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Citation: Juan CHEN, Guoyu YANG. A porous-layered aluminoborate built by mixed oxoboron clusters and AlO4 tetrahedra[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(1): 193-200. doi: 10.11862/CJIC.20240341 shu

A porous-layered aluminoborate built by mixed oxoboron clusters and AlO4 tetrahedra

  • MOE Key Laboratory of Cluster Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, China

  • Corresponding author: Guoyu YANG, ygy@bit.edu.cn
  • Received Date: 18 September 2024
    Revised Date: 29 November 2024

Figures(7)

  • An aluminoborate, Na2.5Rb[Al{B5O10}{B3O5}]·0.5NO3·H2O (1), was synthesized under hydrothermal condition, which was built by mixed oxoboron clusters and AlO4 tetrahedra. In the structure, the [B5O10]5- and [B3O7]5- clusters are alternately connected to form 1D [B8O15]n6n- chains, which are further linked by AlO4 units to form a 2D monolayer with 7-membered ring and 10-membered ring windows. Two adjacent monolayers with opposite orientations further form a porous-layered structure with six channels through B—O—Al bonds. Compound 1 was characterized by single crystal X-ray diffraction, powder X-ray diffraction (PXRD), IR spectroscopy, UV-Vis diffuse reflection spectroscopy, and thermogravimetric analysis (TGA), respectively. UV-Vis diffuse reflectance analysis indicates that compound 1 shows a wide transparency range with a short cutoff edge of 201 nm, suggesting it may have potential application in UV regions.
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