Citation: Hexing SONG, Zan SUN. Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402 shu

Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid

Hexing SONG ,
Zan SUN ^,

School of Chemistry and Materials Science, Qinghai Minzu University, Xining 810007, China

Corresponding author: Zan SUN, sunzan_2006@126.com
Received Date: 10 November 2024
Revised Date: 30 March 2025

Figures(5)

Under hydrothermal conditions, a manganese complex [Mn(na)₂(Dmbpy)(H₂O)]·Hna (1) was synthesized by using manganese sulfate, 1-naphthoic acid (Hna), and 4,4'-dimethyl-2, 2'-bipyridine (Dmbpy), and characterized by elemental analysis, single crystal X ray diffraction, powder X ray diffraction, infrared spectrum, Hirshfeld surface analysis, and thermogravimetric analysis. The single-crystal X-ray diffraction result shows that 1 belongs to the triclinic crystal system, $P \overline{1}$ space group, and the central metal Mn(Ⅱ) is located in a six-coordinated, distorted trigonal prism configuration. The 2D supramolecular network structure is formed by intermolecular C/O—H···O, C—H···π, and π···π interactions. CrystalExplorer was used to analyze the Hirshfeld surface of 1. The 2D fingerprint of 1 shows that the H···H interaction plays a significant role in maintaining structural stability. Powder X-ray diffraction analysis shows that the synthesized 1 is in pure phase. Thermogravimetric analysis shows that 1 has good thermal stability. The solid-state fluorescence spectrum showed that 1 had a maximum emission wavelength of 423 nm at an excitation wavelength of 347 nm. In the fluorescence sensing experiment, 1 showed selective recognition ability to Fe³⁺ with a detection limit of 0.52 μmol·L^-1. In addition, the mechanism analysis shows that the fluorescence quenching of 1 may be due to the energy-competitive absorption between Fe³⁺ and 1.
- Mn(Ⅱ) complex,
- crystal structure,
- Hirshfeld surface analysis,
- solid-state emission,
- fluorescence sensing,
- Fe³⁺
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Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe3+ of an Mn(Ⅱ) complex based on 1-naphthalic acid

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通讯作者: 陈斌, bchen63@163.com

Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid