Citation: Yi DING, Peiyu LIAO, Jianhua JIA, Mingliang TONG. Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393 shu

Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates

Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Institute of Green Chemistry and Molecular Engineering, Sun Yat⁃Sen University, Guangzhou 510006, China

Corresponding author: Jianhua JIA, jiajh3@mail.sysu.edu.cn Mingliang TONG, tongml@mail.sysu.edu.cn
Received Date: 1 November 2024
Revised Date: 1 December 2024

Figures(4)

1, 1, 2, 2-Tetra(pyridin-4-yl)ethene (TEPE) was chosen as a bridging ligand to assemble with Ag(Ⅰ) ions to form the cationic frameworks. And, the pentafluoro-benzoate anions (PFB^-) and the benzoate (Bz^-) anions as guests were introduced respectively to generate two new coordination compounds: [Ag(TEPE)(H₂O)](PFB)·7H₂O·3EtOH (1) and [Ag(TEPE)](Bz)·4H₂O·2EtOH (2). The compositions and structures of complexes 1 and 2 were characterized using the thermogravimetric analysis, IR spectra, and single-crystal X-ray diffraction analysis. 1 possesses a 2D brick-like coordination layer structure with the classical hcb topology, each Ag(Ⅰ) center is coordinated with an aqua ligand and three N atoms from three TEPE ligands respectively, forming the distorted tetrahedral coordination geometry. The PFB^- guests are distributed between the 2D layers to form diverse interactions with the main framework. 2 presents a 3D coordination network structure with the sqc8116 topology, in which each Ag(Ⅰ) center is coordinated in a tetrahedral geometry with four N atoms from four TEPE ligands respectively, and Bz^- guests are located at the larger channels along the c-axis. Interestingly, two complexes showed the characteristic fluorescent properties regulated by photoactive guests. Excited by UV light, 1 exhibited a red emission while 2 showed a blue emission.
- 1, 1, 2, 2-tetra(pyridin-4-yl)ethene,
- benzoate,
- metal-organic framework,
- silver(Ⅰ),
- photoluminescence
1. [1]
  WANG Q, ASTRUC D. State of the art and prospects in metal-organic framework (MOF)-based and MOF-derived nanocatalysis[J]. Chem. Rev. , 2019, 120(2): 1438-1511
2. [2]
  LIU J, GOETJEN T A, WANG Q N, KNAPP J G, WASSON M C, YANG Y, SYED Z H, DELFERRO M, NOTESTEIN J M, FARHA O K, HUPP J T. MOF-enabled confinement and related effects for chemical catalyst presentation and utilization[J]. Chem. Soc. Rev. , 2022, 51(3): 1045-1097 doi: 10.1039/D1CS00968K
3. [3]
  REN J W, LANGMI H W, NORTH B C, MATHE M. Review on processing of metal-organic framework (MOF) materials towards system integration for hydrogen storage[J]. Int. J. Energy Res. , 2015, 39(5): 607-620 doi: 10.1002/er.3255
4. [4]
  QIAN Q H, ASINGER P A, LEE M J, HAN G, RODRIGUEZ K M, LIN S, BENEDETTI F M, WU A X, CHI W S, SMITH Z P. MOF-based membranes for gas separations[J]. Chem. Rev. , 2020, 120(16): 8161-8266 doi: 10.1021/acs.chemrev.0c00119
5. [5]
  LI B Z, SUO T Y, XIE S Y, XIA A Q, MA Y J, HUANG H, ZHANG X, HU Q. Rational design, synthesis, and applications of carbon dots@metal-organic frameworks (CD@MOF) based sensors[J]. TrAC‒Trends Anal. Chem. , 2021, 135: 116163 doi: 10.1016/j.trac.2020.116163
6. [6]
  HALDAR R, BHATTACHARYYA S, MAJI T K. Luminescent metal-organic frameworks and their potential applications[J]. J. Chem. Sci. , 2020, 132: 1-25 doi: 10.1007/s12039-019-1689-3
7. [7]
  TANG Y, WU H L, CAO W Q, CUI Y J, QIAN G D. Luminescent metal-organic frameworks for white LEDs[J]. Adv. Opt. Mater. , 2021, 9(23): 2001817 doi: 10.1002/adom.202001817
8. [8]
  ZHOU H, HAN J J, CUAN J, ZHOU Y. Responsive luminescent MOF materials for advanced anticounterfeiting[J]. Chem. Eng. J. , 2022, 431(Part 2): 134170
9. [9]
  YANG G L, JIANG X L, XU H, ZHAO B. Applications of MOFs as luminescent sensors for environmental pollutants[J]. Small, 2021, 17(22): 2005327 doi: 10.1002/smll.202005327
10. [10]
  LI Y. Temperature and humidity sensors based on luminescent metal-organic frameworks[J]. Polyhedron, 2020, 179: 114413 doi: 10.1016/j.poly.2020.114413
11. [11]
  WHELAN É, STEUBER F W, GUNNLAUGSSON T, SCHMITT W. Tuning photoactive metal-organic frameworks for luminescence and photocatalytic applications[J]. Coord. Chem. Rev., 2021, 437: 213757 doi: 10.1016/j.ccr.2020.213757
12. [12]
  RAZAVI S A A, MORSALI A. Metal ion detection using luminescent-MOFs: Principles, strategies and roadmap[J]. Coord. Chem. Rev. , 2020, 415: 213299 doi: 10.1016/j.ccr.2020.213299
13. [13]
  LIU J Q, WU J, LI F M, LIU W C, LI B H, WANG J, LI Q L, YADAV R, KUMAR A. Luminescent sensing from a new Zn(Ⅱ) metal-organic framework[J]. RSC Adv. , 2016, 6(37): 31161-31166 doi: 10.1039/C6RA01709F
14. [14]
  ZHANG D S, GAO Q, CHANG Z, LIU X T, ZHAO B, XUAN Z H, HU T L, ZHANG Y H, ZHU J, BU X H. Rational construction of highly tunable donor-acceptor materials based on a crystalline host-guest platform[J]. Adv. Mater. , 2018, 30(50): 1804715 doi: 10.1002/adma.201804715
15. [15]
  CHANG Z. Recent progress in host-guest metal-organic frameworks: Construction and emergent properties[J]. Coord. Chem. Rev. , 2023, 476: 214921 doi: 10.1016/j.ccr.2022.214921
16. [16]
  KHAN S B, LEE S. Supramolecular chemistry: Host-guest molecular complexes[J]. Molecules, 2021, 26(13): 3995 doi: 10.3390/molecules26133995
17. [17]
  KHATUA S, BISWAS P. Flexible luminescent MOF: Trapping of less stable conformation of rotational isomers, in situ guest-responsive turn-off and turn-on luminescence and mechanistic study[J]. ACS Appl. Mater. Interfaces, 2020, 12(19): 22335-22346 doi: 10.1021/acsami.0c02891
18. [18]
  PAL T K. Metal-organic framework (MOF)-based fluorescence "turn-on" sensors[J]. Mater. Chem. Front. , 2023, 7(3): 405-441 doi: 10.1039/D2QM01070D
19. [19]
  LIAO P Y, LI J X, LIU J C, XIONG Q, RUAN Z Y, LI T, DENG W, JIANG S D, JIA J H, TONG M L. Radical-induced photochromic silver(Ⅰ) metal-organic frameworks: alternative topology, dynamic photoluminescence and efficient photothermal conversion modulated by anionic guests[J]. Angew. Chem. Int. Ed. , 2024, 136(27): e202401448 doi: 10.1002/ange.202401448
20. [20]
  SANG X, LIU Q, LANG J P. Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands[J]. Chinese J. Inorg. Chem. , 2024, 40(11): 2124-2132
21. [21]
  DU L Y, SHI W J, HOU L, WANG Y Y, SHI Q Z, ZHU Z H. Solvent or temperature induced diverse coordination polymers of silver(Ⅰ) sulfate and bipyrazole systems: Syntheses, crystal structures, luminescence, and sorption properties[J]. Inorg. Chem. , 2013, 52(24): 14018-14027 doi: 10.1021/ic401765r
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