Citation: Chen LU, Qinlong HONG, Haixia ZHANG, Jian ZHANG. Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407 shu

Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials

Fujian Institute of Research on the Structure, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Haixia ZHANG, zhanghaixia@fjirsm.ac.cn Jian ZHANG, zhj@fjirsm.ac.cn
Received Date: 30 October 2024
Revised Date: 27 December 2024

Figures(4)

Two examples of copper-iodine cluster-based boron imidazolate framework (BIFs) were obtained using cuprous iodide, pre-synthesized boron imidazolate ligands, and quaternary ammonium salts. Their structures and properties were characterized. X-ray single crystal diffraction results show that [N(C₄H₉)₄]{Cu₆I₆[BH(im)₃]Cu[BH(im)₃]}·0.5CH₃OH (BIF-155, im=imidazolate) is a (3, 4)-connected two-dimensional layer network formed by alternately connecting four-connected Cu₆I₆ clusters, single core Cu atoms and triple-connected boron imidazolate ligands BH(im)₃^-. [N(C₄H₉)₄]{Cu₃I₃ [BH(im)₃]} (BIF-156) is a 3-connected two-dimensional layer network with fes topology obtained by connecting Cu₃I₃ clusters and BH(im)₃^- boronazole ligands. The corresponding crystals of the two compounds had good crystallinity. Under ultraviolet lamp illumination, the two showed different fluorescence properties, that is, BIF-155 emited red light and BIF-156 emited yellow light.
- copper iodide cluster,
- boron imidazolate framework,
- fluorescence
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