Citation: Pingping LU, Shuguang ZHANG, Peipei ZHANG, Aiyun NI. Preparation of zinc sulfate open frameworks based probe materials and detection of Pb²⁺ and Fe³⁺ ions[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(5): 959-968. doi: 10.11862/CJIC.20240411 shu

Preparation of zinc sulfate open frameworks based probe materials and detection of Pb²⁺ and Fe³⁺ ions

1.
School of Civil Engineering, Liaoning Technical University, Fuxin, Liaoning 123000, China
2.
School of Civil Engineering, Guilin University of Technology, Guilin, Guangxi 541004, China
3.
College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, Guangxi 541004, China
4.
College of Pharmacy, Dezhou University, Dezhou, Shandong 253023, China

Corresponding author: Peipei ZHANG, zhangpeipei@glut.edu.cn Aiyun NI, niaiyun_qd@163.com
Received Date: 16 November 2024
Revised Date: 17 January 2025

Figures(5)

A zinc sulfate open framework matrix, [Zn(SO₄)(DMSO)] (1), was synthesized by solvothermal evaporation using dimethyl sulfoxide (DMSO) as the solvent. A composite P@1, which exhibits fluorescence and room temperature phosphorescence (RTP) properties, was prepared by doping 2, 6-naphthalic acid (P) into matrix 1 at a low concentration. P@1 emitted a green RTP that was visible to the naked eye and lasted for approximately 2 s. P@1 exhibited selective phosphorescence enhancement response towards Pb²⁺, with a detection limit of 2.52 μmol·L^-1. The main detection mechanism is the Pb—O coordination-induced phosphorescence enhancement in the system. Interestingly, P@1 also functioned as a dualchannel probe for the rapid detection of Fe³⁺ ions through fluorescence quenching with a detection limit of 0.038 μmol·L^-1. The recognition mechanism may be attributed to the competitive energy absorption between P@1 and Fe³⁺ ions.
- zinc sulfate matrix,
- doping,
- phosphorescence and fluorescence probes,
- Pb²⁺,
- Fe³⁺
1. [1]
  TANG Q, LI L Y, ZHANG S, ZHENG L, MIAO C H. Characterization of heavy metals in coal gangue-reclaimed soils from a coal mining area[J]. J. Geochem. Explor., 2018,186:1-11. doi: 10.1016/j.gexplo.2017.11.018
2. [2]
  LIU X Y, BAI Z K, SHI H D, ZHOU W, LIU X C. Heavy metal pollu-tion of soils from coal mines in China[J]. Nat. Hazards, 2019,99(2):1163-1177. doi: 10.1007/s11069-019-03771-5
3. [3]
  USMAN K, ABU-DIEYEH M H, ZOUARI N, AL-GHOUTI M A. Lead (Pb) bioaccumulation and antioxidative responses in Tetraena qataranse[J]. Sci. Rep., 2020,10(1)17070. doi: 10.1038/s41598-020-73621-z
4. [4]
  YANG C Y, DU C Y, YUAN F Y, YU P T, WANG B X, SU C S, ZOU R Q, WANG J Y, YAN X, SUN C Y, LI H X. CRISPR/Cas12a-derived ratiometric fluorescence sensor for high-sensitive Pb²⁺ detec-tion based on CDs@ZIF-8 and DNAzyme[J]. Biosens. Bioelectron., 2024,251116089. doi: 10.1016/j.bios.2024.116089
5. [5]
  AHMED H E H, MOHAMMED A M A, SOYLAK M. A magnetic sol-id phase extraction procedure for Pb(Ⅱ) at trace levels on magnetic Luffa@TiO 2 in food and water samples[J]. Food Chem., 2023,428136794. doi: 10.1016/j.foodchem.2023.136794
6. [6]
  ZHANG N, SHEN K, YANG X M, LI Z X, ZHOU T K, ZHANG Y, SHENG Q L, ZHENG J B. Simultaneous determination of arsenic, cadmium and lead in plant foods by ICP-MS combined with automated focused infrared ashing and cold trap[J]. Food Chem., 2018,264:462-470. doi: 10.1016/j.foodchem.2018.05.058
7. [7]
  TIGHE M, BIELSKI M, WILSON M, RUSCIO-ATKINSON G, PEASLEE G F, LIEBERMAN M. A sensitive XRF screening method for lead in drinking water[J]. Anal. Chem., 2020,92(7):4949-4953. doi: 10.1021/acs.analchem.9b05058
8. [8]
  XU J M, LIU M B, ZHAO W H, WANG S Q, GUI M F, LI H B, YU R Q. DNAzyme-based cascade signal amplification strategy for highly sensitive detection of lead ions in the environment[J]. J. Hazard. Mater., 2022,429128347. doi: 10.1016/j.jhazmat.2022.128347
9. [9]
  DU X X, LIU Y J, WANG F, ZHAO D Y, GLEESON H F, LUO D. A fluorescence sensor for Pb²⁺ detection based on liquid crystals and aggregation-induced emission luminogens[J]. ACS Appl. Mater. Inter-faces, 2021,13(19):22361-22367. doi: 10.1021/acsami.1c02585
10. [10]
  YANG C Y, YU P T, LI Y, WANG J Y, MA X Y, LIU N, LV T, ZHENG H R, WU H, LI H X, SUN C Y. Platform formed from ZIF-8 and DNAzyme: "Turn-on" fluorescence assay for simple, high-sensi-tivity, and high-selectivity detection of Pb²⁺[J]. J. Agric. Food Chem., 2022,70(30):9567-9576. doi: 10.1021/acs.jafc.2c03503
11. [11]
  NIU X F, ZHONG Y B, CHEN R, WANG F, LIU Y J, LUO D. A "turn-on" fluorescence sensor for Pb²⁺ detection based on graphene quantum dots and gold nanoparticles[J]. Sens. Actuator B -Chem., 2018,255:1577-1581. doi: 10.1016/j.snb.2017.08.167
12. [12]
  LIU T Q, WAN X J, YAO Y W. Dual sensitive and selective sensor for Pb²⁺ and Al³⁺ with distinctive fluorescence response[J]. Sens. Ac-tuator B-Chem., 2018,254:1094-1100. doi: 10.1016/j.snb.2017.07.114
13. [13]
  XUE T, SHI Y Y, GUO J, GUO M X, YAN Y. Preparation of AgInS₂ quantum dots and their application for Pb²⁺ detection based on fluo-rescence quenching effect[J]. Vacuum, 2021,193110514. doi: 10.1016/j.vacuum.2021.110514
14. [14]
  WANG H Y, MIAO L, ZHANG B L, SUN Y J, CHEN J, LIU S Q, ZHANG W Q, WANG T, ZHANG J J. Coordinated solvent mole-cules enable the excellent capabilities of two Zn²⁺-based complexes in detecting L-arginine via long-lived luminescence recovery[J]. Adv. Funct. Mater., 2024202403734.
15. [15]
  ZHANG B L, ZHANG P P, NI A Y, ZHANG J J, WANG H Y, FENG K X, LIU S Q, ZHAO Z B, DUAN C Y. Efficient, multicolored, and stable room-temperature phosphorescence doped materials based on a lead halide matrix: A coordination-driven doping strategy[J]. Adv. Opt. Mater., 2023,11(21)2300717. doi: 10.1002/adom.202300717
16. [16]
  JIN J B, JIANG H, YANG Q Q, TANG L I, TAO Y, LI Y Y, CHEN R F, ZHENG C, FAN Q L, ZHANG K Y, ZHAO Q, HUANG W. Thermally activated triplet exciton release for highly efficient tri-mode organic afterglow[J]. Nat. Commun., 2020,11(1)842. doi: 10.1038/s41467-020-14669-3
17. [17]
  YAN Z A, LIN X H, SUN S Y, MA X, TIAN H. Activating room-tem-perature phosphorescence of organic luminophores via external heavy-atom effect and rigidity of ionic polymer matrix[J]. Angew. Chem.-Int. Edit., 2021,60(36):19735-19739. doi: 10.1002/anie.202108025
18. [18]
  CHEN T H, MA Y J, YAN D P. Single-component 0D metal-organic halides with color-variable long-afterglow toward multi-level informa-tion security and white-light LED[J]. Adv. Funct. Mater., 2023,33(18)2214962. doi: 10.1002/adfm.202214962
19. [19]
  LIU S Y, LIN Y H, YAN D P. Dynamic multi-color long-afterglow and cold-warm white light through phosphorescence resonance energy transfer in host-guest metal-organic frameworks[J]. Sci. Chin. Chem., 2023,66(12):3532-3538. doi: 10.1007/s11426-023-1656-y
20. [20]
  XING C, ZHOU B, YAN D P, FANG W H. Integrating full-color 2D optical waveguide and heterojunction engineering in halide microsheets for multichannel photonic logical gates[J]. Adv. Sci., 2024,11(17)202310262.
21. [21]
  TIAN S A, MA H L, WANG X, LV A Q, SHI H, GENG Y, LI J, LIANG F S, SU Z M, AN Z F, HUANG W. Utilizing d-pπ bonds for ultralong organic phosphorescence[J]. Angew. Chem. -Int. Edit., 2019,58(20):6645-6649. doi: 10.1002/anie.201901546
22. [22]
  YANG Z, XU C, LI W L, MAO Z, GE X Y, HUANG Q Y, DENG H J, ZHAO J, GU F L, ZHANG Y, CHI Z G. Boosting the quantum effi-ciency of ultralong organic phosphorescence up to 52% via intramo-lecular halogen bonding[J]. Angew. Chem. -Int. Edit., 2020,59(40):17451-17455. doi: 10.1002/anie.202007343
23. [23]
  YANG Y S, WANG K Z, YAN D P. Ultralong persistent room tem-perature phosphorescence of metal coordination polymers exhibiting reversible pH-responsive emission[J]. ACS Appl. Mater. Interfaces, 2016,8(24):15489-15496. doi: 10.1021/acsami.6b03956
24. [24]
  WIBOWO A H, SURYANDARI Y, MASYKUR A, PÉREZ-YÁÑEZ S, RODRíGUEZ-DIÉGUEZ A, CEPEDA J. Zinc/itaconate coordina-tion polymers as first examples with long-lasting phosphorescence based on acyclic ligands[J]. J. Mater. Chem. C, 2018,6(40):10870-10880. doi: 10.1039/C8TC03598A
25. [25]
  YIN Y J, ZHAO H, ZHANG L W, HUANG J X, ZHANG J J, CHEN J, NI J, SONG B, LIU S Q, DUAN C Y. Color-tunable long-lived room-temperature phosphorescence in a coordination polymer based on a nonaromatic ligand and its phosphor/coordination polymer-doped systems[J]. Chem. Mater., 2021,33(18):7272-7282. doi: 10.1021/acs.chemmater.1c01514
26. [26]
  LUCENTI E, FORNI A, BOTTA C, CARLUCCI L, GIANNINI C, MARINOTTO D, PAVANELLO A, PREVITALI A, RIGHETTO S, CARIATI E. Cyclic triimidazole derivatives: Intriguing examples of multiple emissions and ultralong phosphorescence at room tempera-ture[J]. Angew. Chem.-Int. Edit., 2017,56(51):16302-16307. doi: 10.1002/anie.201710279
27. [27]
  LI M K, CAI X Y, CHEN Z J, LIU K K, QIU W D, XIE W T, WANG L Y, SU S J. Boosting purely organic room-temperature phosphores-cence performance through a host-guest strategy[J]. Chem. Sci., 2021,12(40):13580-13587. doi: 10.1039/D1SC03420K
28. [28]
  SHI H F, SONG L L, MA H L, SUN C, HUANG K W, LV A Q, YE W P, WANG H, CAI S Z, YAO W, ZHANG Y J, ZHENG R L, AN Z F, HUANG W. Highly efficient ultralong organic phosphorescence through intramolecular-space heavy-atom effect[J]. J. Phys. Chem. Lett., 2019,10(3):595-600. doi: 10.1021/acs.jpclett.8b03712
29. [29]
  ZHU C Y, WANG Z, MO J T, FAN Y N, PAN M. A long persistent phosphorescent metal-organic framework for multi-level sensing of oxygen[J]. J. Mater. Chem. C, 2020,8(29):9916-9922. doi: 10.1039/D0TC02391D
30. [30]
  XU S F, ZHAN L H, HONG C Y, CHEN X M, CHEN X, OYAMA M. Metal-organic framework-5 as a novel phosphorescent probe for the highly selective and sensitive detection of Pb(Ⅱ) in mussels[J]. Sens. Actuator B-Chem., 2020,308127733. doi: 10.1016/j.snb.2020.127733
31. [31]
  NIE Y J, CHEN X W, WANG Y Q, LAI W Q, ZHENG N, WENG W. Matrix-free nitrogen-doped carbon dots with room temperature phos-phorescence for information encryption and temperature detection[J]. Microchem. J., 2022,175107126. doi: 10.1016/j.microc.2021.107126
32. [32]
  ZHANG X P, LIU J K, CHEN B, HE X W, LI X Y, WEI P F, GAO P F, ZHANG G Q, LAM J W Y, TANG B Z. Highly efficient and persistent room temperature phosphorescence from cluster exciton enables ultrasensitive off-on VOC sensing[J]. Matter, 2022,5(10):3499-3512. doi: 10.1016/j.matt.2022.07.010
33. [33]
  ANDREWS N C. Iron metabolism: Iron deficiency and iron overload[J]. Annu. Rev. Genomics Hum., 2000,1:75-98. doi: 10.1146/annurev.genom.1.1.75
34. [34]
  FLEMING ROBERT E, PONKA P. Iron overload in human disease[J]. N. Engl. J. Med., 2012,366(4):348-359. doi: 10.1056/NEJMra1004967
35. [35]
  PASRICHA S R, TYE-DIN J, MUCKENTHALER M U, SWINKELS D W. Iron deficiency[J]. Lancet, 2021,397(10270):233-248. doi: 10.1016/S0140-6736(20)32594-0
36. [36]
  STOLTZFUS R J. Iron-deficiency anemia: Reexamining the nature and magnitude of the public health problem. Summary: Implications for research and programs[J]. J. Nutr., 2001,131(2S-2):697S-700S.
37. [37]
  HOU L L, SONG Y H, XIAO Y J, WU R, WANG L. ZnMOF-74 responsive fluorescence sensing platform for detection of Fe³⁺[J]. Microchem. J., 2019,150104154. doi: 10.1016/j.microc.2019.104154
38. [38]
  RUAN B, YANG J, ZHANG Y J, MA N, SHI D, JIANG T, TSAI F C. UiO-66 derivate as a fluorescent probe for Fe³⁺ detection[J]. Talanta, 2020,218121207. doi: 10.1016/j.talanta.2020.121207
39. [39]
  ÜÇÜNCÜ M. A phenalenone-based fluorescent probe for the detec-tion of Fe³⁺ions[J]. 2022, 33(2): 707-712
40. [40]
  LI Y J, ZHANG X J, WANG Z C, ZHAO L N, LI Y X. Highly sensi-tive Fe³⁺ luminescence detection via single-ion adsorption[J]. Chin. Chem. Lett., 2024,35(1)108532. doi: 10.1016/j.cclet.2023.108532
41. [41]
  CHEN Z E, ZANG X F, ZHANG H. An ethyl thioglycolate-based chemosensor: Spectrophotometric detection of Fe³⁺ and fluorometric detection of Hg²⁺ with high selectivity[J]. Spectroc. Acta Pt. A -Molec. Biomolec. Spectr., 2021,260119955. doi: 10.1016/j.saa.2021.119955
42. [42]
  VADIA F Y, GHOSH S, MEHTA V N, JHA S, MALEK N I, PARK T J, KAILASA S K. Fluorescence"turn off-on"detection of Fe³⁺ and propiconazole pesticide using blue emissive carbon dots from lemon peel[J]. Food Chem., 2023,428136796. doi: 10.1016/j.foodchem.2023.136796
43. [43]
  ALQADAMI A A, NAUSHAD M, ALOTHMAN Z A, ALSUHYBANI M, ALGAMDI M. Excellent adsorptive performance of a new nano-composite for removal of toxic Pb(Ⅱ) from aqueous environment: Adsorption mechanism and modeling analysis[J]. J. Hazard. Mater., 2020,389121896. doi: 10.1016/j.jhazmat.2019.121896
44. [44]
  VERPOORT F, HAEMERS T, ROOSE P, MAES J P. Characteriza-tion of a surface coating formed from carboxylic acid-based coolants[J]. Appl. Spectrosc., 1999,531528. doi: 10.1366/0003702991946262
45. [45]
  BROOKER M H, SUNDER S, TAYLOR P, LOPATA V J. Infrared and Raman spectra and X-ray diffraction studies of solid lead(Ⅱ) car-bonates[J]. Can. J. Chem., 2011,61(3):494-502.
46. [46]
  OTERO V, SANCHES D, MONTAGNER C, VILARIGUES M, CARLYLE L, LOPES J A, MELO M J. Characterisation of metal car-boxylates by Raman and infrared spectroscopy in works of art[J]. J. Raman Spectrosc., 2015,45(11/12):1197-1206.
47. [47]
  ZHANG X F, FENG L H, MA S Y, XIA T F, JIAO F F, KONG Z, DUAN X. A microporous Tb-based MOF for multifunctional detec-tion of the α-CHC, Cu²⁺ and Fe³⁺[J]. J. Solid State Chem., 2022,312123232. doi: 10.1016/j.jssc.2022.123232
48. [48]
  ZHAO F H, ZHAO Z H, LI Y S, FENG R, HAN T, HE Y C, LI Z L. Two diverse 3D 6-connected Cd(Ⅱ)/Co(Ⅱ) MOFs based on binuclear clusters as fluorescence sensors for detection of Fe³⁺, Cr₂O₇^2- and nitrobenzene[J]. J. Mol. Struct., 2024,1298137051. doi: 10.1016/j.molstruc.2023.137051
1. [1]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
2. [2]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
3. [3]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
4. [4]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
5. [5]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
6. [6]
  Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002
7. [7]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-. doi: 10.3866/PKU.WHXB202404023
8. [8]
  Jun LUO , Baoshu LIU , Yunchang ZHANG , Bingkai WANG , Beibei GUO , Lan SHE , Tianheng CHEN . Europium(Ⅲ) metal-organic framework as a fluorescent probe for selectively and sensitively sensing Pb²⁺ in aqueous solution. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2438-2444. doi: 10.11862/CJIC.20240240
9. [9]
  Yuan ZHU , Xiaoda ZHANG , Shasha WANG , Peng WEI , Tao YI . Conditionally restricted fluorescent probe for Fe³⁺ and Cu²⁺ based on the naphthalimide structure. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 183-192. doi: 10.11862/CJIC.20240232
10. [10]
  Yan ZHAO , Jiaxu WANG , Zhonghu LI , Changli LIU , Xingsheng ZHAO , Hengwei ZHOU , Xiaokang JIANG . Gd³⁺-doped Sc₂W3O₁₂: Eu³⁺ red phosphor: Preparation and luminescence performance. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 461-468. doi: 10.11862/CJIC.20240316
11. [11]
  Yan ZHAO , Xiaokang JIANG , Zhonghui LI , Jiaxu WANG , Hengwei ZHOU , Hai GUO . Preparation and fluorescence properties of Eu³⁺-doped CaLaGaO₄ red-emitting phosphors. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1861-1868. doi: 10.11862/CJIC.20240242
12. [12]
  Yanqiong Wang , Yaqi Hou , Fengwei Huo , Xu Hou . Fe³⁺ ion quantification with reusable bioinspired nanopores. Chinese Chemical Letters, 2025, 36(2): 110428-. doi: 10.1016/j.cclet.2024.110428
13. [13]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
14. [14]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
15. [15]
  Jinghan ZHANG , Guanying CHEN . Progress in the application of rare-earth-doped upconversion nanoprobes in biological detection. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2335-2355. doi: 10.11862/CJIC.20240249
16. [16]
  Weiping Guo , Ying Zhu , Hong-Hua Cui , Lingyun Li , Yan Yu , Zhong-Zhen Luo , Zhigang Zou . β-Pb₃P₂S₈: A new optical crystal with exceptional birefringence effect. Chinese Chemical Letters, 2025, 36(2): 110256-. doi: 10.1016/j.cclet.2024.110256
17. [17]
  Mingxin LU , Liyang ZHOU , Xiaoyu XU , Xiaoying FENG , Hui WANG , Bin YAN , Jie XU , Chao CHEN , Hui MEI , Feng GAO . Preparation of La-doped lead-based piezoelectric ceramics with both high electrical strain and Curie temperature. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 329-338. doi: 10.11862/CJIC.20240206
18. [18]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
19. [19]
  Xianghai Song , Xiaoying Liu , Zhixiang Ren , Xiang Liu , Mei Wang , Yuanfeng Wu , Weiqiang Zhou , Zhi Zhu , Pengwei Huo . Insights into the greatly improved catalytic performance of N-doped BiOBr for CO₂ photoreduction. Acta Physico-Chimica Sinica, 2025, 41(6): 100055-. doi: 10.1016/j.actphy.2025.100055
20. [20]
  Yuchen Guo , Xiangyu Zou , Xueling Wei , Weiwei Bao , Junjun Zhang , Jie Han , Feihong Jia . Fe regulating Ni3S2/ZrCoFe-LDH@NF heterojunction catalysts for overall water splitting. Chinese Journal of Structural Chemistry, 2024, 43(2): 100206-100206. doi: 10.1016/j.cjsc.2023.100206

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(66)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of zinc sulfate open frameworks based probe materials and detection of Pb2+ and Fe3+ ions

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of zinc sulfate open frameworks based probe materials and detection of Pb²⁺ and Fe³⁺ ions