Citation: Xiaxia LIU, Xiaofang MA, Luxia GUO, Xianda HAN, Sisi FENG. Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269 shu

Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands

1.
School of Energy Engineering, Shanxi College of Technology, Shuozhou, Shanxi 036000, China
2.
School of Materials Engineering, Shanxi College of Technology, Shuozhou, Shanxi 036000, China
3.
Key Laboratory of Chemical Biology and Molecular Engineering of the Education Ministry, Institute of Molecular Science, Shanxi University, Taiyuan 030006, China

Received Date: 16 July 2024
Revised Date: 11 November 2024

Figures(6)

Two new Mn(Ⅱ) coordination polymers, namely {[Mn₂(HL)(phen)₃(H₂O)₂]·7.5H₂O}_n (1) and [Mn₄(HL)₂(1, 4-bib)₃(H₂O)₂]_n (2), were synthesized under hydrothermal conditions by using Mn(Ⅱ) ions and 6-(3′, 4′-dicarboxylphenoxy)-1, 2, 4-benzenetricarboxylic acid (H₅L) in the presence of N-auxiliary ligands 1, 10-phenanthroline (phen) and 1, 4-bis(1H-imidazol-1-yl)benzene (1, 4-bib). The structures of coordination polymers 1 and 2 were characterized by infrared spectroscopy, single-crystal X-ray diffraction, thermogravimetric analysis, and powder X-ray diffraction. Single-crystal X-ray diffraction reveals that 1 has a 1D chain structure based on binuclear Mn(Ⅱ) units, while 2 features a (3, 8)-connected 3D network structure based on tetranuclear Mn(Ⅱ) units. Magnetic studies show that 1 and 2 exhibit antiferromagnetic interactions between manganese ions. 2 shows stronger antiferromagnetic interactions due to the shorter Mn…Mn distances within the tetranuclear manganese units.
- coordination polymers,
- crystal structures,
- binuclear Mn(Ⅱ) unit,
- tetranuclear Mn(Ⅱ) unit,
- magnetism
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沈阳化工大学材料科学与工程学院沈阳 110142