Citation: Bo YANG, Gongxuan LÜ, Jiantai MA. Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO₂ layer[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(2): 365-384. doi: 10.11862/CJIC.20240063 shu

Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO₂ layer

Bo YANG ^{1, 2, 3} ,
Gongxuan LÜ ^1,, ,
Jiantai MA ³

1.
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: Gongxuan LÜ, gxlu@lzb.ac.cn
Received Date: 27 February 2024
Revised Date: 21 September 2024

Figures(16)

This work studied the corrosion and corrosion inhibition of nickel-cobalt bimetallic phosphide (Ni-Co-P) in aqueous solution. The results show that Ni-Co-P could react with H₂O to produce H₂, while Ni²⁺, Co²⁺, and PO₄^3- ions were released into water. The nickel-to-cobalt ratio affects the reaction rate of Ni-Co-P with H₂O, and increased Co content in Ni-Co-P leads to decreased corrosion rate. The influence factors, such as pH value, oxygen content, light, and temperature on the corrosion of Ni-Co-P(n_Ni/n_Co=1/2) prepared with an initial nickel-to-cobalt ratio of 1∶2 in water were studied in detail. To inhibit the corrosion of Ni-Co-P(n_Ni/n_Co=1/2) in aqueous solution, a strategy of coating an inert TiO₂ protective layer was put forward. The TiO₂ protective layer could effectively reduce the corrosion of Ni-Co-P in water and enhance its stability.
- bimetallic phosphide,
- aqueous solution,
- stability,
- TiO₂ protection layer
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沈阳化工大学材料科学与工程学院沈阳 110142

Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO2 layer

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Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO₂ layer