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Citation: Yan ZHAO, Jiaxu WANG, Zhonghu LI, Changli LIU, Xingsheng ZHAO, Hengwei ZHOU, Xiaokang JIANG. Gd3+-doped Sc2W3O12: Eu3+ red phosphor: Preparation and luminescence performance[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(3): 461-468. doi: 10.11862/CJIC.20240316 shu

Gd3+-doped Sc2W3O12: Eu3+ red phosphor: Preparation and luminescence performance

  • Condensed Phase Transition and Microstructure Laboratory, College of Physics Science and Technology, Yili Normal University, Yining, Xinjiang 835000, China

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  • A series of red-emitting phosphors, specifically Eu3+-doped Sc2W3O12, were synthesized using the sol-gel method. Furthermore, the symmetry of the Sc2W3O12 matrix crystal structure was diminished through Gd3+ doping, thereby enhancing the luminescence intensity of the phosphor. The findings indicate that incorporating Gd3+ did not alter the intrinsic crystal structure of Sc2W3O12. As the doping concentration of Gd3+ increased, the lattice distortion became more pronounced, resulting in a significant enhancement of the luminescence intensity corresponding to the 5D0→7F2 transition (612 nm) from Eu3+. The optimal doping concentration of Gd3+ was determined to be 0.25, yielding a luminescence intensity that was 1.95 times greater than that of solely Eu3+-doped samples. Additionally, the color coordinates (0.613 4, 0.350 3) were near the standard red color coordinates (0.670, 0.330). Furthermore, the fluorescent powder exhibited notable thermal stability; specifically, when the temperature reached 498 K, the fluorescence intensity of the sample with a Gd3+ ion concentration of 0.25 was enhanced compared to that of undoped Gd3+ ions, achieving 53% of its value at room temperature. Additionally, its activation energy was measured at 0.104 1 eV.
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