Citation: Peipei CUI, Xin LI, Yilin CHEN, Zhilin CHENG, Feiyan GAO, Xu GUO, Wenning YAN, Yuchen DENG. Transition metal coordination polymers with flexible dicarboxylate ligand: Synthesis, characterization, and photoluminescence property[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(11): 2221-2231. doi: 10.11862/CJIC.20240234 shu

Transition metal coordination polymers with flexible dicarboxylate ligand: Synthesis, characterization, and photoluminescence property

Peipei CUI ^1,, ,
Xin LI ¹ ,
Yilin CHEN ¹ ,
Zhilin CHENG ¹ ,
Feiyan GAO ¹ ,
Xu GUO ¹ ,
Wenning YAN ^2,, ,
Yuchen DENG ^3,,

1.
School of Life Science, Dezhou University, Dezhou, Shandong 253023, China
2.
School of Energy and Mechanical Engineering, Dezhou University, Dezhou, Shandong 253023, China
3.
School of Chemistry and Chemical Engineering, Dezhou University, Dezhou University, Dezhou, Shandong 253023, China

Corresponding author: Peipei CUI, 1cuipeipei1@163.com Wenning YAN, yanleng@126.com Yuchen DENG, dengyuchen816@163.com
Received Date: 23 June 2024
Revised Date: 9 September 2024

Figures(8)

Under solvothermal conditions, six new coordination polymers (CPs) [Mn(L) (phen) (H₂O)]_n (1), [Co(L) (phen)(H₂O)]_n (2), [Cu(L)(phen)(H₂O)]_n (3), [Zn₂(L)₂(phen)₂(H₂O)]_n (4), [Zn(L)(phen)]_n (5), and [Cd(L)(phen)₂]_n (6) were synthesized by reactions of dicarboxylate ligand 2, 2'-(1, 2-phenylenebis(methylene))bis(sulfanediyl)dinobutyric acid (H₂L) and 1, 10-phenanthroline (phen) with the corresponding metal salts. Complexes 1-6 have been structurally characterized by single-crystal X-ray diffraction analyses, elemental analysis, IR, thermogravimetric analysis, and powder X-ray diffraction. The structures of 1-6 are 1D chains, which are further connected by hydrogen bonding interactions to form 3D supramolecular structures. Among them, 1 and 2 are isomorphic with L^2- of syn-conformation, while L^2- shows anti-conformation in 3-6. In addition, the solid-state photoluminescence property of 4-6 was investigated.
- flexible dicarboxylate ligand,
- coordination polymers,
- hydrogen bonding interaction,
- conformation,
- photoluminescence property
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