Citation: Ke QIAO, Yanlin LI, Shengli HUANG, Guoyu YANG. Advancements in asymmetric catalysis employing chiral iridium (ruthenium) complexes[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(11): 2091-2104. doi: 10.11862/CJIC.20240265 shu

Advancements in asymmetric catalysis employing chiral iridium (ruthenium) complexes

Ke QIAO ¹ ,
Yanlin LI ² ,
Shengli HUANG ^1,, ,
Guoyu YANG ¹

1.
College of Chemistry and Chemical Industry, Beijing Institute of Technology, Beijing 102488, China
2.
China ENFI Engineering Corporation, Beijing 100038, China

Corresponding author: Shengli HUANG, huangsl@bit.edu.cn
Received Date: 12 July 2024
Revised Date: 12 October 2024

Figures(16)

Developing asymmetric catalysts derived solely from octahedral centrochirality has garnered significant attention in the scientific community. Chiral-octahedral metal complexes can be classified into stereogenic-only-at-metal complexes and stereogenic-at-metal complexes with chiral ligands. This review introduces the design and syn-thesis of chiral-octahedral iridium and ruthenium complexes, which can be fine-tuned by altering the metal center, ligand combinations, and the chirality or achirality of the ligands. The applications of these complexes in asymmetric catalysis are then explored, considering catalysis via metal binding and catalysis via the ligand sphere. Addition-ally, the potential of using octahedral chiral metal complexes as building units for supramolecular structures and their integration with asymmetric catalysis are discussed, suggesting promising perspectives for broader applications.
- chirality,
- asymmetric catalysis,
- cyclometalated Ir(Ⅲ),
- polypyridyl Ru(Ⅱ)
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