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Citation: Qinjin DAI, Shan FAN, Pengyang FAN, Xiaoying ZHENG, Wei DONG, Mengxue WANG, Yong ZHANG. Performance of oxygen vacancy-rich V-doped MnO2 for high-performance aqueous zinc ion battery[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326 shu

Performance of oxygen vacancy-rich V-doped MnO2 for high-performance aqueous zinc ion battery

  • College of Material Science and Engineering, Qiqihar University, Qiqihar, Heilongjiang 106000, China

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  • V-doped MnO2 (VMO) was prepared as the aqueous zinc ion battery (ZIB) cathode by a simple hydrothermal method and its electrochemical performance was tested. The material characterization and electrochemical performance test indicated that the bismuth was evenly incorporated into MnO2. V doping expanded the interlayer spacing of MnO2, increased the specific surface area, and improved its internal ionic conductivity. The initial discharge capacity of the assembled ZIB reached 362 mAh·g-1 at a current density of 0.1 A·g-1. The doping of V made the lattice structure of MnO2 more stable, weakened the Jahn-Teller distortion effect, and improved the structural stability of the electrode material. The specific capacity remained 87% of the initial stage after 300 cycles at a 1 A·g-1 current density.
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