Citation: Ran HUO, Zhaohui ZHANG, Xi SU, Long CHEN. Research progress on multivariate two dimensional conjugated metal organic frameworks[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195 shu

Research progress on multivariate two dimensional conjugated metal organic frameworks

State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China

Received Date: 27 May 2024
Revised Date: 22 August 2024

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Multivariate two-dimensional conjugated metal-organic frameworks (MTV 2D c-MOFs) represent a novel class of porous crystalline materials constructed by coordinating multiple organic ligands and metal nodes. These advantages include predictable topology, tunable porosity, high conductivity, and high electrocatalytic activity, making them widely applicable in electrocatalysis, energy storage, and gas sensing. By leveraging the synergistic effects of multiple metal ions or organic ligands, the electrochemical activity and selectivity of MTV 2D c-MOFs can be efficiently optimized, resulting in superior conductivity and catalytic performance compared to traditional two-component 2D c-MOFs. In this mini-review, we first outline several common construction strategies for MTV 2D c-MOFs and provide a detailed comparison with two-component 2D c-MOFs. In addition, we discuss the promising application prospects of MTV 2D c-MOFs across various fields. Finally, we address the current challenges hindering the development of MTV 2D c-MOFs, highlighting directions for future research and improvement.
- multivariate metal-organic frameworks,
- electrical conductivity,
- electrocatalysis
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