Citation: Bin HE, Hao ZHANG, Lin XU, Yanghe LIU, Feifan LANG, Jiandong PANG. Recent progress in multicomponent zirconium?based metal-organic frameworks[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(11): 2041-2062. doi: 10.11862/CJIC.20240161 shu

Recent progress in multicomponent zirconium?based metal-organic frameworks

School of Materials Science and Engineering, Nankai University, Tianjin 300350, China

Corresponding author: Feifan LANG, fflang@nankai.edu.cn Jiandong PANG, jdpang@nankai.edu.cn
Received Date: 8 May 2024
Revised Date: 10 July 2024

Figures(11)

Zirconium‐based metal-organic frameworks (Zr-MOFs) have emerged as one of the most promising crystalline porous framework materials for various applications, owing to their abundant structural varieties, excellent thermal and chemical stability as well as diverse functionalities. Incorporating organic ligands with tailored functional groups into the Zr-MOFs system via various methods such as one‐pot synthesis and post-synthetic modification enables the construction of multicomponent zirconium‐based metal-organic frameworks (MC-Zr-MOFs), allowing precise regulation over their pore environment for particular requirements. MC-Zr-MOFs have found extensive utility in gas adsorption/separation, guest molecule/ion adsorption in the solution phase, multiphase catalysis, chemical sensing, and optical materials for instance while exhibiting remarkable performance. This review aims to carefully investigate the recent advances in the synthetic strategies and novel applications of MC-Zr-MOFs, along with prospects for their future development.
- zirconium-based metal-organic framework,
- structural design,
- multi-component assembly,
- pore environment modulation,
- structure-property relationship
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