Citation: Linjie ZHU, Xufeng LIU. Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207 shu

Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands

Linjie ZHU ,
Xufeng LIU ^,

School of Materials and Chemical Engineering, Ningbo University of Technology, Ningbo, Zhejiang 315211, China

Corresponding author: Xufeng LIU, nkxfliu@126.com
Received Date: 2 June 2024
Revised Date: 28 September 2024

Figures(6)

Two tetra-iron complexes with bridging diphosphine ligands, named [Fe₄(CO)₁₀(μ-SCH₂CH(CH₃)S)₂(dppa)] (1) and [Fe₄(CO)₁₀(μ-SCH₂CH(CH₃)S)₂(trans-dppv)] (2), where dppa=bis(diphenylphosphino)acetylene and trans-dppv= trans-1, 2-bis(diphenylphosphino)ethylene, were prepared by the reaction of complex [Fe₂(CO)₆(μ-SCH₂CH(CH₃)S)] with dppa or trans-dppv. Both complexes were structurally identified by elemental analysis, FTIR spectra, ¹H NMR, and ³¹P NMR, together with single-crystal X-ray diffraction analysis. X-ray crystallographic studies revealed that complex 1 consists of two di-iron propane-1, 2-dithiolate pentacarbonyl sub-units connected by a linear dppa ligand whereas a zigzag trans-dppv ligand is found in complex 2. The electrochemical properties were probed by cyclic voltammetry, showing that two irreversible reductions and one irreversible oxidation were found for both complexes. Furthermore, electrocatalytic studies were carried out by adding acetic acid as a proton source into the solution. The results demonstrated that both complexes can catalyze proton reduction to evolve hydrogen. For comparison, the catalytic efficiency of complex 2 was better than complex 1.
- tetra-iron complex,
- crystal structure,
- cyclic voltammetry,
- electrocatalytic hydrogen production
1. [1]
  ESSWEIN A J, NOCERA D G. Hydrogen production by molecular photocatalysis[J]. Chem. Rev., 2007,107(10):4022-4047. doi: 10.1021/cr050193e
2. [2]
  DU P W, EISENBERG R. Catalysts made of earth-abundant elements (Co, Ni, Fe) for water splitting: Recent progress and future challenges[J]. Energy Environ. Sci., 2012,5(3):6012-6021. doi: 10.1039/c2ee03250c
3. [3]
  ZHANG W, XU R. Hybrid photocatalytic H₂ evolution systems containing xanthene dyes and inorganic nickel based catalysts[J]. Int. J. Hydrogen Energ., 2012,37(23):17899-17909. doi: 10.1016/j.ijhydene.2012.08.150
4. [4]
  LV H J, RUBERU T P A, FLEISCHAUER V E, BRENNESSEL W W, NEIDIG M L, EISENBERG R. Catalytic light-driven generation of hydrogen from water by iron dithiolene complexes[J]. J. Am. Chem. Soc., 2016,138(36):11654-11663. doi: 10.1021/jacs.6b05040
5. [5]
  LI G C, MARK M F, LV H J, McCAMANT D W, EISENBERG R. Rhodamine-platinum diimine dithiolate complex dyads as efficient and robust photosensitizers for light-driven aqueous proton reduction to hydrogen[J]. J. Am. Chem. Soc., 2018,140(7):2575-2586. doi: 10.1021/jacs.7b11581
6. [6]
  DU P W, KNOWLES K, EISENBERG R. A homogeneous system for the photogeneration of hydrogen from water based on a platinum (Ⅱ) terpyridyl acetylide chromophore and a molecular cobalt catalyst[J]. J. Am. Chem. Soc., 2008,130(38):12576-12577. doi: 10.1021/ja804650g
7. [7]
  LAZARIDES T, McCORMICK T, DU P W, LUO G G, LINDLEY B, EISENBERG R. Making hydrogen from water using a homogeneous system without noble metals[J]. J. Am. Chem. Soc., 2009,131(26):9192-9194. doi: 10.1021/ja903044n
8. [8]
  CAO M, LIU R H, WANG D W, WANG Z X, YANG L F, LIU Y, XU S, CUI J L, ZHANG S X, DAI X. Synthesis and photocatalytic activity of two different hydrogenase models based on DMAEMA copolymer structure[J]. Inorg. Chim. Acta, 2023,546121293. doi: 10.1016/j.ica.2022.121293
9. [9]
  HAN Z J, QIU F, EISENBERG R, HOLLAND P L, KRAUSS T D. Robust photogeneration of H₂ in water using semiconductor nanocrys-tals and a nickel catalyst[J]. Science, 2012,338(6112):1321-1324. doi: 10.1126/science.1227775
10. [10]
  HELM M L, STEWART M P, BULLOCK R M, DUBOIS M R, DUBOIS D L. A synthetic nickel electrocatalyst with a turnover frequency above 100, 000 s^-1 for H₂ production[J]. Science, 2011,333(6044):863-866. doi: 10.1126/science.1205864
11. [11]
  LUBITZ W, OGATA H, RÜDIGER O, REIJERSE E. Hydrogenases[J]. Chem. Rev., 2014,114(8):4081-4148. doi: 10.1021/cr4005814
12. [12]
  TARD C, PICKETT C J. Structural and functional analogues of the active sites of the[Fe]-, [NiFe]-, and[FeFe]-hydrogenases[J]. Chem. Rev., 2009,109(6):2245-2274. doi: 10.1021/cr800542q
13. [13]
  FREY M. Hydrogenases: Hydrogen-activating enzymes[J]. ChemBio-Chem, 2002,3(2-3):153-160. doi: 10.1002/1439-7633(20020301)3:2/3<153::AID-CBIC153>3.0.CO;2-B
14. [14]
  PETERS J W, LANZILOTTA W N, LEMON B J, SEEFELDT L C. X-ray crystal structure of the Fe-only hydrogenase (CpI) from Clostridium Pasteurianum to 1.8 angstrom resolution[J]. Science, 1998,282(5395):1853-1858. doi: 10.1126/science.282.5395.1853
15. [15]
  NICOLET Y, PIRAS C, LEGRAND P, HATCHIKIAN C E, FONTECILLA-CAMPS J C. Desulfovibrio Desulfuricans iron hydrogenase: The structure shows unusual coordination to an active site Fe binuclear center[J]. Structure, 1999,7(1):13-23. doi: 10.1016/S0969-2126(99)80005-7
16. [16]
  LYON E J, GEORGAKAKI I P, REIBENSPIES J H, DARENSBOURG M Y. Carbon monoxide and cyanide ligands in a classical organome-tallic complex model for Fe-only hydrogenase[J]. Angew. Chem.-Int. Edit., 1999,38(21):3178-3180. doi: 10.1002/(SICI)1521-3773(19991102)38:21<3178::AID-ANIE3178>3.0.CO;2-4
17. [17]
  LAWRENCE J D, LI H X, RAUCHFUSS T B, BÉNARD M, ROHMER M M. Diiron azadithiolates as models for the iron-only hydrogenase active site: Synthesis, structure, and stereoelectronics[J]. Angew. Chem.-Int. Edit., 2001,40(9):1768-1771. doi: 10.1002/1521-3773(20010504)40:9<1768::AID-ANIE17680>3.0.CO;2-E
18. [18]
  GEORGE S J, CUI Z, RAZAVET M, PICKETT C J. The di-iron subsite of all-iron hydrogenase: mechanism of cyanation of a synthetic{2Fe3S}-carbonyl assembly[J]. Chem.-Eur. J., 2002,8(17):4037-4046. doi: 10.1002/1521-3765(20020902)8:17<4037::AID-CHEM4037>3.0.CO;2-O
19. [19]
  JIANG S, LIU J H, SHI Y, WANG Z, ÅKERMARK B, SUM L C. Fe-S complexes containing five-membered heterocycles: Novel models for the active site of hydrogenases with unusual low reduction potential[J]. Dalton Trans., 2007:896-902.
20. [20]
  HOGARTH G. An unexpected leading role for[Fe₂(CO)₆(μ-pdt)] in our understanding of[FeFe]-H₂ases and the search for clean hydrogen production[J]. Coord. Chem. Rev., 2023,490215174. doi: 10.1016/j.ccr.2023.215174
21. [21]
  GAO W M, EKSTRÖM J, LIU J H, CHEN C N, ERIKSSON L, WENG L H, ÅKERMARK B, SUN L C. Binuclear iron-sulfur complexes with bidentate phosphine ligands as active site models of Fe-hydrogenase and their catalytic proton reduction[J]. Inorg. Chem., 2007,46(6):1981-1991. doi: 10.1021/ic0610278
22. [22]
  ZHANG Q Q, DICKSON R S, FALLON G D, MAYADUNNE R. A comparison of the reactions of pentacarbonyliron with cyclic thioethers and related dialkyl sulfides[J]. J. Organomet. Chem., 2001,627(2):201-205. doi: 10.1016/S0022-328X(01)00733-1
23. [23]
  CHEN F Y, HE J, YU X Y, WANG Z, MU C, LIU X F, LI Y L, JIANG Z Q, WU H K. Electrocatalytic properties of diiron ethanedi-thiolate complexes containing benzoate ester[J]. Appl. Organomet. Chem., 2018,32(12)e4549. doi: 10.1002/aoc.4549
24. [24]
  BAI S F, MA J W, GUO Y N, DU X M, WANG Y L, LI Q L, LÜ S. Aminophosphine-substituted Fe/E (E=S, Se) carbonyls related to[FeFe]-hydrogenases: Synthesis, protonation, and electrocatalytic proton reduction[J]. J. Mol. Struct., 2023,1283135287. doi: 10.1016/j.molstruc.2023.135287
25. [25]
  YAN L, HU K, LIU X F, LI Y L, LIU X H, JIANG Z Q. Diiron ethane-1, 2-dithiolate complexes with 1, 2, 3-thiadiazole moiety: Synthesis, X-ray crystal structures, electrochemistry and fungicidal activity[J]. Appl. Organomet. Chem., 2021,35(2)e6084. doi: 10.1002/aoc.6084
26. [26]
  LIU X F, XU B, XU H, LI Y L. Synthesis, characterization, and electrocatalytic hydrogen evolution of diiron dithiolato pentacarbonyl complexes bearing phosphine ligand[J]. Chinese J. Inorg. Chem., 2023,39(8):1619-1627.
27. [27]
  ORTAN G R F, GHOSH S, ALKER L, SARKER J C, PUGH D, RICHMOND M G, HARTL F, HOGARTH G. Biomimics of[FeFe]-hydrogenases incorporating redox-active ligands: Synthesis, redox properties and spectroelectrochemistry of diiron-dithiolate complexes with ferrocenyl-diphosphines as Fe₄S₄ surrogates[J]. Dalton Trans., 2022,51(25):9748-9769. doi: 10.1039/D2DT00419D
28. [28]
  ZHAO P H, MA Z Y, HU M Y, HE J, WANG Y Z, JING X B, CHEN H Y, LI Y L. PNP-Chelated and-bridged diiron dithiolate complexes Fe₂(μ-pdt)(CO)₄{(Ph₂P)₂NR} together with related monophosphine complexes for the[2Fe]_H subsite of[FeFe]-hydrogenases: preparation, structure, and electrocatalysis[J]. Organometallics, 2018,37(8):1280-1290. doi: 10.1021/acs.organomet.8b00030
29. [29]
  ZHAO P H, HU M Y, LI J R, MA Z Y, WANG Y Z, HE J, LI Y L, LIU X F. Influence of dithiolate bridges on the structures and electrocatalytic performance of small bite-angle PNP-chelated diiron complexes Fe₂(μ-xdt)(CO)₄{κ²-(Ph₂P)₂NR} related to[FeFe]-hydroge-nases[J]. Organometallics, 2019,38(2):385-394. doi: 10.1021/acs.organomet.8b00759
30. [30]
  LIU X F, XU B, XU H, LI Y L. Diiron butane-1, 2-dithiolate complexes with phosphine ligands: preparation, crystal structures, and electrochemical catalytic performance[J]. Chinese J. Inorg. Chem., 2022,38(12):2521-2529. doi: 10.11862/CJIC.2022.245
31. [31]
  LIU X F, WANG S J, ZHAO P H. Di-iron dithiolato complexes with 3-bromothiophene moiety: Preparation, structures, and electrochemistry[J]. J. Mol. Struct., 2023,1294136454. doi: 10.1016/j.molstruc.2023.136454
32. [32]
  BAI S F, DU X M, TIAN W J, XU H, ZHANG R F, MA C L, WANG Y L, LÜ S, LI Q L, LI Y L. Di-, tri-and tetraphosphine-substituted Fe/Se carbonyls: Synthesis, characterization and electrochemical properties[J]. Dalton Trans., 2022,51(29):11125-11134. doi: 10.1039/D2DT01376B
33. [33]
  YAN L, YANG J, LÜ S, LIU X F, LI Y L, LIU X H, JIANG Z Q. Phosphine-containing diiron propane-1, 2-dithiolate derivatives: Synthesis, spectroscopy, X-ray crystal structures, and electrochemistry[J]. Catal. Lett., 2021,151(7):1857-1867. doi: 10.1007/s10562-020-03450-2
34. [34]
  LIU X F, YIN B S. Synthesis and structural characterization of diiron propanedithiolate complex[(μ-PDT) Fe₂(CO)₅]₂[(η⁵-Ph₂PC₅H₄)₂Fe] containing a bidentate phosphine ligand 1, 1'-bis (diphenylphosphino) ferrocene[J]. J. Coord. Chem., 2010,63(23):4061-4067. doi: 10.1080/00958972.2010.531715
35. [35]
  LIU X F, JIANG Z Q, JIA Z J. Synthesis, characterization and crystal structures of tetrairon ethanedithiolate complexes containing bridging bidentate phosphine ligands[J]. Polyhedron, 2012,33(1):166-170. doi: 10.1016/j.poly.2011.11.032
36. [36]
  LIU X F. Synthesis and structures of diiron dithiolate complexes with 1, 2-bis (diphenylphosphino) acetylene or tris (2-methoxyphenyl) phosphine[J]. Polyhedron, 2016,117:672-678. doi: 10.1016/j.poly.2016.07.009
37. [37]
  LI R X, LIU X F, LIU T, YIN Y B, ZOU Y, MEI S K, YAN J. Electrocatalytic properties of[FeFe]-hydrogenases models and visible-light-driven hydrogen evolution efficiency promotion with porphyrin functionalized graphene nanocomposite[J]. Electrochim. Acta, 2017,237:207-216. doi: 10.1016/j.electacta.2017.03.216
38. [38]
  JIN B, TAN X, ZHANG X X, WANG Z Y, QU Y P, HE Y B, HU T P, ZHAO P H. Substituent effects in carbon-nanotube-supported diiron monophosphine complexes for hydrogen evolution reaction[J]. Electrochim. Acta, 2022,434141325. doi: 10.1016/j.electacta.2022.141325
39. [39]
  DEY S, RANA A, DEY S G, DEY A. Electrochemical hydrogen production in acidic water by an azadithiolate bridged synthetic hydro-genese mimic: Role of aqueous solvation in lowering overpotential[J]. ACS Catal., 2013,3(3):429-436. doi: 10.1021/cs300835a
40. [40]
  AHMED M E, DEY S, MONDAL B, DEY A. H₂ evolution catalyzed by a FeFe-hydrogenase synthetic model covalently attached to graphite surfaces[J]. Chem. Commun., 2017,53(58):8188-8191. doi: 10.1039/C7CC04281G
41. [41]
  CHONG D, GEORGAKAKI I P, MEJIA-RODRIGUEZ R, SANABRIA-CHINCHILLA J, SORIAGA M P, DARENSBOURG M Y. Electrocatalysis of hydrogen production by active site analogues of the iron hydrogenase enzyme: Structure/function relationships[J]. Dalton Trans., 2003,4158-4163.
42. [42]
  DONOVAN E S, NICHOL G S, FELTON G A N. Structural effects upon the durability of hydrogenase-inspired hydrogen-producing electrocatalysts: Variations in the (μ-edt)[Fe₂(CO)₆] system[J]. J. Organomet. Chem., 2013,726:9-13. doi: 10.1016/j.jorganchem.2012.12.006
43. [43]
  GLOAGUEN F, LAWRENCE J D, RAUCHFUSS T B. Biomimetic hydrogen evolution catalyzed by an iron carbonyl thiolate[J]. J. Am. Chem. Soc., 2001,123(38):9476-9477. doi: 10.1021/ja016516f
44. [44]
  LÜ S, BAI S F, GAO X P, WANG Y L, LI Q L. Aminodiphosphine substituted 2Fe2Se complex as new precursor to single and double butterfly Fe/Se models related to FeFe hydrogenase models[J]. J. Mol. Struct., 2023,1290135939. doi: 10.1016/j.molstruc.2023.135939
45. [45]
  LI Z M, XIAO Z Y, XU F F, ZENG X H, LIU X M. Enhancement in catalytic proton reduction by an internal base in a diiron pentacarbonyl complex: Its synthesis, characterisation, interconversion and electrochemical investigation[J]. Dalton Trans., 2017,46(6):1864-1871. doi: 10.1039/C6DT04409C
46. [46]
  ZHONG W, WU L, JIANG W D, LI Y L, MOOKAN N, LIU X M. Proton-coupled electron transfer in the reduction of diiron hexacarbonyl complexes and its enhancement on the electrocatalytic reduction of protons by a pendant basic group[J]. Dalton Trans., 2019,48(36):13711-13718. doi: 10.1039/C9DT02058F
47. [47]
  XIAO Z Y, ZHONG W, LIU X M. Recent developments in electrochemical investigations into iron carbonyl complexes relevant to the iron centres of hydrogenases[J]. Dalton Trans., 2022,51(1):40-47. doi: 10.1039/D1DT02705K
48. [48]
  LIU X F, LI Y L, LIU X H. Synthesis, characterization, electrocata-lytic properties, and antifungal activity of isoxazole-containing di-iron complexes[J]. Chinese J. Inorg. Chem., 2023,39(12):2367-2376. doi: 10.11862/CJIC.2023.204
49. [49]
  LIU X F, LI Y L, LIU X H. Heterocyclic pyrazole-containing diiron dithiolato analogues: Synthesis, characterization, electrochemistry, and fungicidal activity[J]. Appl. Organomet. Chem., 2022,36(11)e6884. doi: 10.1002/aoc.6884
1. [1]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
2. [2]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
3. [3]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
4. [4]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
5. [5]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
6. [6]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
7. [7]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
8. [8]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
9. [9]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
10. [10]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
11. [11]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
12. [12]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
13. [13]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
14. [14]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
15. [15]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
16. [16]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
17. [17]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
18. [18]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
19. [19]
  Dongju Zhang . Exploring the Descriptions and Connotations of Basic Concepts of Teaching Crystal Structures. University Chemistry, 2024, 39(3): 18-22. doi: 10.3866/PKU.DXHX202304003
20. [20]
  Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(437)
HTML views(72)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142