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Citation: Yinling HOU, Jia JI, Hong YU, Xiaoyun BIAN, Xiaofen GUAN, Jing QIU, Shuyi REN, Ming FANG. A rhombic Dy4-based complex showing remarkable single-molecule magnet behavior[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251 shu

A rhombic Dy4-based complex showing remarkable single-molecule magnet behavior

  • 1.

    Key Laboratory of Preparation and Application of Micro & Mesoporous Nanomaterials of Guizhou Province, Kaili University, Kaili, Guizhou 556011, China

  • 2.

    Department of Chemistry, Hebei Normal University of Science & Technology, Qinhuangdao, Hebei 066004, China

  • 3.

    College of Chemistry and Materials, Taiyuan Normal University, Jinzhong, Shanxi 030619, China

Figures(6)

  • A tetranuclear Ln(Ⅲ)-based complex: [Dy4(dbm)4(L)6(μ3-OH)2]·CH3CN (1) (HL=5-[(4-methylbenzylidene)amino]quinolin-8-ol, Hdbm=dibenzoylmethane) was manufactured and its structure was characterized in detail. X-ray diffraction analysis shows that complex 1 belongs to the monoclinic crystal system and its space group is P21/n, which contains a rhombic Dy4 core. Magnetic measurements of 1 suggest it possesses extraordinary single-molecule magnet (SMM) behavior. Its energy barrier Ueff/kB was 116.7 K, and the pre-exponential coefficient τ0=1.05×10-8 s.
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