Citation: Gaofeng WANG, Shuwen SUN, Yanfei ZHAO, Lixin MENG, Bohui WEI. Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479 shu

Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone

1.
Department of Applied Chemistry, Yuncheng University, Yuncheng, Shanxi 044000, China
2.
Science Experiment Center, Yuncheng University, Yuncheng, Shanxi 044000, China

Corresponding author: Gaofeng WANG, wgf1979@126.com
Received Date: 19 December 2023
Revised Date: 9 March 2024

Figures(9)

Three zinc coordination polymers, {[Zn₂(bipmo)₂(ipa)₂]·3H₂O}_n (1), {[Zn(bipmo)(5-OH-ipa)]·DMA·H₂O}_n (2), and {[Zn(bipmo)(5-Me-ipa)]·H₂O}_n (3), where bipmo=bis(4-(1H-imidazol-1-yl)phenyl)methanone, H₂ipa=isophthalic acid, 5-OH-ipaH₂=5-hydroxyisophthalic acid, 5-Me-ipaH₂=5-methylisophthalic acid, were synthesized under solvothermal conditions. These complexes have been characterized by elemental analyses, IR spectra, single-crystal X-ray diffraction, etc. Complex 1 shows a 2D 2-fold interpenetrating {4⁴·6²} network. Complex 2 displays a 2D uninodal framework with the {6⁵·8} topology. Complex 3 reveals a 2D layer structure with {6³} topology. The results indicate that the presence of a 5-substituted group in the isophthalate exerts a significant influence on the formation of the final structures. The luminescent properties of the complexes in the solid state have also been studied.
- coordination polymers,
- zinc(Ⅱ),
- topology,
- luminescent property,
- interpenetration
1. [1]
  Dutta A, Singh A, Wang X X, Kumar A, Liu J Q. Luminescent sensing of nitroaromatics by crystalline porous materials[J]. CrystEngComm, 2020,22:7736-7781. doi: 10.1039/D0CE01087A
2. [2]
  Yang L F, Qian S H, Wang X B, Cui X L, Chen B L, Xing H B. Energy-efficient separation alternatives: Metal-organic frameworks and membranes for hydrocarbon separation[J]. Chem. Soc. Rev., 2020,49:5359-5406. doi: 10.1039/C9CS00756C
3. [3]
  KANG X Q, WANG J H, GU J Z. Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), nickel(Ⅱ) and cobalt(Ⅱ) coordination polymers constructed from 4,4'-(pyridin-3,5-diyl)dibenzoic acid[J]. Chinese J. Inorg. Chem., 2023,39(12):2385-2392. doi: 10.11862/CJIC.2023.190
4. [4]
  Rao K P, Higuchi M, Duan J, Kitagawa S. pH-Dependent interpenetrated, polymorphic, Cd²⁺- and BTB-based porous coordination polymers with open metal sites[J]. Cryst. Growth Des., 2013,13:981-985. doi: 10.1021/cg301476p
5. [5]
  XIA Y P, WANG C X, ZHENG J Y, LI N, CHANG Z, BU X H. Construction of a Fe-MOF based on carbazole-carboxylate ligand for CO₂/CH₄ separation[J]. Chem. J. Chinese Universities, 2020,41(11):2415-2420.
6. [6]
  Zhao Z H, Huang J R, Liao P Q, Chen X M. Highly efficient electroreduction of CO₂ to ethanol via asymmetric C—C coupling by a metal-organic framework with heterodimetal dual sites[J]. J. Am. Chem. Soc., 2023,145:26783-26790. doi: 10.1021/jacs.3c08974
7. [7]
  Mu Y J, Ran Y G, Zhang B B, Du J L, Jiang C Y, Du J. Dicarboxylate ligands modulated structural diversity in the construction of Cd(Ⅱ) coordination polymers built from N-heterocyclic ligand: Synthesis, structures, and luminescent sensing[J]. Cryst. Growth Des., 2020,20:6030-6043. doi: 10.1021/acs.cgd.0c00739
8. [8]
  Wang G F, Zhang X, Sun S W, Sun H, Yang X, Li H, Yao C Z, Sun S G, Tang Y P, Meng L X. Syntheses, crystal structures, and characterization of two Mn(Ⅱ) coordination polymers with bis(4-(1H-imidazol-1-yl)phenyl)methanone ligands[J]. Z. Naturforsch. B, 2016,71:869-874.
9. [9]
  Wang G F. Structural diversity of two coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone and polycarboxylate coligands: Syntheses, structures, and fluorescent properties[J]. Russ. J. Coord. Chem., 2018,44:540-546. doi: 10.1134/S1070328418090075
10. [10]
  WANG G F, SUN S W, SONG S F, LÜ M. Synthesis of a Cd(Ⅱ)-based coordination polymer for luminescence detecting 2,4,6-trinitrophenol[J]. Chinese J. Inorg. Chem., 2023,39(12):2407-2414.
11. [11]
  CrysAlis^Pro, Version 1.171.35.19. Agilent Technologies Inc., Santa Clara, CA, USA, 2011.
12. [12]
  Sheldrick G M. SHELXL 2014/7, Program for crystal structure refinement. University of Gö ttingen, Germany, 2014.
13. [13]
  Sheldrick G M. A short history of SHELX[J]. Acta Crystallogr. Sect. A, 2008(A64):112-122.
14. [14]
  Blatov V A. Multipurpose crystallochemical analysis with the program package TOPOS. [2023-11-03]. https://www.iucr.org/resources/commissions/crystallographic-computing/newsletters/7/topos
15. [15]
  Wang C F, Yao Z S, Yang G Y, Tao J. Ligand substituent effects on the spin-crossover behaviors of dinuclear iron(Ⅱ) compounds[J]. Inorg. Chem., 2019,58:1309-1316. doi: 10.1021/acs.inorgchem.8b02789
16. [16]
  Minnick J L, Raincrow J, Meinders G, Latifi R, Tahsini L. Synthesis, characterization, and spectroscopic studies of 2,6-dimethylpyridyl-linked Cu(Ⅰ)-CNC complexes: the electronic influence of aryl wingtips on copper centers[J]. Inorg. Chem., 2023,62:15912-15926. doi: 10.1021/acs.inorgchem.3c01973
17. [17]
  He X, Lu C Z, Yuan D Q. Two 3D porous cadmium tetrazolate frameworks with hexagonal tunnels[J]. Inorg. Chem., 2006,45:5760-5766. doi: 10.1021/ic0520162
18. [18]
  Ouellette W, Hudson B S, Zubieta J. Hydrothermal and structural chemistry of the zinc(Ⅱ)- and cadmium(Ⅱ)-1,2,4-triazolate systems[J]. Inorg. Chem., 2007,46:4887-4904. doi: 10.1021/ic062269a
19. [19]
  Song X Z, Zhao L, Zhang N, Liu L, Ren X, Ma H M, Luo C N, Li Y Y, Wei Q. Zinc-based metal-organic framework with MLCT properties as an efficient electrochemiluminescence probe for trace detection of trenbolone[J]. Anal. Chem., 2022,94:14054-14060. doi: 10.1021/acs.analchem.2c03615
20. [20]
  Zhang Y, Liu Y H, Huo F, Zhang B W, Su W Z, Yang X P. Photoluminescence quenching in recyclable water-soluble Zn-based metal-organic framework nanoflakes for dichromate sensing[J]. ACS Appl. Nano Mater., 2022,5:9223-9229. doi: 10.1021/acsanm.2c01556
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