Citation: Han ZHANG, Jianfeng SUN, Jinsheng LIANG. Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098 shu

Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor

Han ZHANG ¹ ,
Jianfeng SUN ^{1, 2} ,
Jinsheng LIANG ^{1, 2,,}

1.
Key Laboratory of Special Functional Materials for Ecological Environment and Information of Ministry of Education, Hebei University of Technology, Tianjin 300130, China
2.
Institute of Power Source and Ecomaterials Science, Hebei University of Technology, Tianjin 300130, China

Corresponding author: Jinsheng LIANG, Liangjinsheng@hebut.edu.cn
Received Date: 27 March 2024
Revised Date: 27 October 2024

Figures(6)

A broadband near-infrared Na₃CrF₆ phosphor was synthesized by hydrothermal method, and its structure, microstructure, and photoluminescence properties were investigated. The results show that under excitation of 435 nm, the Na₃CrF₆ phosphor can emit broadband near-infrared light of 650-850 nm, with a peak at 738 nm and a half maximum width of 95 nm. The crystal field intensity of Cr³⁺ in Na₃CrF₆ phosphor was calculated to be 1.72 by analyzing spectral data, indicating that Cr³⁺ is located in the weak crystal field environment. The luminescent intensity of Na₃CrF₆ phosphor decreased slowly with the increase of heating temperature in the temperature range of 298-473 K.
- broadband near-infrared phosphor,
- hydrothermal synthesis,
- Na₃CrF₆,
- photoluminescent property,
- phosphor-converted light-emitting diode
1. [1]
  SHENG X X, XIAO F, LÜ J B. Luminescence characteristics and device applications of Cr³⁺-doped Ca₄HfGe₃O₁₂ broadband near-infra-red phosphors[J]. Chinese J. Inorg. Chem., 2024,40(2):345-352. doi: 10.11862/CJIC.20230260
2. [2]
  WANG K N, LIU L Y, MAO D, HOU M X, TAN C P, MAO Z W, LIU B. A nuclear-targeted AIE photosensitizer for enzyme inhibition and photosensitization in cancer cell ablation[J]. Angew. Chem.-Int. Edit., 2022,61(15)e202114600. doi: 10.1002/anie.202114600
3. [3]
  WANG K N, LIU L Y, QI G B, CHAO X J, MA W, YU Z Q, PAN Q L, MAO Z W, LIU B. Light-driven cascade mitochondria-to-nucleus photosensitization in cancer cell ablation[J]. Adv. Sci., 2021,8(8)2004379. doi: 10.1002/advs.202004379
4. [4]
  LEE H, CHO S, LIM J, LEE A, KIM G, SONG D J, CHUN S W, KIM M J, MO C Y. Performance comparison of tungsten-halogen light and phosphor converted NIR LED in soluble solid content estimation of apple[J]. Sensors, 2023,23(4)1961. doi: 10.3390/s23041961
5. [5]
  CHEN S Y, HAN M X, LI J, LI Y G, GAO Z X, ZHANG Y, MENG M M, ZHANG Q H, DENG D G, CHEN L. Cr³⁺-activated NaInSi₂O₆: An efficient broadband near-infrared phosphor with its applications in LED[J]. Ceram. Int., 2023,49(22):36360-36367. doi: 10.1016/j.ceramint.2023.08.320
6. [6]
  SONG E H, MING H, ZHOU Y Y, HE F Q, WU J C, XIA Z G, ZHANG Q Y. Cr³⁺-doped Sc-based fluoride enabling highly efficient near infrared luminescence: A case study of K₂NaScF₆: Cr³⁺[J]. Laser Photonics Rev., 2021,15(2)2000410. doi: 10.1002/lpor.202000410
7. [7]
  GU J Y, FAN W G, ZHANG Z Q, YAO Q, ZHAN H Q. Structure and optical property of Pr₂O₃ powder prepared by reduction[J]. J. Inorg. Mater., 2023,38(7):771-777.
8. [8]
  WANG Z W, JI H P, WANG F X, HOU X H, YI S S, ZHOU Y, CHEN D L. Valence state control of manganese in MgAl₂O₄: Mn⁴⁺ phosphor by varying the Al₂O₃ crystal form[J]. J. Inorg. Mater., 2021,36(5):513-520.
9. [9]
  JIN M H, ZHANG T, LI J G, ZHU Q. Incorporation of Eu³⁺ in ZnGa₂O₄: Ni²⁺ for improved NIR persistent luminescence located in second transparency window[J]. J. Am. Ceram. Soc., 2024,107(1):265-275. doi: 10.1111/jace.19442
10. [10]
  YU H J, CHEN J, MI R Y, YANG J Y, LIU Y G. Broadband near-infrared emission of K₃ScF₆: Cr³⁺ phosphors for night vision imaging system sources[J]. Chem. Eng. J., 2021,417129271. doi: 10.1016/j.cej.2021.129271
11. [11]
  YU D C, ZHOU Y S, MA C S, MELMAN J H, BAROUDI K M, LACAPRA M, RIMAN R E. Non-rare-earth Na₃AlF₆: Cr³⁺ phosphors for far-red light-emitting diodes[J]. ACS. Appl. Electron. Mater., 2019,1(11):2325-2333. doi: 10.1021/acsaelm.9b00527
12. [12]
  MALYSA B, MEIJERINK A, WU W W, JVSTEL T. On the influence of calcium substitution to the optical properties of Cr³⁺ doped SrSc₂O₄[J]. J. Lumines., 2017,190:234-241. doi: 10.1016/j.jlumin.2017.05.030
13. [13]
  LEE C, BAO Z, FANG M H, LESNIEWSKI T, MAHLIK S, GRINBERG M, LENIEC G, KACZMAREK S M, BRIK M G, TSAI Y T, TSAI T L, LIU R S. Chromium (Ⅲ)-doped fluoride phosphors with broadband infrared emission for light-emitting diodes[J]. Inorg. Chem., 2020,59(1):376-385. doi: 10.1021/acs.inorgchem.9b02630
14. [14]
  YAO L Q, SHAO Q Y, HAN S Y, LIANG C, HE J H, JIANG , J Q. Enhancing near-infrared photoluminescence intensity and spectral properties in Yb³⁺ codoped LiScP₂O₇: Cr³⁺[J]. Chem. Mater., 2020,32(6):2430-2439. doi: 10.1021/acs.chemmater.9b04934
15. [15]
  XU X X, SHAO Q Y, YAO L Q, DONG Y, JIANG J Q. Highly efficient and thermally stable Cr³⁺-activated silicate phosphors for broadband near-infrared LED applications[J]. Chem. Eng. J., 2020,383123108. doi: 10.1016/j.cej.2019.123108
16. [16]
  ZHOU Z, LI P, XU H B, ZHANG Y. A chemical precipitation method to synthesize Na₃CrF₆ crystal with unique shapes[J]. J. Inorg. Organomet. Polym. Mater., 2013,23(6):1529-1533. doi: 10.1007/s10904-013-9931-9
17. [17]
  LIU L, ZHANG J X, WANG X L, HOU W L, LIU X W, XU M, YANG J K, LIANG B. Preparation and fluorescence properties of a Cr³⁺: Gamma-AlON powder by high temperature solid state reaction[J]. Mater. Lett., 2020,258126811. doi: 10.1016/j.matlet.2019.126811
18. [18]
  NIE W D, LI Y, ZUO J X, KONG Y K, ZOU W F, CHEN G, PENG J Q, DU F, HAN L, YE X Y. Cr³⁺-activated Na₃X₂Li₃F₁₂(X=Al, Ga, or In) garnet phosphors with broadband NIR emission and high lumi-nescence efficiency for potential biomedical application[J]. J. Mater. Chem. C, 2021,9(42):15230-15241. doi: 10.1039/D1TC03763C
19. [19]
  ZHANG R, SUN J F. An efficient perovskite-type Rb₂CaPO₄F: Eu²⁺ phosphor with high brightness towards closing the cyan gap[J]. J. Alloy. Compd., 2021,872159698. doi: 10.1016/j.jallcom.2021.159698
20. [20]
  ZHAO F Y, SONG Z, ZHAO J, LIU Q L. Double perovskite Cs₂AgInCl₆: Cr³⁺: Broadband and near-infrared luminescent materials[J]. Inorg. Chem. Front., 2019,6(12):3621-3628. doi: 10.1039/C9QI00905A
21. [21]
  BU Q Z, WANG Y J, LI D S, YAN Y J, CHANG Y, XIANG G T, ZHOU X J. Highly efficient and thermally stable Cr³⁺-activated garnet phosphors for application in broadband NIR pc-LEDs[J]. J. Lumines., 2024,45(4):591-602. doi: 10.37188/CJL.20240016
22. [22]
  YUAN W H, PANG R, ZHANG S, ZHANG H J. Near-infrared phosphor BaY₂Al₂Ga₂SiO₁₂: Cr³⁺ with excellent thermal stability and considerable quantum efficiency[J]. Chinese Journal of Luminescence, 2024,45(2):290-298.
23. [23]
  SUN Z S, NING Q X, ZHOU W Y, LUO J B, CHEN P C, ZHOU L Y, PANG Q, ZHANG X G. Structural and spectroscopic investigation of an efficient and broadband NIR phosphor InBO₃: Cr³⁺ and its application in NIR pc-LEDs[J]. Ceram. Int., 2021,47(10):13598-13603. doi: 10.1016/j.ceramint.2021.01.218
24. [24]
  XIE X, GE W Y, ZHANG Q, YANG M H, WU C G, HE P, YIN H L. Effect of Yb³⁺/Nd³⁺ doped on luminescent properties of Sr₉Ga (PO₄)7:Cr³⁺[J]. Chinese Journal of Luminescence, 2024,45(5):736-744.
25. [25]
  SHAO Q Y, DING H, YAO L Q, XU J F, LIANG C, JIANG J Q. Photoluminescence properties of a ScBO₃: Cr³⁺ phosphor and its applications for broadband near-infrared LEDs[J]. RSC Adv., 2018,8(22):12035-12042. doi: 10.1039/C8RA01084F
26. [26]
  HE F Q, WU J C, SHAO P S, SONG E H. Preparation and luminescent properties research of broadband near-infrared fluoride phosphor Cs₂NaAlF₆: Cr³⁺[J]. Laser Optoelectron. Prog., 2021,58(15):114-121.
27. [27]
  MALYSA B, MEIJERINK A, JVSTEL T. Temperature dependent Cr³⁺ photoluminescence in garnets of the type X₃Sc₂Ga₃O₁₂(X=Lu, Y, Gd, La)[J]. J. Lumines., 2018,202:523-531. doi: 10.1016/j.jlumin.2018.05.076
28. [28]
  ZHANG H S, ZHONG J Y, LI C J, WANG L G, ZHAO W R. Broad-band near-infrared luminescence in the NaAlP₂O₇: Cr³⁺ phosphor for spectroscopy applications[J]. J. Lumines., 2022,251119211. doi: 10.1016/j.jlumin.2022.119211
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Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor