Citation: Jiming XI, Yukang TENG, Rui ZHANG, Zhenzhong LU. Fluorescent coordination polymers based on anthracene-and pyrene-derivative ligands[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(5): 847-854. doi: 10.11862/CJIC.20240367 shu

Fluorescent coordination polymers based on anthracene-and pyrene-derivative ligands

Jiming XI ^{1, 2} ,
Yukang TENG ² ,
Rui ZHANG ^1,, ,
Zhenzhong LU ²

1.
School of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Anhui 234000, China
2.
School of Flexible Electronics (Future Technologies) & Institute of Advanced Materials (IAM), Nanjing Tech University, Nanjing 211800, China

Corresponding author: Rui ZHANG, chemzr@126.com
Received Date: 13 October 2024
Revised Date: 31 March 2025

Figures(8)

We report five coordination polymers (CPs) based on fluorescent ligands [1, 6-di(1H-imidazol-1-yl)pyrene (dip), 9, 10-di(1H-imidazol-1-yl)anthracene (dia)] and anionic ligands [cyclohexane-1, 4-dicarboxylic acid (H₂cda), camphoric acid (H₂cpa)]. In [Cd(dip)(cda)]·4H₂O}_n (1), the Cd²⁺ ions, acting as tetrahedral nodes, are linked by dip and cda^2- ligands with four Cd²⁺ ions into five-fold interpenetrating network array of topology of dia. In {[Cd(dip) (cpa)]·4H₂O}_n (2), the Cd²⁺ ions, acting as a 4-connector, are linked by cpa^2- and dip ligands into a 3D framework of cds topology. In {[Ni(dia)₂Cl₂]·DMF}_n (3), the Ni²⁺ ion is linked by four dia ligands into a layer structure, and 1D channels of a cross-section of 1.35 nm×0.96 nm are formed. In {[Cd(dia)₂(H₂O)₂](NO₃)₂·2DMSO}_n (4), the dia ligands connected Cd²⁺ ions into a 2D layer, and 1D channels are formed between adjacent layers with a cross-section of 0.87 nm×0.43 nm. In [Zn(dip)Cl₂]_n (5), the Zn²⁺ ion is linked by dip ligands into an infinite 1D chain. The infrared, thermal gravimetric, and fluorescent emission data were collected and analyzed for these coordination polymers.
- coordination polymer,
- anthracene derivatives,
- pyrene derivatives,
- fluorescence
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