Citation: Jiahong ZHENG, Jingyun YANG. Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170 shu

Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires

Jiahong ZHENG ^, ,
Jingyun YANG

School of Materials Science and Engineering, Chang'an University, Xi'an 710061, China

Corresponding author: Jiahong ZHENG, jhzheng@chd.edu.cn
Received Date: 14 May 2024
Revised Date: 17 July 2024

Figures(7)

Using ultra-long MnO₂ nanowires as templates and ZIF-67 as precursors, hollow bead string structured MnO₂/CoNi₂S₄ was prepared via a simple room temperature stirring method and one-step vulcanization. In the unique structure, the ultra-long MnO₂ nanowires provide a direct pathway for electron transfer, and their largeaspect ratio is conducive to the formation of self-supporting three-dimensional conductive network structure; the hollow and porous CoNi₂S₄ provides richer active sites and mitigates the charging and discharging process of the volume change during charging and discharging. Thanks to the above advantages, MnO₂/CoNi₂S₄ had a specific capacitance value of 1 531.1 F·g^-1 at 1 A·g^-1 and a capacitance retention rate of 86.9% at 10 A·g^-1. Using MnO₂/CoNi₂S₄ as the positive electrode and activated carbon (AC) as the negative electrode, the assembled MnO₂/CoNi₂S₄||AC devices achieved high energy density (40 Wh·kg^-1 at 800 W·kg^-1) and excellent cycling stability (64.8% retention after 5 000 cycles).
- metal-organic framework,
- manganese dioxide nanowire,
- transition metal sulfide,
- supercapacitor
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Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires