Citation: Zhuo WANG, Xiaotong LI, Zhipeng HU, Junqiao PAN. Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223 shu

Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties

Guangzhou Greater Bay Technology Co., Ltd., Guangzhou 510000, China

Corresponding author: Zhuo WANG, wangzhuo@gbtrnd.com Xiaotong LI, lixiaotong@gbtrnd.com
Received Date: 13 June 2024
Revised Date: 17 October 2024

Figures(7)

Bi nanoparticles were decorated on three-dimensional porous carbon (3DPC) to prepare Bi/3DPC composite, in which the 3DPC acts as a carbon framework to buffer the volume expansion of the material during discharging and charging and to enhance the electrical conductivity of the material. Besides, the micropores and mesopores of 3DPC can increase the specific surface area of the material and provide active sites for the adsorption of sodium ions. Constructing nanoscale bismuth particles cushions the structural destruction during charge and discharge processes. The impedance decreased after 50 cycles at 0.5 A·g^-1, which indicates good long-term cycle stability of Bi/ 3DPC composite. And the charge storage mechanism of the materials was explored by performing cycle voltammetry tests at different scan rates, where capacitance behavior predominated. Meanwhile, Bi nanoparticles and the 3DPC take advantage of the synergistic effect, showing longterm cycle stability in sodium ion batteries. When placed under the current density of 5 A·g^-1, Bi/3DPC maintained a capacity of 268.52 mAh·g^-1 after 1 000 cycles.
- three-dimensional porous carbon,
- bismuth,
- sodium-ion battery,
- anode material
1. [1]
  WANG J W, LIU X H, MAO S X, HUANG J Y. Microstructural evolution of tin nanoparticles during in situ sodium insertion and extraction[J]. Nano Lett., 2012,12(11):5897-5902. doi: 10.1021/nl303305c
2. [2]
  DARWICHE A, MARINO C, SOUGRATI M T, FRAISSE B, STIEVANO L, MONCONDUIT L. Better cycling performances of bulk Sb in Na-ion batteries compared to Li-ion systems: An unexpected electrochemical mechanism[J]. J. Am. Chem. Soc., 2012,134(51):20805-20811. doi: 10.1021/ja310347x
3. [3]
  KUBOTA K, DAHBI M, HOSAKA T, KUMAKURA S, KOMABA S. Towards K-ion and Na-ion batteries as "beyond Li ion"[J]. Chem. Rec., 2018,18(4):459-479. doi: 10.1002/tcr.201700057
4. [4]
  CHENG X L, LI D J, WU Y, XU R, YU Y. Bismuth nanospheres embedded in three-dimensional (3D) porous graphene frameworks as high performance anodes for sodium- and potassium-ion batteries[J]. J. Mater. Chem. A, 2019,7(9):4913-4921.
5. [5]
  LIN Z H, QIU X Q, ZU X H, ZHANG X S, ZHONG L, SUN S R, HAO S H, SUN Y J, ZHANG W L. Ultra-high-rate Bi anode encapsulated in 3D lignin-derived carbon framework for sodium-ion hybrid capacitors[J]. Rare Metals, 2024,43(3):1037-1047. doi: 10.1007/s12598-023-02508-5
6. [6]
  ZHOU J, CHEN J C, CHEN M X, WANG J, LIU X Z, WEI B, WANG Z C, LI J J, GU L, ZHANG Q H, WANG H, GUO L. Few-layer bismuthene with anisotropic expansion for high-areal-capacity sodium-ion batteries[J]. Adv. Mater., 2019,31(12)1807874. doi: 10.1002/adma.201807874
7. [7]
  HU Z J, LI X Y, QU J K, ZHAO Z Q, XIE H W, YIN H Y. Electrolytic bismuth/carbon nanotubes composites for high-performance sodium-ion battery anodes[J]. J. Power Sources, 2021,496229830. doi: 10.1016/j.jpowsour.2021.229830
8. [8]
  LIANG Y Z, SONG N, ZHANG Z C Y, CHEN W H, FENG J K, XI B J, XIONG S L. Integrating Bi@C nanospheres in porous hard carbon frameworks for ultrafast sodium storage[J]. Adv. Mater., 2022,34(28)2202673. doi: 10.1002/adma.202202673
9. [9]
  KIM H, HONG J, PARK Y U, KIM J, HWANG I, KANG K. Sodium storage behavior in natural graphite using ether-based electrolyte systems[J]. Adv. Funct. Mater., 2015,25(4):534-541. doi: 10.1002/adfm.201402984
10. [10]
  YANG H, XU R, YAO Y, YE S F, ZHUO X F, YU Y. Multicore-shell Bi@N-doped carbon nanospheres for high power density and long cycle life sodium- and potassium-ion anodes[J]. Adv. Funct. Mater., 2019,29(13)1809195. doi: 10.1002/adfm.201809195
11. [11]
  YUAN H C, MA F X, WEI X B, LAN J L, LIU Y, YU Y H, YANG X P, PARK H S. Ionic-conducting and robust multilayered solid electrolyte interphases for greatly improved rate and cycling capabilities of sodium ion full cells[J]. Adv. Energy Mater., 2020,10(37)2001418. doi: 10.1002/aenm.202001418
12. [12]
  CAI S, YAN F, ZHAO Y X, LI M Q, CHEN Y W, HE X R, WANG C. Hierarchical micro-composite assembled from Bi spheres and expanded graphite flakes as anodes for sodium-ion half/full cells with excellent comprehensive electrochemical performance[J]. Chem. Eng. J., 2022,430132938. doi: 10.1016/j.cej.2021.132938
13. [13]
  YANG F H, YU F, ZHANG Z A, ZHANG K, LAI Y Q, LI J. Bismuth nanoparticles embedded in carbon spheres as anode materials for sodium/lithium-ion batteries[J]. Chem.‒Eur. J., 2016,22(7):2333-2338. doi: 10.1002/chem.201503272
14. [14]
  JIN Y Q, YUAN H C, LAN J L, YU Y H, LIN Y H, YANG X P. Bio-inspired spider-web-like membranes with a hierarchical structure for high performance lithium/sodium ion battery electrodes: The case of 3D freestanding and binder-free bismuth/CNF anodes[J]. Nanoscale, 2017,9(35):13298-13304. doi: 10.1039/C7NR04912A
15. [15]
  YIN H, LI Q W, CAO M L, ZHANG W, ZHAO H, LI C, HUO K F, ZHU M Q. Nanosized-bismuth-embedded 1D carbon nanofibers as high-performance anodes for lithium-ion and sodium-ion batteries[J]. Nano Res., 2017,10(6):2156-2167. doi: 10.1007/s12274-016-1408-z
16. [16]
  LIU R Z, LI W X, YANG X J, LU H, GAO Y P, SHUAI H L. Bismuth nanoparticles confined in multi-walled carbon nanotubes toward enhanced sodium storage anodes[J]. J. Alloy. Compd., 2023,967171660. doi: 10.1016/j.jallcom.2023.171660
17. [17]
  LIU S, FENG J K, BIAN X F, LIU J, XU H. Advanced arrayed bismuth nanorod bundle anode for sodium-ion batteries[J]. J. Mater. Chem., 2016,4(26):10098-10104. doi: 10.1039/C6TA02796B
18. [18]
  LI X T, LIANG H J, LIU X L, SUN R, QIN Z X, FAN H S, ZHANG Y F. Ion-exchange strategy of CoS₂/Sb₂S₃ hetero-structured nanocrystals encapsulated into 3D interpenetrating dual-carbon framework for high-performance Na⁺/K⁺ batteries[J]. Chem. Eng. J., 2021,425130657. doi: 10.1016/j.cej.2021.130657
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