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Citation: Chang LIU, Chao ZHANG, Tongbu LU. Small-size Au nanoparticles anchored on pyrenyl-graphdiyne for N2 electroreduction[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(1): 174-182. doi: 10.11862/CJIC.20240305 shu

Small-size Au nanoparticles anchored on pyrenyl-graphdiyne for N2 electroreduction

  • Institute for New Energy Materials and Low Carbon Technologies, School of Materials Science & Engineering, Tianjin University of Technology, Tianjin 300384, China

  • Corresponding author: Tongbu LU, lutongbu@tjut.edu.cn
  • Received Date: 14 August 2024
    Revised Date: 17 November 2024

Figures(4)

  • A gold catalyst of Au/ pyrenyl-graphdiyne (Pyr-GDY) was prepared by anchoring small size of gold nanoparticles (Au NPs) on the surface of Pyr-GDY for electrocatalytic nitrogen reduction reaction (eNRR), in which Au NPs with a size of approximately 3.69 nm was evenly distributed on spongy-like porous Pyr-GDY. The catalyst exhibited a good electrocatalytic activity for N2 reduction in a nitrogen-saturated electrolyte, with an ammonia yield of 32.1 μg·h-1·mgcat-1 at -0.3 V (vs RHE), 3.5 times higher than that of Au/C (Au NPs anchored on carbon black). In addition, Au/Pyr-GDY showed a Faraday efficiency (FE) of 26.9% for eNRR, and a good catalysis durability for over 22 h.
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