Construction and application of multi-component systems based on luminous copper nanoclusters
- Corresponding author: Hua XIANG, 873312555@qq.com Mei PAN, panm@mail.sysu.edu.cn
Citation:
Yanting HUANG, Hua XIANG, Mei PAN. Construction and application of multi-component systems based on luminous copper nanoclusters[J]. Chinese Journal of Inorganic Chemistry,
;2024, 40(11): 2075-2090.
doi:
10.11862/CJIC.20240196
Wang Z G, Chen B K, Rogach A L. Synthesis, optical properties and applications of light-emitting copper nanoclusters[J]. Nanoscale Horiz., 2017,2(3):135-146.
Busi K B, Palanivel M, Ghosh K K, Ball W B, Gulyás B, Padmanabhan P, Chakrabortty S. The multifarious applications of copper nanoclusters in biosensing and bioimaging and their translational role in early disease detection[J]. Nanomaterials, 2022,12(3)301.
Hu X, Liu T T, Zhuang Y X, Wang W, Li Y Y, Fan W H, Huang Y M. Recent advances in the analytical applications of copper nanoclusters[J]. Trends Anal. Chem., 2016,77:66-75.
An Y, Ren Y, Bick M, Dudek A, Waworuntu E H W, Tang J, Chen J, Chang B S. Highly fluorescent copper nanoclusters for sensing and bioimaging[J]. Biosens. Bioelectron., 2020,154112078.
Shi Y E, Ma J Z, Feng A R, Wang Z G, Rogach A L. Aggregation-induced emission of copper nanoclusters[J]. Aggregate, 2021,2(6)e112.
Shahsavari S, Hadian-Ghazvini S, Saboor F H, Oskouie I M, Hasany M, Simchi A, Rogach A L. Ligand functionalized copper nanoclusters for versatile applications in catalysis, sensing, bioimaging, and optoelectronics[J]. Mat. Chem. Front., 2019,3(11):2326-2356.
Vázquez-Vázquez C, Bañobre-López M, Mitra A, López-Quintela M A, Rivas J. Synthesis of small atomic copper clusters in microemulsions[J]. Langmuir, 2009,25(14):8208-8216.
LI C H, SUN P P, DING H, LING T, SUN D, XIN X.. Synthesis of metal nanoclusters and regulation of their photoluminescent properties.[J]. Scientia Sinica Chimica, 2021,51(6):688-702.
Biswas S, Negishi Y. A comprehensive analysis of luminescent crystallized Cu nanoclusters[J]. J. Phys. Chem. Lett., 2024,15(4):947-958.
Qing T P, Zhang K W, Qing Z H, Wang X, Long C C, Zhang P, Hu H Z, Feng B. Recent progress in copper nanocluster-based fluorescent probing: A review[J]. Microchim. Acta, 2019,186670.
Lin L Y, Hu Y F, Zhang L L, Huang Y, Zhao S L. Photoluminescence light-up detection of zinc ion and imaging in living cells based on the aggregation induced emission enhancement of glutathionecapped copper nanoclusters[J]. Boisens. Bioelectron., 2017,94:523-529.
Huang Y Y, Feng , Liu W D, Zhang S S, Tang C, Chen J R, Qian Z S. Cation-driven luminescent self-assembled dots of copper nanoclusters with aggregation-induced emission for β-galactosidase activity monitoring[J]. J. Mater. Chem. B, 2017,5(26):5120-5127.
HAN B Y, HOU X F, XIANG R C, YU M B, LI Y, PENG T T, HE G H.. Detection of lead ion based on aggregation-induced emission of copper nanoclusters.[J]. Chin. J. Anal. Chem., 2017,45(1):23-27.
Mei H, Wang Q, Jiang J H, Zhu X L, Wang H L, Qu S G, Wang X D. A novel ratiometric nanoprobe based on copper nanoclusters and graphitic carbon nitride nanosheets using Ce(Ⅲ) as crosslinking agent and aggregation-induced effect initiator for sensitive detection of hydrogen peroxide and glucose[J]. Talanta, 2022,248123604.
Qu F, Yang Q Q, Wang B J, You J M. Aggregation-induced emission of copper nanoclusters triggered by synergistic effect of dual metal ions and the application in the detection of H2O2 and related biomolecules[J]. Talanta, 2020,207120289.
Ma F H, Deng L, Wang T T, Zhang A M, Yang M H, Li X Q, Chen X. Determination of 2, 6-dipicolinic acid as an anthrax biomarker based on the enhancement of copper nanocluster fluorescence by reversible aggregation-induced emission[J]. Microchim. Acta, 2023,190291.
Mei H, Wang J P, Zhu X L, Sun J, Shi W, Wang H L, Qu S G, Wang X D. Ce3+ and Fe2+ co-enhanced ratiometric fluorescence probe utilizing copper nanoclusters and coumarin for sensitive assay of hydrogen peroxide and glucose[J]. Ecotox. Environ. Safe., 2022,245114117.
Yuan J, Wu W N, Guo L X, Hao J C, Dong S L. Multistimuli-responsive and antifreeze aggregation-induced emission-active gels based on Cu NCs[J]. Langmuir, 2022,38(1):343-351.
Chen X Q, Liu Y H, Liu X T, Lu C. Nanoparticle-based single molecule fluorescent probes[J]. Luminescence, 2022,37(11):1808-1821.
Lin S M, Dong J X, Zhang B W, Yuan Z M, Lu C X, Han P, Xu J, Jia L N, Wang L. Synthesis of bifunctional fluorescent nanohybrids of carbon dots-copper nanoclusters via a facile method for Fe3+ and Tb3+ ratiometric detection[J]. Anal. Methods, 2021,13:3577-3584.
Song S L, Zhao Y, Li Y, Yang X D, Wang D, Wen Z Q, Yang M H, Lin Q. pH-responsive copper-cluster-based dual-emission ratiometric fluorescent probe for imaging of bacterial metabolism[J]. Talanta, 2021,221121621.
Li Y Y, He Y, Ge Y L, Song G W, Zhou J G. Different fluorescence emitting copper nanoclusters protected by egg white and double-emission fluorescent probe for fast detection of ethanol[J]. Microchim.Acta, 2021,188101.
Chen L Y, Luque R, Li Y W. Controllable design of tunable nanostructures inside metal-organic frameworks[J]. Chem. Soc. Rev., 2017,46(15):4614-4630.
Wang Z G, Chen R, Xiong Y, Cepe K, Schneider J, Zboril R, Lee C S, Rogach A L. Incorporating copper nanoclusters into metal-organic frameworks: confinement-assisted emission enhancement and application for trinitrotoluene detection[J]. Part. Part. Syst. Charact, 2017,34(6)1700029.
Lu J Y, Yuan Y R, Zhang Q, Wang Y L, Liu S Y, Wu J Z. A novel ratiometric fluorescent probe for the detection of bilirubin based on the copper nanoclusters-metal organic frameworks hybrids[J]. Fuller.Nanotub. Carbon Nanostruct., 2023,31(8):724-730.
Han B Y, Hu X X, Yu M B, Peng T T, Li Y, He G H. One-pot synthesis of enhanced fluorescent copper nanoclusters encapsulated in metal-organic frameworks[J]. RSC Adv., 2018,8:22748-22754.
Wang Z G, Xiong Y, Kershaw S V, Chen B K, Yang X M, Goswami N, Lai M F, Xie J P, Rogach A L. In situ fabrication of flexible, thermally stable, large-area, strongly luminescent copper nanocluster/polymer composite films[J]. Chem. Mater., 2017,29(23):10206-10211.
Wang Z G, Shi Y E, Yang X M, Xiong Y, Li Y X, Chen B K, Lai W F, Rogach A L. Water-soluble biocompatible copolymer hypromellose grafted chitosan able to load exogenous agents and copper nanoclusters with aggregation-induced emission[J]. Adv. Funct. Mater., 2018,28(34)1802848.
Talite M J, Chou W C, Yuan C T. Efficient synthesis and optical properties of highly luminescent copper nanoclusters[J]. J. Fluoresc., 2018,10672106723H.
Li L, Huang M, Liu X H, Sun D M, Shao C Y. In situ generation of fluorescent copper nanoclusters embedded in monolithic eggshell membrane: Properties and applications[J]. Materials, 2018,11(10)1913.
Lettieri M, Palladino P, Scarano S, Minunni M. Copper nanoclusters and their application for innovative fluorescent detection strategies: An overview[J]. Sens. Actuator Rep., 2022,4100108.
Ma J Z, Lu Z D, Li C M, Luo Y J, Shi Y E, Alam P, Lam J W Y, Wang Z G, Tang B Z. Fluorescence ratiometric assay for discriminating GSH and Cys based on the composites of UiO-66-NH2 and Cu nanoclusters[J]. Biosens. Bioelectron., 2022,215114582.
Shi Y E, Han F, Xie L Y, Zhang C C, Li T Z, Wang H G, Lai W F, Luo S J, Wei W, Wang Z G, Huang Y. A MXene of type Ti3C2Tx functionalized with copper nanoclusters[J]. Microchim. Acta, 2020,18738.
Huang X M, Lan M J, Wang J, Guo L H, Lin Z Y, Sun N, Wu C M, Qiu B. A fluorescence signal amplification and specific energy transfer strategy for sensitive detection of β-galactosidase based on the effects of AIE and host-guest recognition[J]. Biosens. Bioelectron., 2020,169112655.
Geng F H, Zou C P, Liu J H, Zhang Q C, Guo X Y, Fan Y C, Yu H D, Yang S, Liu Z P, Li L. Development of luminescent nanoswitch for sensing of alkaline phosphatase in human serum based on Al3+-PPi interaction and Cu NCs with AIE properties[J]. Anal. Chim. Acta, 2019,1076:131-137.
Song S L, Zhang Y P, Yang Y Z, Wang C X, Zhou Y, Zhang C, Zhao Y Q, Yang M H, Lin Q. Ratiometric fluorescence detection of trace water in organic solvents based on aggregation-induced emission enhanced Cu nanoclusters[J]. Analyst, 2018,143(13):3068-3074.
Mei H, Wang Q, Jiang J H, Zhu X L, Wang H L, Qu S G, Wang X D. A novel ratiometric nanoprobe based on copper nanoclusters and graphitic carbon nitride nanosheets using Ce(Ⅲ) as crosslinking agent and aggregation-induced effect initiator for sensitive detection of hydrogen peroxide and glucose[J]. Talanta, 2022,248123604.
Zhang L B, Wang E K. Metal nanoclusters: New fluorescent probes for sensors and bioimaging[J]. Nano Today, 2014,9(1):132-157.
Xin Y, Zhang D, Zeng Y, Wang Y W, Qi P. A dual-emission ratiometric fluorescent sensor based on copper nanoclusters encapsulated in zeolitic imidazolate framework-90 for rapid detection and imaging of adenosine triphosphate[J]. Anal. Methods, 2023,15:788-796.
Luo X Y, Pan M. Metal-organic materials with circularly polarized luminescence[J]. Coord. Chem. Rev., 2022,468214640.
Liu M Y, Kuang K X, Li G H, Yang S Q, Yuan Z W. Photoluminescence-enhanced cholesteric films: Coassembling copper nanoclusters with cellulose nanocrystals[J]. Carbohydr. Polym., 2021,257117641.
Wang Y J, Jin Y, Shi X Y, Dong X Y, Zang S Q. Achiral copper clusters helically confined in self-assembled chiral nanotubes emitting circularly polarized phosphorescence[J]. Inorg. Chem. Front., 2022,9(13):3330-3334.
Li S L, Zhang S S, Feng N, Zhang N, Zhu Y, Liu Y H, Wang W J, Xin X. Chiral inversion and recovery of supramolecular luminescent copper nanocluster hydrogels triggered by polyethyleneimine and polyoxometalates[J]. ACS Appl. Mater. Interfaces, 2022,14(46):52324-52333.
Xiaxue Chen , Yuxuan Yang , Ruolin Yang , Yizhu Wang , Hongyun Liu . Adjustable Polychromatic Fluorescence: Investigating the Photoluminescent Properties of Copper Nanoclusters. University Chemistry, 2024, 39(9): 328-337. doi: 10.3866/PKU.DXHX202308019
Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm3+-doped Ba0.85Ca0.15Ti0.90Zr0.10O3 lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr3 Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
Jianjun Liu , Xue Yang , Chi Zhang , Xueyu Zhao , Zhiwei Zhang , Yongmei Chen , Qinghong Xu , Shao Jin . Preparation and Fluorescence Characterization of CdTe Semiconductor Quantum Dots. University Chemistry, 2024, 39(7): 307-315. doi: 10.3866/PKU.DXHX202311031
Dongheng WANG , Si LI , Shuangquan ZANG . Construction of chiral alkynyl silver chains and modulation of chiral optical properties. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 131-140. doi: 10.11862/CJIC.20240379
. . Chinese Journal of Inorganic Chemistry, 2024, 40(11): 0-0.
Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
Bin HE , Hao ZHANG , Lin XU , Yanghe LIU , Feifan LANG , Jiandong PANG . Recent progress in multicomponent zirconium?based metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2041-2062. doi: 10.11862/CJIC.20240161
Tingting XU , Wenjing ZHANG , Yongbo SONG . Research advances of atomic precision coinage metal nanoclusters in tumor therapy. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2275-2285. doi: 10.11862/CJIC.20240229
Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au11(dppf)4Cl2 nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131
Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
Qin Hou , Jiayi Hou , Aiju Shi , Xingliang Xu , Yuanhong Zhang , Yijing Li , Juying Hou , Yanfang Wang . Preparation of Cuprous Iodide Coordination Polymer and Fluorescent Detection of Nitrite: A Comprehensive Chemical Design Experiment. University Chemistry, 2024, 39(8): 221-229. doi: 10.3866/PKU.DXHX202312056
Feng Lu , Tao Wang , Qi Wang . Preparation and Characterization of Water-Soluble Silver Nanoclusters: A New Design and Teaching Practice in Materials Chemistry Experiment. University Chemistry, 2025, 40(4): 375-381. doi: 10.12461/PKU.DXHX202406005
Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
B: Cu-brown, S-yellow, P-violet, O-red, N-blue, C-gray; Other ligands were omitted for clarity; Me=methyl; Ph=phenyl.
ESM: eggshell membrane; VC: vitamin C.
CNC: cellulose nanocrystal; EISA: evaporation-induced self-assembly.
Inset in B: the left inset provides important indicators of the device, and the right shows a photograph of the orange emitting device.