Citation: Yiping HUANG, Liqin TANG, Yufan JI, Cheng CHEN, Shuangtao LI, Jingjing HUANG, Xuechao GAO, Xuehong GU. Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224 shu

Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation

1.
China Construction Industrial & Energy Engineering Group Co., Ltd., Nanjing 210023, China
2.
State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China

Corresponding author: Xuechao GAO, xuechao.gao@njtech.edu.cn Xuehong GU, xhgu@njtech.edu.cn
Received Date: 21 May 2024
Revised Date: 21 September 2024

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This work investigated the deep dehydration process of ethanol solvent by vapor permeation technique of hollow fiber supported NaA zeolite membrane using the combined operations of N₂ sweeping and vacuum suction. The results indicated sweeping gas plays a dominant role in the deep dehydration of ethanol. Compared with the case without any sweeping (under an operation temperature of 100 ℃ and a feeding liquid flow rate of 30 mL·min^-1), the N₂ sweeping with a flow rate of 60 mL·min^-1 could promote the membrane dehydration efficiency by several folds, where the production efficiency was enhanced by 43% to obtain the ethanol with ultra-low water content of 0.04%. For a higher operation temperature of 120 ℃, the water content in ethanol could be further reduced to 0.068‰ when the feeding liquid flow rate increased to 50 mL·min^-1, where the harvest percentage was high up to 99.86%.
- hollow fiber NaA zeolite membrane,
- vapor permeation,
- deep dehydration of ethanol,
- N₂ sweeping
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沈阳化工大学材料科学与工程学院沈阳 110142