygen-vacancy-rich defective tungsten oxide (W₁₈O₄₉)/reduced graphene oxide (rGO) composites were constructed via an in-situ solvothermal method. Comprehensive characterization confirmed its structural integrity and defect-rich nature. The W₁₈O₄₉/rGO composite exhibited exceptional photothermal catalytic activity for CO₂ cycloaddition under ambient conditions, achieving a 95% styrene carbonate yield (173 mmol·g^-1·h^-1) with excellent cycling stability. The integration of rGO enhances the CO₂ adsorption, broadens the light absorption, and facilitates charge transfer efficiency. The coupling effect of photocatalysis and thermal catalysis significantly improves the catalytic performance.
- CO₂ cycloaddition,
- photocatalysis,
- photothermal effect,
- defective tungsten oxide,
- reduced graphene oxide
1. [1]
  SURI D, DAS S, CHOUDHARY S, VENKANNA G, SHARMA B, AFROZ M A, TAILOR N K, JOSHI R, SATAPATHI S, TRIPATHI K. Enigma of sustainable CO₂ conversion to renewable fuels and chemicals through photocatalysis, electrocatalysis, and photoelectrocatalysis: Design strategies and atomic level insights[J]. Small, 2025, 21(8): 2408981 doi: 10.1002/smll.202408981
2. [2]
  FENG Y, YAO J F. Photo-driven CO₂ conversion into cyclic carbonates[J]. Sep. Purif. Technol., 2024, 356: 130027
3. [3]
  CHENG R L, REN J, WANG H R, LIANG H G, TSIAKARAS P. Photo-induced CO₂ cycloaddition and tetracycline degradation over novel FeO_x modified defective graphitic carbon nitride composite[J]. Appl. Catal. B–Environ., 2024, 352: 124024 doi: 10.1016/j.apcatb.2024.124024
4. [4]
  SHEN Q Y, CHEN W R, WANG M, JIN X X, ZHANG L X, SHI J L. A MOF@MOF S-scheme heterojunction with Lewis acid-base sites synergistically boosts cocatalyst‑free CO₂ cycloaddition[J]. ChemSusChem, 2024, 18(2): e202401362
5. [5]
  LIANG J X, JIANG X, ZHANG X R, YU H, SHI J J, WANG M. Co-porphyrin-based metal-organic framework for light-driven efficient green conversion of CO₂ and epoxides[J]. Chem. Eng. J., 2024, 499: 156428 doi: 10.1016/j.cej.2024.156428
6. [6]
  ZHANG H G, ZHAI G Y, LEI L F, ZHANG C Y, LIU Y Y, WANG Z Y, CHENG H F, ZHENG Z K, WANG P, DAI Y, HUANG B B. Photo-induced photo-thermal synergy effect leading to efficient CO₂ cycloaddition with epoxide over a Fe-based metal organic framework[J]. J. Colloid Interface Sci., 2022, 625: 33-41 doi: 10.1016/j.jcis.2022.05.146
7. [7]
  HE Y Z, XU M S, XIA J H, ZHANG C H, SONG X T, ZHAO X F, FU M, LI S Q, LIU X Y. Effect of exposed active sites of semi-amorphous Fe-BTC on photocatalytic CO₂ cycloaddition reaction under ambient conditions[J]. Mol. Catal., 2023, 542: 113134 doi: 10.1016/j.mcat.2023.113134
8. [8]
  CHENG R L, WANG H R, REN J, MA Y Y, LIANG H G. Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst[J]. Chinese J. Inorg. Chem., 2024, 40(3): 523-532 doi: 10.11862/CJIC.20230349
9. [9]
  CHENG R L, JIN X X, FAN X Q, WANG M, TIAN J J, ZHANG L X, SHI J L. Incorporation of N-doped reduced graphene oxide into pyridine-copolymerized g-C₃N₄ for greatly enhanced H₂ photocatalytic evolution[J]. Acta Phys.‒Chim. Sin., 2017, 33(7): 1436-1445
10. [10]
  SHA M S, ANWAR H, MUSTHAFA F N, AL-LOHEDAN H, ALFARWATI S, RAJABATHAR J R, ALAHMAD J K, CABIBIHAN J J, KARNAN M, SADASIVUNI K K. Photocatalytic degradation of organic dyes using reduced graphene oxide (rGO)[J]. Sci. Rep., 2024, 14(1): 360810
11. [11]
  DONG S Y, ZHAO Y L, YANG J Y, LIU X D, LI W, ZHANG L Y, WU Y H, SUN J H, FENG J L, ZHU Y F. Visible-light responsive PDI/rGO composite film for the photothermal catalytic degradation of antibiotic wastewater and interfacial water evaporation[J]. Appl. Catal. B‒Environ., 2021, 291: 120127 doi: 10.1016/j.apcatb.2021.120127
12. [12]
  CHENG R L, STEELE J A, ROEFFAERS M B J, HOFKENS J, DEBROYE E. Dual-channel charge carrier transfer in CsPbX₃ perovskite/W₁₈O₄₉ composites for selective photocatalytic benzyl alcohol oxidation[J]. ACS Appl. Energ. Mater., 2021, 4(4): 3460-3468 doi: 10.1021/acsaem.0c03215
13. [13]
  BIBI S, AHMAD A, ANJUM M A R, HALEEM A, SIDDIQ M, SHAH S S, AI KAHTANI A. Photocatalytic degradation of malachite green and methylene blue over reduced graphene oxide (rGO) based metal oxides (rGO-Fe₃O₄/TiO₂) nanocomposite under UV-visible light irradiation[J]. J. Environ. Chem. Eng., 2021, 9(4): 105580 doi: 10.1016/j.jece.2021.105580
14. [14]
  LUO Z R, LI D D, TAN S Z, HUANG L H. Preparation and oil-water separation of 3D kapok fiber-reduced graphene oxide aerogel[J]. J. Chem. Technol. Biotechnol., 2020, 95(3): 639-648 doi: 10.1002/jctb.6245
15. [15]
  ZHANG S, ZHANG H, CAO F X, MA Y Y, QU Y Q. Catalytic behavior of graphene oxides for converting CO₂ into cyclic carbonates at one atmospheric pressure[J]. ACS Sustain. Chem. Eng., 2018, 6(3): 4204-4211 doi: 10.1021/acssuschemeng.7b04600
16. [16]
  ZHANG N, JALIL A, WU D X, CHEN S M, LIU Y F, GAO C, YE W, QI Z M, JU H X, WANG C M, WU X J, SONG L, ZHU J F, XIONG Y J. Refining defect states in W₁₈O₄₉ by Mo doping: A strategy for tuning N₂ activation towards solar-driven nitrogen fixation[J]. J. Am. Chem. Soc., 2018, 140(30): 9434-9443 doi: 10.1021/jacs.8b02076
17. [17]
  ZHANG X L, HUANG W, XIA Z X, XIAN M, BU F, LIANG F B, FENG D X. One-pot synthesis of S-scheme WO₃/BiOBr heterojunction nanoflowers enriched with oxygen vacancies for enhanced tetracycline photodegradation[J]. Sep. Purif. Technol., 2022, 290: 120897 doi: 10.1016/j.seppur.2022.120897
18. [18]
  ZHAI G Y, LIU Y Y, LEI L F, WANG J J, WANG Z Y, ZHENG Z K, WANG P, CHENG H F, DAI Y, HUANG B B. Light-promoted CO₂ conversion from epoxides to cyclic carbonates at ambient conditions over a Bi-based metal-organic framework[J]. ACS Catal., 2021, 11(4): 1988-1994 doi: 10.1021/acscatal.0c05145
19. [19]
  JIANG B, ZHANG C C, YANG N, ZHOU Q, ZHANG L F, LI J S, YANG W, YANG X D, ZHANG L H. 2D/2D ZIF-L-derived Zn^δ+ (0≤δ≤2) and N codoped carbon skeleton@ZnIn₂S₄ S-scheme heterojunction for solar-driven CO₂ cycloaddition[J]. ACS Sustain. Chem. Eng., 2024, 12(17): 6584-6595 doi: 10.1021/acssuschemeng.3c08407
20. [20]
  GONG X Q, ZHANG Y J, XU Y Y, ZHAI G Y, LIU X L, BAO X L, WANG Z Y, LIU Y Y, WANG P, CHENG H F, FAN Y C, DAI Y, ZHENG Z K, HUANG B B. Synergistic effect between CO₂ chemisorption using amino-modified carbon nitride and epoxide activation by high-energy electrons for plasmon-assisted synthesis of cyclic carbonates[J]. ACS Appl. Mater. Interfaces, 2022, 14(45): 51029-51040 doi: 10.1021/acsami.2c16382
21. [21]
  KHALID A, RAZZAQ Z, AHMAD P, AL-ANZI B S, REHMAN F, MUHAMMAD S, KHANDAKER M U, ALBASHER G, ALSULTAN N, LIAQAT I, HAYAT D. Visible-light promoted chemical fixation of carbon dioxide with epoxide into cyclic carbonates over S-scheme CdS-CeO₂ photocatalyst[J]. Mater. Sci. Semicond. Process, 2023, 165: 107649 doi: 10.1016/j.mssp.2023.107649
22. [22]
  JING S Y, REN J, WANG A H, CHENG R L, LIANG H G, LIU H, CHEN F, TSIAKARAS P. An efficient photo-Fenton In₂O₃@FeIn₂S₄ composite catalyst for tetracycline degradation[J]. Chem. Eng. J., 2024, 491: 151549 doi: 10.1016/j.cej.2024.151549
23. [23]
  CHENG R L, WANG A H, SANG S X, LIANG H G, LIU S Q, TSIAKARAS P. Photocatalytic CO₂ cycloaddition over highly efficient W₁₈O₄₉-based composites: An economic and ecofriendly choice[J]. Chem. Eng. J., 2023, 466: 142982 doi: 10.1016/j.cej.2023.142982
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Efficient photothermal catalytic CO₂ cycloaddition over W₁₈O₄₉/rGO composites